European Journal of Chemistry

Synthesis, characterization and analytical study of tellurated Schiff base of bis[2-(3-nitrobenzylideneamino)-5-nitrophenyl]telluride and its complexation reactions with Mn(II), Co(II) and Ni(II) ions



Main Article Content

Adil Ali Al-Fregi
Mayada Abdulaa Adnan

Abstract

Reaction of 2-amino-5-nitrophenylmercuric chloride with 3-nitro benzaldehyde gave 2-(3-nitrobenzylideneamino)-5-nitrophenylmercuric chloride (1). Reaction of the mercurated Schiff bases 1 with tellurium tetrabromide in 2:1 mole ratio gave the tellurated Schiff bases, bis[2-(3-nitrobenzylidineamino)-5-nitrophenyl] tellurium dibromide (2). Reduction of compound 2 by hydrazine hydrate gave the corresponding telluride, bis[2-(3-nitro benzylideneamino)-5-nitrophenyl]telluride (3). Complexation reactions of equilibrium mole ratios compound 3 with MnCl2.4H2O, CoCl2.6H2O and NiCl2.6H2O gave the corresponding complexes, i.e compounds 4-6, respectively. All the prepared compounds were characterized by elemental analysis, conductivity measurements and 1H and 13C NMR, FT-IR and UV-visible spectroscopic data. These data suggested that the compound 3 coordinate with metal ions as tridentate ligand. The molar conductivity study indicated compounds 1-3 are neutral and behave as non-electrolytes in DMSO solvent at room temperature while compounds 4-6 behave as 1:1 electrolytes in the same conditions. The molar ratio method was used to determine metal-ligand ratio, which was found as 1:1, metal: ligand. The thermal analysis of compounds 2 and 3 were also investigated and discussed.


icon graph This Abstract was viewed 1713 times | icon graph Article PDF downloaded 1153 times

How to Cite
(1)
Al-Fregi, A. A.; Adnan, M. A. Synthesis, Characterization and Analytical Study of Tellurated Schiff Base of bis[2-(3-Nitrobenzylideneamino)-5-nitrophenyl]telluride and Its Complexation Reactions With Mn(II), Co(II) and Ni(II) Ions. Eur. J. Chem. 2016, 7, 195-200.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Pykko, P. Chem. Rev. 1997, 97, 597-636.
http://dx.doi.org/10.1021/cr940396v

[2]. Sadekov, I. D.; Minkin, V. I.; Zakharov, A. V.; Stankov, A. G.; Borodkin, G. S.; Aldoshin, S. M.; Tkachev, V. V.; Shilov G. V.; Berry, F. J. J. Organomet . Chem. 2005, 690, 103-111.

[3]. Chauhan, A. K.; Anamica; Kumar, A.; Srivastava, R. C.; Butcher, R. J.; Beckman, J.; Duthie, A. J. Organomet. Chem. 2005, 690, 1350-1358.
http://dx.doi.org/10.1016/j.jorganchem.2004.12.001

[4]. Rolling, P. V.; Kirt, D. D.; Dill, J. L.; Hal S. l; Holtstrom, C. J. Organomet. Chem. 1976, 116, 39-46.

[5]. Bruce, M. I.; Goodall, B. L.; Stone, F. A. J. Chem. Soc., Chem. Commun. 1973, 558-559.
http://dx.doi.org/10.1039/c39730000558

[6]. Singh, H. B.; McWhinnie, W. R. J. Chem. Soc. Dalton Trans. 1985, 821- 825.
http://dx.doi.org/10.1039/dt9850000821

[7]. Menon, S. C.; Singh, H. B.; Patal, R. P.; Das, K.; Butcher, R. J. Organometallics 1997, 16, 563- 572.
http://dx.doi.org/10.1021/om9604280

[8]. Al-Rubaie, A. Z.; Al-Masoudi, W. A.; Al-Jadaan, S. A.N.; Jalbout, A. F.; Hameed, A. J. Heteroatom Chem. 2008, 19(3), 307-315.
http://dx.doi.org/10.1002/hc.20437

[9]. Chauhan, A. K. S.; Anamika, Kumar, A.; Singh, P.; Srivastava, R. C.; Butcher, R. J.; Beckmann, J.; Dthie, A. J. Organomet. Chem. 2006, 691, 1954-1963.
http://dx.doi.org/10.1016/j.jorganchem.2006.01.034

[10]. Menon, S. C.; Singh, H. B.; Patel, R. P.; Kulshreshta, S. K. J. Chem. Soc., Dalton Trans. 1996, 1203-1207.
http://dx.doi.org/10.1039/dt9960001203

[11]. Apte, S. D.; Zade, S. S.; Singh, H. B.; Butcher, R. J. Organometallics 2003, 22, 5473-5481.
http://dx.doi.org/10.1021/om034222s

[12]. Mbogo, S. A.; McWhinne, W. R.; Lobana, T. S. J. Organomet. Chem. 1990, 384, 115-124.
http://dx.doi.org/10.1016/0022-328X(90)87058-L

[13]. Khandewal, L.; Singh, A. K.; Srivastava, V. Polyhedron 1990, 9, 2041-2049.
http://dx.doi.org/10.1016/S0277-5387(00)84034-6

[14]. Kumar, R. P.; Singh, A. K.; Drake, J. E. Hursthouse, M. B.; Light, M. E. Inorg. Chem. Commun. 2004, 7, 502-512.

