Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid  under solvent-free grinding technique

Sainath Zangade; Shyam Mokle; Avinash Shinde; Yeshwant Vibhute

doi:10.5155/eurjchem.3.3.314-315.641

European Journal of Chemistry 2012, 3(3), 314-315 | doi: https://doi.org/10.5155/eurjchem.3.3.314-315.641 | Get rights and content

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Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique

Sainath Zangade ^(1,*)

, Shyam Mokle ⁽²⁾

, Avinash Shinde ⁽³⁾

, Yeshwant Vibhute ⁽⁴⁾

⁽¹⁾ Department of Chemistry, Madhavrao Patil Mahavidyalaya, Palam, Prabhani, Maharashtra, 431720, India
⁽²⁾ Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
⁽³⁾ Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
⁽⁴⁾ Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
^(*) Corresponding Author

Received: 27 May 2012 | Accepted: 02 Jun 2012 | Published: 30 Sep 2012 | Issue Date: September 2012

Abstract

Selective electrophilic iodination of 2-acetyl-1-naphthol was achieved using iodine and iodic acid in combination with grinding at room temperature under solvent-free conditions to yield 1-(1-hydroxy-4-iodo-naphthalen-2-yl)-ethanone. Grinding mode of reactions has not only of interest from economical point of view, in many cases they also offer considerable advantages in terms of yield, mild reaction conditions, selectivity and simplicity of reaction procedure.

3_3_314_315_800

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Editor-in-Chief

European Journal of Chemistry

Keywords

Iodine; Iodic acid; Solvent-free; Grinding technique; Selective iodination; 2-Acetyl-1-naphthol

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DOI: 10.5155/eurjchem.3.3.314-315.641

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Funding information

University Grant Commission (UGC), (No. 38-267/2009), New Delhi, India

Citations

[1]. Sainath B. Zangade, Shyam S. Mokle, Avinash T. Shinde, Yeshwant B. Vibhute
An atom efficient, green synthesis of 2-pyrazoline derivatives under solvent-free conditions using grinding technique
Green Chemistry Letters and Reviews 6(2), 123, 2013
DOI: 10.1080/17518253.2012.713123

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How to cite

Zangade, S.; Mokle, S.; Shinde, A.; Vibhute, Y. Eur. J. Chem. 2012, 3(3), 314-315. doi:10.5155/eurjchem.3.3.314-315.641

Zangade, S.; Mokle, S.; Shinde, A.; Vibhute, Y. Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique. Eur. J. Chem. 2012, 3(3), 314-315. doi:10.5155/eurjchem.3.3.314-315.641

Zangade, S., Mokle, S., Shinde, A., & Vibhute, Y. (2012). Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique. European Journal of Chemistry, 3(3), 314-315. doi:10.5155/eurjchem.3.3.314-315.641

Zangade, Sainath, Shyam Mokle, Avinash Shinde, & Yeshwant Vibhute. "Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique." European Journal of Chemistry [Online], 3.3 (2012): 314-315. Web. 9 Aug. 2022

Zangade, Sainath, Mokle, Shyam, Shinde, Avinash, AND Vibhute, Yeshwant. "Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique" European Journal of Chemistry [Online], Volume 3 Number 3 (30 September 2012)

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DOI Link: https://doi.org/10.5155/eurjchem.3.3.314-315.641

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