European Journal of Chemistry 2016, 7(3), 368-374 | doi: https://doi.org/10.5155/eurjchem.7.3.368-374.1443 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases


Subramanian Vedanayaki (1,*) , Poomalai Jayaseelan (2)

(1) Department of Chemistry, Kandaswami Kandar’s College, Paramathi Velur, Tamilnadu, 638182, India
(2) Chemical Division, Mettur Thermal Power Station, Mettur Dam, Tamilnadu, 636406, India
(*) Corresponding Author

Received: 28 Apr 2016 | Revised: 25 Jun 2016 | Accepted: 02 Jul 2016 | Published: 30 Sep 2016 | Issue Date: September 2016

Abstract


New binucleating Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of the prepared ligands with N4 donor were synthesized. The ligands are obtained by the condensation of para-phenylenediamine with diacetylmonoxime and benzilmonoxime. The synthesized ligands and their metal complexes were characterized by elemental analysis and various spectroscopic techniques. The Cu(II), Ni(II) complexes were square planar, VO(II) complex was square pyramidal, whereas Mn(II), Zn(II) complexes were of tedrahedral geometry. Both the ligands and their metal complexes were screened for their antibacterial and antifungal activities by minimum inhibitory concentration method. The results showed that the metal complexes were found to be more active than free ligand. The DNA binding capacities of all the complexes were analyzed by using UV absorption spectra. The DNA cleaving capacities of all complexes were analyzed by agarose gel electrophoresis method against pBR322 DNA.


Keywords


Dioxime; Binuclear; Schiff base; DNA binding; DNA cleavage; Antimicrobial activity

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.7.3.368-374.1443

Links for Article


| | | | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 893 times | PDF Article downloaded 256 times

Funding information


University Grant Commission (MRP-5388/14 (SERO/UGC), March 2014, Com.code TNPE004), Hyderabad, India.

Citations

/


[1]. P. Priya, S. Vedanayaki, P. Jayaseelan
Synthesis, Spectral Characterization and Biological Evaluation of Schiff Base Metal Complexes Derived from Aniline Derivative
Asian Journal of Chemistry  31(9), 2095, 2019
DOI: 10.14233/ajchem.2019.22129
/


References

[1]. Priyarega, S.; Senthil, R. D.; Ganesh, B. S.; Karvembu, R.; Hashimoto, T.; Endo, A.; Natarajan, K. Polyhedron 2012, 34, 143-148.
http://dx.doi.org/10.1016/j.poly.2011.12.017

[2]. Prabu, R.; Vijayaraj, A.; Suresh, R.; Shenbhagaraman, R.; Kaviyarasan, V.; Narayanan, V. Spectrochim. Acta A 2011, 78, 601-606.
http://dx.doi.org/10.1016/j.saa.2010.11.029

[3]. Naderi, E.; Jafari, A. H.; Ehteshamzadeh, M.; Hosseini, M. G. Mater. Chem. Phys. 2009, 115, 852-858.
http://dx.doi.org/10.1016/j.matchemphys.2009.03.002

[4]. Mistry, B. M.; Jauhari, S. Res. Chem. Intermed. 2013, 39, 1049-1068.
http://dx.doi.org/10.1007/s11164-012-0666-y

[5]. Chena, X.; Yamaguchi, A.; Namekawa, M.; Kamijoa, T.; Teramae, N.; Tong, A. Anal. Chim. Acta 2011, 696, 94-100.
http://dx.doi.org/10.1016/j.aca.2011.04.002

[6]. Joseph, J.; Nagashri, K.; BoomadeviJanaki, G. Eur. J. Med. Chem. 2012, 49, 151-163.
http://dx.doi.org/10.1016/j.ejmech.2012.01.006

[7]. Muniyandi, V.; Pravin, N.; Mitu, L.; Raman, N. J. Mol. Struc. 2015, 1086, 56-63.
http://dx.doi.org/10.1016/j.molstruc.2015.01.011

