European Journal of Chemistry

Synthesis, spectral characterization, electrochemical and anti-microbial activities of new binuclear Schiff base metal complexes derived from 3,3’ diaminobenzedine



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Poomalai Jayaseelan
Selladurai Prasad
Subramanian Vedanayaki
Rangappan Rajavel

Abstract

A novel oxime ligand has been synthesized by refluxing 3,3’-diaminobenzedine and phthalaldehyde monoxime. Copper (II), cobalt (II), nickel (II) and manganese (II) binuclear complexes of this ligand have been prepared and characterized by using elemental analysis, molar conductance studies, IR, UV, NMR, EPR and magnetic studies. The molar conductance measurements correspond to a non-electrolytic nature for all complexes which can be formulated as [M2(L)X4] (Where M = Cu(II), Ni(II), Co(II) and Mn(II); X = Cl). The UV-visible spectra of all the complexes are well characterized by broad weak d-d band and a high intensity charge-transfer transition. Thermal studies supported the chemical formation of these complexes showed that they decomposed in three or four stages depending on the type of ligand. The far-IR spectrum confirms the presence of coordinate chloride ion in all the complexes as evidenced by one intense far IR bands around 310-330 cm−1. In electrochemical studies the resulting cyclic voltammogram consists of single quasi-reversible one electron transfer. The ligand and complexes have been screened for their antimicrobial activity against two Gram-positive bacteria, two Gram-negative bacteria and fungi. The binuclear metal complexes were found to possess potent antimicrobial, antifungal activity better than ligand alone.

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Jayaseelan, P.; Prasad, S.; Vedanayaki, S.; Rajavel, R. Synthesis, Spectral Characterization, Electrochemical and Anti-Microbial Activities of New Binuclear Schiff Base Metal Complexes Derived from 3,3’ Diaminobenzedine. Eur. J. Chem. 2011, 2, 480-484.

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References

[1]. Kiani, S.; Staples, R. J.; Ted T. S.; Packard, A. B. Polyhedron 2009, 28, 775-781.
http://dx.doi.org/10.1016/j.poly.2008.12.006
PMid:20161333 PMCid:2678757

[2]. Karabocek, S.; Karabocek, N.; Armutcu, A. Trans. Met. Chem. 2006, 31, 459-464.
http://dx.doi.org/10.1007/s11243-006-0012-6

[3]. Karabocek, N.; Armutcu, A.; Karabocek, S. Trans. Met. Chem. 2006, 31, 938-942.
http://dx.doi.org/10.1007/s11243-006-0089-y

[4]. Wu, H. C.; Thanasekaran, P.; Tsai, C. H.; Wu, J. Y.; Huang, S. M.; Wen, Y.; Lu. K. L. Inorg. Chem. 2006, 45, 295-303.
http://dx.doi.org/10.1021/ic051235k
PMid:16390068

[5]. Maity, D.; Drew, M. G. B.; Godsell, J. F.; Roy, S.; Mukhopadhyay, G. Trans. Met. Chem. 2010, 35, 197-204.
http://dx.doi.org/10.1007/s11243-009-9314-9

[6]. Kilic, A.; Tas, E.; Gumgum, B.; Yilmaz, I. J. Coord. Chem. 2007, 60, 1233-1246.
http://dx.doi.org/10.1080/00958970601035914

[7]. Arab C. M.; Soltanpanah, S.; Goudarzi, N. Sensors and Actuators B 2009, 138, 251-256.
http://dx.doi.org/10.1016/j.snb.2009.01.049

[8]. Dede, B.; Karipcin, F.; Cengiz, M. J. Chem. Sci. 2009, 121, 163-171.
http://dx.doi.org/10.1007/s12039-009-0018-7

[9]. Dhar, S.; Nethaji, M.; Chakravarty, A. R. Inorg. Chim. Acta 2005, 358, 2437-2444.
http://dx.doi.org/10.1016/j.ica.2005.02.006

[10]. Li, L. Z.; Zhao, C.; Xu, T.; Ji, H. W.; Yu, Y. H.; Guo, G. Q.; Chao, H. J. Inorg. Biochem. 2005, 99, 1076-1082.
http://dx.doi.org/10.1016/j.jinorgbio.2005.01.017
PMid:15833330

[11]. Babu, M. S. S.; Reddy, K. H.; Krishna, P. G. Polyhedron 2007, 26, 572-580.
http://dx.doi.org/10.1016/j.poly.2006.08.026

[12]. Pope, L. E.; Sigman, D. S. Proc. Natl. Acad. Sci. USA, 1984, 806-813.
PMid:16593414 PMCid:344926

[13]. Tumer, M.; Koksal, H.; Serin, S.; Petat, S. Inorg. Met. Org. Chem. 1997, 27, 59-68.
http://dx.doi.org/10.1080/00945719708000182

[14]. Vogel, A. I. Text Book of Practical organic chemistry 5th edn., Longman London, 1989.

