European Journal of Chemistry

Synthesis and characterization of some new organotellurium compounds based on quinoline

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Published: Sep 30, 2017
DOI: https://doi.org/10.5155/eurjchem.8.3.218-223.1578
Keywords:
organotellurium compounds palladium(II) complexes platinum(II) complexes rhodium(III) complexes transmetallation reaction. Quinoline derivatives
Section
Research Article
Issue
Vol. 8 No. 3 (2017): September 2017
Dates
Received 2017-04-30
Accepted 2017-05-17
Published 2017-09-30


Main Article Content

Adil Ali Al-Fregi
Department of Chemistry, College of Science, University of Basrah, 61001, Basrah, Iraq
Haider Abdul-Sattar Jaid
Department of Chemistry, College of Science, University of Basrah, 61001, Basrah, Iraq
Hassan Thamir Abdulsahib
Department of Chemistry, College of Science, University of Basrah, 61001, Basrah, Iraq

Abstract

A new series of organotellurium compounds based on quinoline were prepared by the reaction of 8-(quinolyl)mercuric chloride (1) with tellurium tetrabromide in 1:1 and 1:2 mole ratio in dry dioxane to obtain 8-(quinolyl)tellurium tribromide (2) and bis[8-(quinolyl)]tellurium dibromide (3), respectively, in good yields. Reaction of compounds 2 and 3 by ethanolic hydrazine hydrate gave bis[8-(quinolyl)]ditelluride (4) and bis[8-(quinolyl)]telluride (5), respectively, in moderate yields. Furthermore, the ligand properties of bis[8-(quinolyl)] telluride (5) will be carried out with K2PtCl4, Na2PdCl4 and RhCl3.3H2O. All compounds were characterized by spectroscopic data and elemental analysis.


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Al-Fregi, A. A.; Jaid, H. A.-S.; Abdulsahib, H. T. Synthesis and Characterization of Some New Organotellurium Compounds Based on Quinoline. Eur. J. Chem. 2017, 8, 218-223.

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