

Synthesis and crystal structure of poly{bis-(3-nitro-2,4-pentanediono)-copper(II)}, [Cu(NO2-acac)2]n
Najat Lauibi Ghali (1)




(1) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(2) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(3) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(4) Department of Chemical Engineering, National University of Malaysia, Pekan Bangi, 43600 Bangi, Selangor, Malaysia
(*) Corresponding Author
Received: 24 Jan 2017 | Revised: 23 Feb 2017 | Accepted: 16 Mar 2017 | Published: 30 Jun 2017 | Issue Date: June 2017
Abstract
The organo-inorganic polymer, poly[{Cu(NO2-acac)2}3]n, has been prepared and its crystal structure was determined. The structure consists of a trimeric unit in which, acetylacetone ligated symmetrically to copper atoms that pose in the center of octahedrons. The three octahedral fragments of the trimer are linked to each other through nitro group. Crystal Data: C10H12CuN2O8, Mr = 351.76, triclinic, P-1 (No. 2), a = 5.8237(2) Å, b = 7.7963(3) Å, c = 7.8847(3) Å, α = 81.988(2)°, b = 75.294(2)°, γ = 72.217(2)°, V = 328.98(2) Å3, T = 143(2) K, Z = 1, Z' = 0.5, μ(Mo Kα) = 1.703, 3021 reflections measured, 1421 unique (Rint = 0.0156) which were used in all calculations. The final wR2 was 0.0686 (all data) and R1 was 0.0217 (I > 2σ (I)).
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DOI: 10.5155/eurjchem.8.2.109-111.1548
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Chemical Engineering, the National University of Malaysia, Malaysia
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DOI Link: https://doi.org/10.5155/eurjchem.8.2.109-111.1548

















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