European Journal of Chemistry 2016, 7(3), 368-374 | doi: https://doi.org/10.5155/eurjchem.7.3.368-374.1443 | Get rights and content

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Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases


Subramanian Vedanayaki (1,*) , Poomalai Jayaseelan (2)

(1) Department of Chemistry, Kandaswami Kandar’s College, Paramathi Velur, Tamilnadu, 638182, India
(2) Chemical Division, Mettur Thermal Power Station, Mettur Dam, Tamilnadu, 636406, India
(*) Corresponding Author

Received: 28 Apr 2016 | Revised: 25 Jun 2016 | Accepted: 02 Jul 2016 | Published: 30 Sep 2016 | Issue Date: September 2016

Abstract


New binucleating Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of the prepared ligands with N4 donor were synthesized. The ligands are obtained by the condensation of para-phenylenediamine with diacetylmonoxime and benzilmonoxime. The synthesized ligands and their metal complexes were characterized by elemental analysis and various spectroscopic techniques. The Cu(II), Ni(II) complexes were square planar, VO(II) complex was square pyramidal, whereas Mn(II), Zn(II) complexes were of tedrahedral geometry. Both the ligands and their metal complexes were screened for their antibacterial and antifungal activities by minimum inhibitory concentration method. The results showed that the metal complexes were found to be more active than free ligand. The DNA binding capacities of all the complexes were analyzed by using UV absorption spectra. The DNA cleaving capacities of all complexes were analyzed by agarose gel electrophoresis method against pBR322 DNA.


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Keywords


Dioxime; Binuclear; Schiff base; DNA binding; DNA cleavage; Antimicrobial activity

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DOI: 10.5155/eurjchem.7.3.368-374.1443

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Funding information


University Grant Commission (MRP-5388/14 (SERO/UGC), March 2014, Com.code TNPE004), Hyderabad, India.

Citations

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[1]. P. Priya, S. Vedanayaki, P. Jayaseelan
Synthesis, Spectral Characterization and Biological Evaluation of Schiff Base Metal Complexes Derived from Aniline Derivative
Asian Journal of Chemistry  31(9), 2095, 2019
DOI: 10.14233/ajchem.2019.22129
/


[2]. Karthik Somasundaram, Gomathi Thulasimani, Vedanayaki Subramaniam
Synthesis,Characterization, biocidal, Anti-diabetic, Anti-inflammatory and Anti-Cancer(MCF-7) Studies of Schiff base ligand and its metal (II) complexes
Oriental Journal Of Chemistry  37(1), 58, 2021
DOI: 10.13005/ojc/370107
/


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How to cite


Vedanayaki, S.; Jayaseelan, P. Eur. J. Chem. 2016, 7(3), 368-374. doi:10.5155/eurjchem.7.3.368-374.1443
Vedanayaki, S.; Jayaseelan, P. Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases. Eur. J. Chem. 2016, 7(3), 368-374. doi:10.5155/eurjchem.7.3.368-374.1443
Vedanayaki, S., & Jayaseelan, P. (2016). Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases. European Journal of Chemistry, 7(3), 368-374. doi:10.5155/eurjchem.7.3.368-374.1443
Vedanayaki, Subramanian, & Poomalai Jayaseelan. "Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases." European Journal of Chemistry [Online], 7.3 (2016): 368-374. Web. 6 Jul. 2022
Vedanayaki, Subramanian, AND Jayaseelan, Poomalai. "Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases" European Journal of Chemistry [Online], Volume 7 Number 3 (30 September 2016)

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