European Journal of Chemistry 2017, 8(3), 279-287 | doi: https://doi.org/10.5155/eurjchem.8.3.279-287.1593 | Get rights and content

Issue cover





  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Carbon Aerogels: a study with different models of the effect resorcinol/catalyst at different ratios after pyrolysis and the effect on textural properties


Rafael Alberto Fonseca-Correa (1) , Marlon Jose Bastidas-Barranco (2) , Liliana Giraldo (3) , Juan Carlos Moreno-Piraján (4,*)

(1) Facultad de Ciencias, Departamento de Química, Grupo de Investigación en Sólidos Porosos y Calorimetría, Universidad de los Andes, Bogotá, 11001000, Colombia
(2) Facultad de Ingeniería, Grupo DestaCar, Universidad de la Guajira, Guajira, 440001, Colombia
(3) Facultad de Ciencias, Departamento de Química, Universidad Nacional de Colombia, Bogotá, 11001000, Colombia
(4) Facultad de Ciencias, Departamento de Química, Grupo de Investigación en Sólidos Porosos y Calorimetría, Universidad de los Andes, Bogotá, 11001000, Colombia
(*) Corresponding Author

Received: 03 Jun 2017 | Revised: 31 Jul 2017 | Accepted: 05 Aug 2017 | Published: 30 Sep 2017 | Issue Date: September 2017

Abstract


Eight samples of carbon aerogels were prepared at various resorcinol/catalytic (R/C) ratios (ranging from 25 to 1500) and followed the changes in structure after pyrolysis. Isotherms of N2 to 77 K were determined to calculate the textural parameters using Dubinin-Astakhov (DA), Barret Joyner and Halenda (BJH), Non-Local Density Functional Theory (NLDFT) and Quenched Solid Density Functional Theory (QSDFT) models. The results generated two series of samples. In series I, a single type of pores developed (microporous, at low R/C weight ratio). Series II developed mesoporosity to top gears of R/C (> 400). The specific areas ranged from 64 to 990 m2/g. Additional models were applied to the materials synthesized, which allowed for adjustment to a system of “cylinder-slit” pores by applying the QSDFT kernel, with an error percentage ranging from 0.03 to 0.74.


Keywords


QSDFT; NLDFT; Aerogels; Surface chemistry; Adsorption properties; Microporous materials

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.8.3.279-287.1593

Links for Article


| | | | | | |

| | | | | | |

| | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 1211 times | icon graph PDF Article downloaded 235 times

Funding information


Grant Basic Sciences by the University of the Andes through the Faculty of Science and the Vice-rectory of Research; and the Bank of the Republic of Colombia for their funding and the Convention 3580.

Citations

/


[1]. Xu Han, Mei Wang, My Linh Le, Nicholas M. Bedford, Taylor J. Woehl, V. Sara Thoi
Effects of substrate porosity in carbon aerogel supported copper for electrocatalytic carbon dioxide reduction
Electrochimica Acta  297, 545, 2019
DOI: 10.1016/j.electacta.2018.11.203
/

[2]. Rafael A. Fonseca-Correa, Liliana Giraldo, Juan Carlos Moreno-Piraján
Thermodynamic study of adsorption of nickel ions onto carbon aerogels
Heliyon  5(6), e01789, 2019
DOI: 10.1016/j.heliyon.2019.e01789
/

References


[1]. Zarzycki, J.; Woignier, T. Aerogels, Springer Proceedings in Physics 6th, Springer-Verlag Berlin Heidelberg, 1986.

[2]. Pekala, R. W.; Alviso, C. T. Mater. Res. Soc. Symp. Proc. 1992, 270, 3-14.
https://doi.org/10.1557/PROC-270-3

[3]. Pekala, R. W.; Alviso, C. T.; Kong, F. M.; Hulsey, S. S. J. Non-Cryst. Solids 1992, 145, 90-98.
https://doi.org/10.1016/S0022-3093(05)80436-3

[4]. Pekala, R. W.; Kong, F. M. Polym. Prepr. 1989, 30, 221-223.

[5]. Lin, C.; Ritter, J. A. Carbon 1997, 35, 1271-1280.
https://doi.org/10.1016/S0008-6223(97)00069-9

[6]. Gallegos, S. E.; Perez, C. A. F.; Maldonado, H. F. J.; Carrasco, M. F. Chem. Eng. J. 2012, 181-182, 851-855.
https://doi.org/10.1016/j.cej.2011.12.002

[7]. Luzny, R.; Ignasiak, M.; Walendzewski, J.; Stolarski, M. Chemik 2014, 68(6), 544-553.

