European Journal of Chemistry

Synthesis, characterization and thermal decomposition of 2’-amino-6’-(1H-indol-3-yl)-1-methyl-2-oxospiro-[indoline-3,4’-pyran]-3’,5’-dicarbonitrile under non-isothermal condition in nitrogen atmosphere



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Ganesan Nalini
Natesan Jayachandramani
Radhakrishnan Suresh
Venugopal Thanikachalam
Govindasamy Manikandan

Abstract

The kinetics and decomposition of a new spirooxindole compound, 2’-amino-6’-(1H-indol-3-yl)-1-methyl-2-oxospiro[indoline-3,4’-pyran]-3’,5’-dicarbonitrile was studied by thermo gravimetric technique under non-isothermal conditions. The kinetic parameters were calculated using model-free (Friedman, Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa methods) and model-fitting (Coats-Redfern) methods. The results of the Friedman isoconversional analysis of the thermo gravimetric data suggested that the investigated decomposition process follows a single-step.


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Nalini, G.; Jayachandramani, N.; Suresh, R.; Thanikachalam, V.; Manikandan, G. Synthesis, Characterization and Thermal Decomposition of 2’-Amino-6’-(1H-Indol-3-Yl)-1-Methyl-2-Oxospiro-[indoline-3,4’-Pyran]-3’,5’-Dicarbonitrile under Non-Isothermal Condition in Nitrogen Atmosphere. Eur. J. Chem. 2016, 7, 380-386.

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