[15]. Mugesh, G.; Panda, A.; Singh, H. B. Proc. Indian Acad. Sci. (Chem. Sci.) 2000, 112, 239-246.
http://dx.doi.org/10.1007/BF02706176

[16]. Al-Rubaie, A. Z.; Al-Fregi, A. A.; Al-Jadaan, S. A. Phosphorus, Sulfur, and Silicon 2011, 186, 115-124.
http://dx.doi.org/10.1080/10426507.2010.485154

[17]. Al-Fregi, A. A.; Al-Asfoor, A. F.; Jabar, S. F. Int. J. Sci. Eng. Res. 2015, 6(3), 274-281.

[18]. Al-Fregi, A. A.; Shabeeb, G. M. American Int. J. Res. Formal, Appl. Nat. Sci. 2014, 6(2), 161-171.

[19]. Feher, F., Hand Book of Preparative Inorganic Chemistry, 2nd Ed., Academic Press, NY, Ch. 7, 1967.

[20]. Doyle, J. R.; Slade, P. E.; Jonassen, H. B. Inorg. Synth. 1960, 6, 218-222.
http://dx.doi.org/10.1002/9780470132371.ch69

[21]. Vogel, A. I., Text Book of Practical Chemistry, 3rd Ed., Academic Press, NY, Ch. 7, 1967.

[22]. Armarego, W. L. F.; Perrin, D. D., Purification of Laboratory Chemicals, 4th Ed., Butterworth-Heinemann, Woburn, MA, USA, 1996.

[23]. Makarova, L. G.; Nesmeyanov, H. M., The Organic Chemistry of Mercury Compound, In Method of Elementary of Organic Chemistry (Edited by A. N. Nesmyanov and K. A. Kocheshakov), Vol. 4, 1st Ed., Northland Publishing Company, Amsterdam, 1967.

[24]. Al-Rubaie, A. Z.; Al-Najar, A. A.; Jassim, F. A. Inorg. Chim. Acta 1990, 175, 181-190.
http://dx.doi.org/10.1016/S0020-1693(00)84825-2

[25]. Al-Rubaie, A. Z.; Al-Shirayda, H. A.; Granger, P.; Chapelle, S. J. Organomet. Chem. 1982, 234, 287-298.
http://dx.doi.org/10.1016/0022-328X(82)80004-1

[26]. Zumbulyad, N.; Gysling, H. J. J. Organomet. Chem. 1980, 192, 183-192.
http://dx.doi.org/10.1016/S0022-328X(00)94422-X

[27]. Jassim, F. A., M. Sc. Thesis, University of Basrah, 1989.

[28]. Silerstien, R. M.; Webster, F. X.; Kiemle, D. J. Spectrometric Identification of Organic Chemistry Compounds, 6th Ed., John Wiley and Sons, NY, 2005.

[29]. Shriner, I.; Hermann, C. K., Spectroscopic Techniques for Organic Chemistry, John Wiley and Sons, NY, 2004.

[30]. Martin, G. E., Cryogenic NMR Probs: Application, D. M. Grant and R. K. Harris, Encyclopedia of Nuclear Magnetic Resonance, Vol. 9, Wiley Chichester, 2002.

[31]. Yoe, J. H.; Jone, A. L. Ind. Eng. Chem., Anal. Ed. 1944, 16, 11-24.

[32]. Jain, A. K.; Aggarwala, V. P.; Chand, P.; Garg, S. P. Talanta 1972, 19(11), 1481-1482.
http://dx.doi.org/10.1016/0039-9140(72)80152-8

[33]. Mohamed, F. J., Chemical Analysis by Atomic Absorption Spectroscopy, Part one, Dar Al-Hekma Ltd., Baghdad, 1989.

[34]. Al-Rubaie, A. Z.; Al-Salim N. I.; Al-Jaddan, S. A. Thermochimica Acta 1993, 215, 235-240.
http://dx.doi.org/10.1016/0040-6031(93)80097-T

Supporting Agencies

Department of Chemistry, College of Science, University of Basra, 61001, Basrah, Iraq
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).