[8]. Nianping, L.; Jun, S.; Pung, L. Microporous Mesoporous Mater. 2013, 167, 176-181.
https://doi.org/10.1016/j.micromeso.2012.09.009

[9]. Yonk, K.; Ya, Z.; Xiaodong, S.; Sheng, C.; Meng, Y.; Kaming, T.; Junjun, Z. J. Non-Cryst. Solids 2012, 358, 3150-3155.
https://doi.org/10.1016/j.jnoncrysol.2012.08.029

[10]. Yousheng, T.; Morinobu, E.; Katsumi, K. Recent Pat. Chem. Eng. 2008, 1, 192-200.

[11]. Ai, D.; Bin, Z.; Zhihua, Z.; Jun, S. Materials 2013, 6(3), 941-968.
https://doi.org/10.3390/ma6030941

[12]. Al-Muhtaseb, S. A.; Ritter, J. A. Adv. Mater. 2013, 15(2), 101-114.
https://doi.org/10.1002/adma.200390020

[13]. Jyotsna, G.; Kadirvelu, K.; Rajagopal, C.; Garg, V. K. Ind. Eng. Chem. Res. 2006, 45, 6531-6537.
https://doi.org/10.1021/ie060010u

[14]. Gang, P. W.; Junbing, Y.; Dapeng, W.; Rui, X.; Khalil, A.; Chun, X. L. Mater. Lett. 2014, 115, 1-4.
https://doi.org/10.1016/j.matlet.2013.10.003

[15]. Kaneko, K.; Ishii, C. Colloids Surf. 1992, 67, 203-212.
https://doi.org/10.1016/0166-6622(92)80299-H

[16]. Kaneko, K.; Shimizu, K.; Suzuki, T. J. Chem. Phys. 1992, 98, 8705-8711.
https://doi.org/10.1063/1.463389

[17]. Setoyama, N.; Kaneko, K.; Rodriguez, R. F. J. Phys. Chem. 1996, 100, 10331-10336.
https://doi.org/10.1021/jp960467p

[18]. Setoyama, N.; Ruike, M.; Kasu, T.; Suzuki, T.; Kaneko, K. Langmuir 1993, 9(10), 2612-2617.
https://doi.org/10.1021/la00034a021

[19]. Setoyama, N.; Suzuki, S.; Kaneko, K. Carbon 1998, 36, 1459-1467.
https://doi.org/10.1016/S0008-6223(98)00138-9

[20]. Ruike, M.; Kasu, T.; Setoyama, N.; Suzuki, T.; Kaneko, K. J. Phys. Chem. 1994, 98(38), 9594-9600.
https://doi.org/10.1021/j100089a038

[21]. Liyama, T.; Nishikawa, K.; Otowa, T.; Kaneko, K. J. Phys. Chem. 1995, 99(25), 10075-10076.
https://doi.org/10.1021/j100025a004

[22]. Sing, K. S. W.; Everett, D. H.; Haul, R. A. W.; Moscou, L.; Pierotti, R. A.; Rouquerol, F.; Siemieniewska, T. Pure Appl. Chem. 1985, 57(4), 603-619.
https://doi.org/10.1351/pac198557040603

[23]. Hanzawa, Y.; Kaneko, K.; Pekala, R. W.; Dresselhaus, M. S. Langmuir 1996, 12(26), 6167-6169.
https://doi.org/10.1021/la960481t

[24]. Dollimore, D.; Heal, G. R. J. Appl. Chem. 1964, 14, 109-114.
https://doi.org/10.1002/jctb.5010140302

[25]. Dollimore, D.; Heal, G. R. J. Colloid Interface sci. 1979, 33, 508-519.
https://doi.org/10.1016/0021-9797(70)90002-0

[26]. Pekala, R. W.; Schaefer, D. W. Macromolecules 1993, 26, 5487-5493.
https://doi.org/10.1021/ma00072a029

[27]. Schaefer, D. W.; Pekala, R. W.; Beaucage, G. J. Non-Cryst. Solids 1995, 186, 159-167.
https://doi.org/10.1016/0022-3093(95)00043-7

[28]. Maldonado, H. F. J. Catal. Today 2013, 218-219, 43-50.
https://doi.org/10.1016/j.cattod.2013.06.005

[29]. Morales, T. S.; Maldonado, H. F. J.; Pérez, C. A. F.; Carrasco, M. F. Phys. Chem. Chem. Phys. 2012, 12, 10365-10372.
https://doi.org/10.1039/c003396k

[30]. Fairen, J. D.; Carrasco, M. F.; Moreno, C. C. Carbon. 2006, 44, 2301-2307.
https://doi.org/10.1016/j.carbon.2006.02.021

[31]. Barret, E. P.; Joyner, L. G.; Halenda, P. P. J. Am. Chem. Soc. 1951, 73, 373-380.
https://doi.org/10.1021/ja01145a126

[32]. Dubinin, M.; Astakhov, V. A. Bull. Acad. Sci. USSR, Div. Chem. Sci. 1971, 20, 3-7.
https://doi.org/10.1007/BF00849307

[33]. Ravikovitch, P. I.; Neimark, A. V. Langmuir. 2006, 22, 11171-11179.
https://doi.org/10.1021/la0616146

[34]. Neimark, A. V.; Lin, Y.; Ravikovitch, P. I.; Thommes, M. Carbon. 1998, 36, 469-1474.