[8]. Kamath, A.; Naik, K.; Netalkar, S. P.; Kokare, D. G.; Revanka, V. K. Med. Chem. Res. 2013, 22, 1948-1956.
http://dx.doi.org/10.1007/s00044-012-0199-3

[9]. Farag, A. M.; Guan, T. S.; Osman, H.; Abdul, M. S.; Iqbal, M. A.; Khadeer, A. M. B. Med. Chem. Res. 2013, 22, 4727-4736.
http://dx.doi.org/10.1007/s00044-013-0482-y

[10]. Jayaseelan, P.; Prasad, S.; Vedanayaki, S.; Rajavel, R. Arabian J. Chem. 2011, DOI: 10.1016/j.arabjc.2011.07.029.
http://dx.doi.org/10.1016/j.arabjc.2011.07.029

[11]. Akila, E.; Usharani, M.; Ramachandran, S.; Jayaseelan, P.; Velraj, G.; Rajavel, R. Arabian J. Chem. 2013, DOI: 10.1016/j.arabjc.2013.11.031.
http://dx.doi.org/10.1016/j.arabjc.2013.11.031

[12]. Chen, Z.; Zhang, J.; Zhang, S. New J. Chem. 2015, 39, 1814-1821.
http://dx.doi.org/10.1039/C4NJ01623H

[13]. Krishna, M. P.; Hussain, R. K.; Prakash, P. J.; Siddavattam, D. Trans. Metal Chem. 2008, 33, 661-668.
http://dx.doi.org/10.1007/s11243-008-9094-7

[14]. Mohini, Y.; Prasad, R. B. N.; Karuna, M. S. L.; Ganesh, K. C.; Poornima, M.; Sujitha P. Med. Chem. Res. 2013, 22, 4360-4366.
http://dx.doi.org/10.1007/s00044-012-0450-y

[15]. Sumrra, S. H.; Chohan, Z. H. Med. Chem. Res. 2013, 22, 3934-3942.
http://dx.doi.org/10.1007/s00044-012-0388-0

[16]. Lahiri, D.; Majumdar, R.; Patra, K.; Chakravarty, A. R. J. Chem. Sci. 2010, 122(3), 321-333.
http://dx.doi.org/10.1007/s12039-010-0037-4

[17]. Joseph, J.; Nagashri, K.; Bibin, R. G. A. J. Saudi Chem. Soc. 2013, 17(3), 285-294.
http://dx.doi.org/10.1016/j.jscs.2011.04.007

[18]. Marmur J. J. Mole. Biol. 1961, 3, 208-214.

[19]. Anbu, S.; Kamalraj, S.; Varghese, B.; Muthumary, J.; Kandaswamy, M. Inorg. Chem. 2012, 51, 5580-5592.
http://dx.doi.org/10.1021/ic202451e

[20]. Shivakumar, L.; Shivaprasad, K.; Revanasiddappa, H. D. Spectrochim. Acta A 2012, 97, 659-666.
http://dx.doi.org/10.1016/j.saa.2012.07.015

[21]. Souaya, E. R.; Hanna, W. G.; Ismail, E. H.; Milad, N. E. Molecules 2000, 5(10), 1121-1129.
http://dx.doi.org/10.3390/51001121

[22]. Lever, A. B. P. Inorganic electronic spectroscopy, Elsevier, Amsterdam, New York, 1984.

[23]. Sathyanarayana, E. N. Electronic absorption spectroscopy and related techniques, UniversityPress (India) limited, Hyderabad, 2001.

[24]. Kivelson, D.; Neiman, R. J. Chem. Phys. 1961, 35, 149-155.
http://dx.doi.org/10.1063/1.1731880

[25]. Abdel-Aiz, A. A.; Salem, A.N.M.; Sayed, M.A.; Abolay, M.N. Mol. Struct. 2012, 1010, 130-138.
http://dx.doi.org/10.1016/j.molstruc.2011.11.043

[26]. Hathaway, B. J.; Bardley, J. N.; Gillard, R. D. Essays in Chemistry, Academic Press Eds. New York, USA, 1971.