[15]. Gross, D. C.; De Vay, S. C. Physiol. Plant Pathol. 1977, 11, 13-21.

[16]. William, H.; Stephen, V. Theory and Application of Microbiological Assay, Academic Press, San Diego, 1989.

[17]. Jeffery, G. H.; Basset, J.; Mendhan, J.; Denny, R. J.; Vogel’s quantitative chemical analysis, 5th edn., Longman Science and tech, Sussex UK, 1989.

[18]. Refat, M. S.; El-Korashy, S. A.; Kumar, D. N.; Ahmad, A. S. Spectrochim. Acta A 2008, 70(4), 898-906.
http://dx.doi.org/10.1016/j.saa.2007.10.005
PMid:18024192

[19]. Souaya, E. R.; Hanna, W. G.; Ismail, E. H.; Milad, N. E. Molecules 2000, 5, 1121-1129.
http://dx.doi.org/10.3390/51001121

[20]. Tarafder, M. T. H.; Khoo, T. J.; Crouse, K. A.; Ali, A. M.; Yamin, B. M.; Fun, H. K. Polyhedron 2002, 21, 2691-2698.
http://dx.doi.org/10.1016/S0277-5387(02)01272-X

[21]. Ferraro, J. R. Low frequency vibrations of inorganic and coordination compounds, New York, Plenum press, 1971.

[22]. Murphy, B.; Nelson, J.; Nelson, S. M.; Drew, M. G. B.; Yates, P. C. J. Chem. Soc. Dalton. Trans 1987, 123, 127-135.

[23]. Tas E.; Aslanoglu, M.; Kilic. A.; Kara, Z. J. Coord. Chem. 2006, 59(8), 861-872.
http://dx.doi.org/10.1080/00958970500412206

[24]. Serbest, K.; Karabocek, S.; Degirmencioglu, I.; Guner, S. Transition. Met. Chem 2001, 26, 375-379.
http://dx.doi.org/10.1023/A:1011073212502

[25]. Lever, A. B. P. Inorganic electronic spectroscopy, Amsterdam, The Netherlands Elsevier, 1984.

[26]. Sathyanarayana, E. N. Electronic absorption spectroscopy and related techniques, University press, 2001.

[27]. Sreedaran, S.; Shanmuga Bharathi, K.; Kalilur R. A.; Jagadish, L.; Kaviyarasan, V.; Narayanan, V. Polyhedron 2008, 27, 2931-2938.
http://dx.doi.org/10.1016/j.poly.2008.06.025

[28]. Dolaza, M.; McKeeb, V.; Golcua, A.; Tumera, M. Spectrochim, Acta A 2009, 71, 1648-1654.
http://dx.doi.org/10.1016/j.saa.2008.06.012
PMid:18667354

[29]. Budagumpi, S.; Revankar, V. K. Spectrochim. Acta A 2010, 77, 184-188.
http://dx.doi.org/10.1016/j.saa.2010.05.005
PMid:20965136

[30]. Venkatachalam, G.; Raja, N.; Pandiarajan, D.; Ramesh, R. Spectrochim. Acta A 2008, 71, 884-891.
http://dx.doi.org/10.1016/j.saa.2008.02.006
PMid:18358767

[31]. Olar, R.; Badea, M.; Marinescu, D. J. Therm. Anal. Calorim. 2010, 99, 893-898.
http://dx.doi.org/10.1007/s10973-009-0487-4

[32]. Venkateswara Rao, B. J Therm. Anal. Calorim. 2010, 100, 577-587.
http://dx.doi.org/10.1007/s10973-009-0512-7

[33]. Emara, A. A. A. Spectrochim. Acta A 2010, 77, 117-125.
http://dx.doi.org/10.1016/j.saa.2010.04.036
PMid:20627808

[34]. Rosu, T.; Pahontu, E.; Maxim, C.; Georgescu, R.; Stanica, N.; Almajan, G. L.; Gulea, A. Polyhedron 2010, 29, 757-766.
http://dx.doi.org/10.1016/j.poly.2009.10.017

[35]. Sonmez, M.; Celebi, M.; Berber, I. Euro. J. Med. Chem. 2010, 45, 1935-1940.
http://dx.doi.org/10.1016/j.ejmech.2010.01.035
PMid:20163896

[36]. Chang, E. L.; Simmers, C.; Andrew Knight, D. Pharmaceuticals 2010, 3, 1711-1728.
http://dx.doi.org/10.3390/ph3061711

[37]. Kurtomg lu, M.; Dagdelen, M. M.; Torog lu, S. Trans. Met. Chem. 2006, 31, 382-388.

[38]. Tweedy, B. G. Phytopathalogy 1964, 55, 910-914.

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