[35]. Ravikovitch, P. I.; Vishnyakov, A.; Russo, R.; Neimark, A. V. Langmuir. 2000, 16(5), 2311-2320.
https://doi.org/10.1021/la991011c

[36]. Neimark, A. V.; Ravikovitch, P. I.; Vishnyakov, A. J. Phys: Condens. Matter. 2003, 15, 347-365.
https://doi.org/10.1088/0953-8984/15/3/303

[37]. Fonseca-Correa, R. A.; Giraldo, L.; Moreno-Piraján, J. C. Microporous Mesoporous Mater. 2017, 248, 164-172.
https://doi.org/10.1016/j.micromeso.2017.04.037

[38]. Brunauer, S.; Emmett, P. H. J. Am. Chem. Soc. 1935, 57, 1754-1755.
https://doi.org/10.1021/ja01312a503

[39]. Brunauer, S.; Emmett, P. H. J. Am. Chem. Soc. 1937, 59, 2682- 2689.
https://doi.org/10.1021/ja01291a060

[40]. Brunauer, S.; Emmett, P. H.; Teller, E. J. Am. Chem. Soc. 1938, 60, 309-319.
https://doi.org/10.1021/ja01269a023

[41]. Brunauer, S.; Deming, L. S.; Deming, W. E. Teller, E. J. Am. Chem. Soc. 1940, 62, 1723-1732.
https://doi.org/10.1021/ja01864a025

[42]. Vargas, D. D. P.; Giraldo, L.; Moreno, P. J. C. Eur. J. Chem. 2017, 8(2), 130-136
https://doi.org/10.5155/eurjchem.8.2.130-136.1555

[43]. Elrazek, H. J. A.; Abd, E. D. R.; Rashad, A. M.; Elazab, W.; Fathy, A. H. Eur. J. Chem. 2015, 6(4), 488-492
https://doi.org/10.5155/eurjchem.6.4.488-492.1340

[44]. Dubinin, J. M. M. Prog. Surf. Membr. Sci. 1975, 9, 1-70
https://doi.org/10.1016/B978-0-12-571809-7.50006-1

[45]. Thommes, M.; Cychosz, K. A.; Neimark, A. V. Novel carbon adsorbents, 1st edition, Elsevier, 2012.

[46]. Thommes, M.; Kaneko, K.; Neimark, A. V.; Olivier, J. P.; Rodriguez, R. F.; Rouquerol, J.; Sing, K. S. W. Pure Appl. Chem. 2015, 87, 1051-1069.
https://doi.org/10.1515/pac-2014-1117


How to cite


Fonseca-Correa, R.; Bastidas-Barranco, M.; Giraldo, L.; Moreno-Piraján, J. Eur. J. Chem. 2017, 8(3), 279-287. doi:10.5155/eurjchem.8.3.279-287.1593
Fonseca-Correa, R.; Bastidas-Barranco, M.; Giraldo, L.; Moreno-Piraján, J. Carbon Aerogels: a study with different models of the effect resorcinol/catalyst at different ratios after pyrolysis and the effect on textural properties. Eur. J. Chem. 2017, 8(3), 279-287. doi:10.5155/eurjchem.8.3.279-287.1593
Fonseca-Correa, R., Bastidas-Barranco, M., Giraldo, L., & Moreno-Piraján, J. (2017). Carbon Aerogels: a study with different models of the effect resorcinol/catalyst at different ratios after pyrolysis and the effect on textural properties. European Journal of Chemistry, 8(3), 279-287. doi:10.5155/eurjchem.8.3.279-287.1593
Fonseca-Correa, Rafael, Marlon Jose Bastidas-Barranco, Liliana Giraldo, & Juan Carlos Moreno-Piraján. "Carbon Aerogels: a study with different models of the effect resorcinol/catalyst at different ratios after pyrolysis and the effect on textural properties." European Journal of Chemistry [Online], 8.3 (2017): 279-287. Web. 10 May. 2021
Fonseca-Correa, Rafael, Bastidas-Barranco, Marlon, Giraldo, Liliana, AND Moreno-Piraján, Juan. "Carbon Aerogels: a study with different models of the effect resorcinol/catalyst at different ratios after pyrolysis and the effect on textural properties" European Journal of Chemistry [Online], Volume 8 Number 3 (30 September 2017)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.8.3.279-287.1593

CrossRef | Scilit | GrowKudos | Researchgate | Publons | Microsoft | scibey | Scite | Lens | OUCI

WorldCat Paperbuzz Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2017, 8(3), 279-287 | doi: https://doi.org/10.5155/eurjchem.8.3.279-287.1593 | Get rights and content

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c)




© Copyright 2010 - 2021 • Atlanta Publishing House LLC • All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2021 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.