[27]. Tweedy, B. G. Phytopathalogy 1964, 55, 910-914.

[28]. Silva, C. M.; Silva, D. L.; Modolo, L. V.; Alves, R. B.; Resende, M. A.; Martins, C. V. B. Fatima, A. J. Adv. Res. 2011, 2, 1-8.

[29]. Arjmand, F.; Sayeed, F.; Muddassir, M. J. Photochem. Photobiol. B: Biol. 2011, 103, 166-179.
http://dx.doi.org/10.1016/j.jphotobiol.2011.03.001

[30]. Iqbal, M.; Ali, S.; Rehman, Z.; Muhammad, N.; Sohail, M.; Pandarinathan, V. J. Mol. Struc. 2015, 1093, 135-143.
http://dx.doi.org/10.1016/j.molstruc.2015.03.058

[31]. Sobha, S.; Mahalakshmi, R.; Raman, N. Spectrochim. Acta A 2012, 92, 175-183.
http://dx.doi.org/10.1016/j.saa.2012.02.063

[32]. Vilson, K.; Walker, J. Principles and Techniques of Biochemistry and Molecular biology, Seventh edn., Cambridge University Press, India, 2010.

[33]. Lin, Y.; Cho, H.; Tan, L.; Yuan, Y.; Wei, W.; Ji, L. J. Inorg. Biochem. 2005, 99, 530-537.
http://dx.doi.org/10.1016/j.jinorgbio.2004.10.030

[34]. Jayaseelan. P.; Akila, E.; Usha, R. M.; Rajavel, R. J. Saudi Chem. Soc. 2013. DOI:10.1016/j.jscs.2013.07.001.
http://dx.doi.org/10.1016/j.jscs.2013.07.001

How to cite


Vedanayaki, S.; Jayaseelan, P. Eur. J. Chem. 2016, 7(3), 368-374. doi:10.5155/eurjchem.7.3.368-374.1443
Vedanayaki, S.; Jayaseelan, P. Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases. Eur. J. Chem. 2016, 7(3), 368-374. doi:10.5155/eurjchem.7.3.368-374.1443
Vedanayaki, S., & Jayaseelan, P. (2016). Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases. European Journal of Chemistry, 7(3), 368-374. doi:10.5155/eurjchem.7.3.368-374.1443
Vedanayaki, Subramanian, & Poomalai Jayaseelan. "Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases." European Journal of Chemistry [Online], 7.3 (2016): 368-374. Web. 27 May. 2020
Vedanayaki, Subramanian, AND Jayaseelan, Poomalai. "Synthesis, structural characterization and biological properties of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) complexes of tetradentate Schiff bases" European Journal of Chemistry [Online], Volume 7 Number 3 (30 September 2016)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.7.3.368-374.1443

| | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2016, 7(3), 368-374 | doi: https://doi.org/10.5155/eurjchem.7.3.368-374.1443 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.

hatay escort hatay escort corlu escort corum escort burgaz escort giresun escort aydin escort ordu escort erzincan escort hatay escort sivas escort rize escort edirne escort aksaray escort kibris escort isparta escort erzurum escort tekirdag escort usak escort urfa escort kastamonu escort kibris escort manisa escort giresun escort urfa escort nevsehir escort sivas escort yalova escort ordu escort hatay escort yalova escort amasya escort kayseri escort ordu escort maras escort canakkale escort yalova escort balikesir escort manisa escort urfa escort mugla escort trabzon escort bolu escort corlu escort diyarbakir escort isparta escort kutahya escort elazig escort erzurum escort sakarya escort afyon escort kutahya escort konya escort agri escort cesme escort sinop escort sivas escort konya escort kibris escort adapazari escort luleburgaz escort adana escort kibris escort rize escort sakarya escort alanya escort isparta escort burdur escort konya escort bitlis escort canakkale escort sivas escort amasya escort mus escort aydin escort van escort yalova escort kastamonu escort mardin escort bolu escort afyon escort sakarya escort isparta escort tokat escort trakya escort bayburt escort urfa escort mardin escort