European Journal of Chemistry

Synthesis and crystal structure of poly{bis-(3-nitro-2,4-pentanediono)-copper(II)}, [Cu(NO2-acac)2]n

Article Sidebar

PDF CIF FILE
Published: Jun 30, 2017
DOI: https://doi.org/10.5155/eurjchem.8.2.109-111.1548
Keywords:
Octahedron, Acetyl acetone, Crystal structure, Copper(II) complex, Coordination polymer, Organo-inorganic polymer
Section
Research Article
Issue
Vol. 8 No. 2 (2017): June 2017
Dates
Received 2017-01-24
Accepted 2017-03-16
Published 2017-06-30


Main Article Content

Najat Lauibi Ghali
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
Mohammed Jassim Al-Assadi
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
Hadi Salman Al-Lami
Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
Abdul Amir Hassan Kadhum
Department of Chemical Engineering, National University of Malaysia, Pekan Bangi, 43600 Bangi, Selangor, Malaysia

Abstract

The organo-inorganic polymer, poly[{Cu(NO2-acac)2}3]n, has been prepared and its crystal structure was determined. The structure consists of a trimeric unit in which, acetylacetone ligated symmetrically to copper atoms that pose in the center of octahedrons. The three octahedral fragments of the trimer are linked to each other through nitro group. Crystal Data: C10H12CuN2O8, Mr = 351.76, triclinic, P-1 (No. 2), a = 5.8237(2) Å, b = 7.7963(3) Å, c = 7.8847(3) Å, α = 81.988(2)°, b = 75.294(2)°, γ = 72.217(2)°, V = 328.98(2) Å3, T = 143(2) K, Z = 1, Z' = 0.5, μ(Mo Kα) = 1.703, 3021 reflections measured, 1421 unique (Rint = 0.0156) which were used in all calculations. The final wR2 was 0.0686 (all data) and R1 was 0.0217 (I > 2σ (I)).


icon graph This Abstract was viewed 1484 times | icon graph Article PDF downloaded 757 times icon graph Article CIF FILE downloaded 0 times

How to Cite
(1)
Ghali, N. L.; Al-Assadi, M. J.; Al-Lami, H. S.; Kadhum, A. A. H. Synthesis and Crystal Structure of poly{bis-(3-Nitro-2,4-Pentanediono)-copper(II)}, [Cu(NO2-acac)2]n. Eur. J. Chem. 2017, 8, 109-111.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Batter, S. R.; Champness, N. R.; Chew, X. M.; Garcia, M. J.; Kitagawa, S.; Ohrstrom, L.; O'keeffe, M.; Suh, M. P.; Reedijk, J. Pure Appl. Chem. IUPAC 2013, 85(8), 1715-1724.

[2]. Fromm, K. Coord. Chem. Rev. 2008, 252(8-9), 856-885.
https://doi.org/10.1016/j.ccr.2007.10.032

[3]. You, X. Coord. Chem. Rev. 2006, 35, 3257-3263.

[4]. Atwood, J. L. Inclusion Compounds in Ullmanu's Encyclopedia of Industrial Chemistry, Weily-VCH, Weinheim, 2012.

[5]. Bureekaew, S. Sci. Techno. Adv. Mater. 2007, 9, 2-4.

[6]. Hoskins, B. F.; Robson, R. J. Amer. Chem. Soc. 1999, 112(4), 1546-1554.
https://doi.org/10.1021/ja00160a038

[7]. Gardner, G. B.; Venkataraman, D.; Moore, J. S.; Lees, S. Nature 1997, 374, 792-795.
https://doi.org/10.1038/374792a0

[8]. Keller, S. W. Angew. Chem. Int. Ed., Engl. 1997, 36(3), 247-248.
https://doi.org/10.1002/anie.199702471

[9]. Abrahams, B. F.; Hoskins, D. M.; Robson, R. Nature 1994, 369, 727-729.
https://doi.org/10.1038/369727a0

[10]. Bowmaker, G. A.; Hanna, J. V.; Healy, P. C.; Reid, J. C.; Rickard, C. E.; White, A. H. J. Chem. Soc., Dalton Trans. 2000, 753-768.
https://doi.org/10.1039/a908427d

[11]. Lazarou, K. N.; Perlepcs, S. P.; Psycharis, V.; Raptopoulou, C. P. Polyhedron 2008, 27(9-10), 2131-2142.
https://doi.org/10.1016/j.poly.2008.04.005

[12]. Stuant, R. B.; Suzanne, M. N.; David, R. T. Coordination polymers: Design, Analysis and Application. RSC Publishing, 2008.

[13]. Hagerman, D.; Hammond, R. P.; Haushalter, R.; Zubieta, J. Chem. Mater. 1998, 10(8), 2091-2100.

[14]. Tong, M. L.; Chen, H. J.; Chen, X. M. Inorg. Chem. 2000, 39(10), 2235-2238.
https://doi.org/10.1021/ic991312+

[15]. Dong, Y. B.; Smith, M. D.; Loye, H. C. Inorg. Chem. 2000, 39(21), 4927-4935.
https://doi.org/10.1021/ic0006504

[16]. Dong, Y. B.; Smith, M. D.; Layland, R. C.; zur Loye, H. C. Chem. Mater. 2000, 12, 1156-1161.
https://doi.org/10.1021/cm9907965

[17]. Mustapha, A. B.; Mose, L. J. Amer. Chem. Soc. 2014, 4(3), 280-285.
https://doi.org/10.9734/ACSJ/2014/7529

[18]. Baker, M. H.; Dorweiller, J. D.; Amande, N. L.; Pike, R. D.; Berry, S. M. Polyhedron 2009, 28(1), 188-194.
https://doi.org/10.1016/j.poly.2008.10.019

[19]. Singh, P. R.; Sahai, R. Aust. J. Chem. 1967, 20, 649-655.
https://doi.org/10.1071/CH9670649

[20]. Sheldrick, G. M. SHELXL-97, Program for Solution Crystal Structure, University of Gottingen, Germany, 1997.

[21]. LeBrun, P. C.; Lyon, W. D.; Kuska, H. A. J. Crystallogr. Spectrosc. Res. 1986, 6, 889-893.
https://doi.org/10.1007/BF01188194

[22]. Golochoubain, H. Asian J. Chem. 2008, 20(8), 5834-5838.

Supporting Agencies

Chemical Engineering, the National University of Malaysia, Malaysia
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).