European Journal of Chemistry

Synthesis and characterization of some new organotellurium compounds based on quinoline



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Adil Ali Al-Fregi
Haider Abdul-Sattar Jaid
Hassan Thamir Abdulsahib

Abstract

A new series of organotellurium compounds based on quinoline were prepared by the reaction of 8-(quinolyl)mercuric chloride (1) with tellurium tetrabromide in 1:1 and 1:2 mole ratio in dry dioxane to obtain 8-(quinolyl)tellurium tribromide (2) and bis[8-(quinolyl)]tellurium dibromide (3), respectively, in good yields. Reaction of compounds 2 and 3 by ethanolic hydrazine hydrate gave bis[8-(quinolyl)]ditelluride (4) and bis[8-(quinolyl)]telluride (5), respectively, in moderate yields. Furthermore, the ligand properties of bis[8-(quinolyl)] telluride (5) will be carried out with K2PtCl4, Na2PdCl4 and RhCl3.3H2O. All compounds were characterized by spectroscopic data and elemental analysis.


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Al-Fregi, A. A.; Jaid, H. A.-S.; Abdulsahib, H. T. Synthesis and Characterization of Some New Organotellurium Compounds Based on Quinoline. Eur. J. Chem. 2017, 8, 218-223.

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References

[1]. Reichel, L.; Ilberg, K. Ber. 1943, 76B, 1108-1117.

[2]. Tamang, S. R.; Son, J. H.; Hoefelmeyer, J. D. Dalton Trans. 2014, 43(19), 7139-7145.
https://doi.org/10.1039/C4DT00384E

[3]. Lin, T. P.; Gabbai, F. Angew. Chem. Int. Ed. 2013, 52, 3864-3870.
https://doi.org/10.1002/anie.201300337

[4]. Al-Assadi, R. Ph. D. Thesis, University of Basrah, Iraq, 2013.

[5]. Kumar, S.; Engman, L.; Valgimigli, L.; Amorati, R.; Fumo, M. G; Pedulli, G. F. J. Org. Chem. 2007, 72, 6046-6055.
https://doi.org/10.1021/jo0705465

[6]. Ukai, I. T. J. Pharma. Soc. Japan 1927, 548, 873-879.

[7]. Al-Rubaie, A. Z.; Al-Najar, A. A.; Jassim, F. A. Inorg. Chim. Acta 1990, 175, 181-188.
https://doi.org/10.1016/S0020-1693(00)84825-2

[8]. Qseer, H. A. Croatical Chem. Acta 2005, 78(1), 79-89.

[9]. Kumar, R.; Singh, A. K.; Butcher, R. J.; Shama P.; Toscano, R. A. Eur. J. Inorg. Chem. 2004, 5, 1107-1116.
https://doi.org/10.1002/ejic.200300433

[10]. Kumar, R.; Singh, A. K.; Drake, J. E.; Hursthouse, M. B.; Light, M. E. Inorg. Chem. Commun. 2004, 7, 502-511.
https://doi.org/10.1016/j.inoche.2004.02.001

[11]. Silerstien, R. M.; Webster F. X.; Kiemle, D. J., Spectrometric Identification of Organic Chemistry Compounds, 6th Ed., John Wiley and Sons, N. Y., 2005.

[12]. Al-Rubaie, A. Z.; Al-Fregi, A. A.; Al-Jadaan, S. A. Phosphorus Sulfur Silicon 2011, 186, 115-124.
https://doi.org/10.1080/10426507.2010.485154

[13]. Saadon, H. L.; Ali B.; Al-Fregi, A. A. Optics Laser Tech. 2014, 58, 33-44.
https://doi.org/10.1016/j.optlastec.2013.10.032

[14]. Al-Fregi, A. A. Int. J. Adv. Res. 2015, 3(3), 637-647.

[15]. Al-Fregi, A. A.; Al-Asfoor A. F.; Jabar, S. F. Int. J. Sci. Eng. Res. 2015, 6(3), 274-283.

[16]. Bernstein, M. P.; Mattioda, A.; Sandford, S. A.; Hudgins, D. Astrophysical J. 2005, 626(2), 909-918.
https://doi.org/10.1086/430120

[17]. Nakamoto, K., Infrared and Raman Spectra of Organic and Coordination Compounds, John Wiley and Sons Ltd., 7th Ed., N. Y., 2009.

[18]. Al-Salami, B. K.; Al-Fadhly, A. L.; Al-Fregi, A. A. Der Pharma Chem. 2016, 8(19), 488-497.

[19]. Shriner, R. L.; Hermann, C. K.; Morrill, T. C.; Curtan D. Y.; Fuson, R. C., The systematic identification of Organic compounds, 8th Edition, John Wiley and Sons, N. Y., 2004.

[20]. Mitra, A.; Assarpour, A.; Seaton, P. J.; Williamson, R. T. J. Chem. Ed. 2002, 79(1), 106-109.
https://doi.org/10.1021/ed079p106

[21]. Rouge, P. Food Chem. 2013, 141, 1888-1895.
https://doi.org/10.1016/j.foodchem.2013.04.072

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Department of Chemistry, College of Science, University of Basrah, 61001, Basrah, Iraq
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