Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
RESEARCH ARTICLE
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique
Sainath Zangade (1,*)
, Shyam Mokle (2) , Avinash Shinde (3) , Yeshwant Vibhute (4) (1) Department of Chemistry, Madhavrao Patil Mahavidyalaya, Palam, Prabhani, Maharashtra, 431720, India
(2) Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
(3) Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
(4) Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
(*) Corresponding Author
Received: 27 May 2012 | Accepted: 02 Jun 2012 | Published: 30 Sep 2012 | Issue Date: September 2012
Abstract
Selective electrophilic iodination of 2-acetyl-1-naphthol was achieved using iodine and iodic acid in combination with grinding at room temperature under solvent-free conditions to yield 1-(1-hydroxy-4-iodo-naphthalen-2-yl)-ethanone. Grinding mode of reactions has not only of interest from economical point of view, in many cases they also offer considerable advantages in terms of yield, mild reaction conditions, selectivity and simplicity of reaction procedure.
Keywords
DOI: 10.5155/eurjchem.3.3.314-315.641
Links for Article
| | | | |
| | | | | | |
Related Articles
Article Metrics
This Abstract was viewed 959 times |
PDF Article downloaded 280 times
Funding information
University Grant Commission (UGC), (No. 38-267/2009), New Delhi, India
Citations
[1]. Sainath B. Zangade, Shyam S. Mokle, Avinash T. Shinde, Yeshwant B. Vibhute
An atom efficient, green synthesis of 2-pyrazoline derivatives under solvent-free conditions using grinding technique
Green Chemistry Letters and Reviews 6(2), 123, 2013
DOI: 10.1080/17518253.2012.713123
References
[1]. Diederich, F.; Stang, P. J. Metal-Catalyzed Cross Coupling Reactions; Wiley-VCH: Weinheim, Germany, 1998.
http://dx.doi.org/10.1002/9783527612222
[2]. Seevers, R. H.; Counsell, R. Chem. Rev. 1982, 82, 575-590.
http://dx.doi.org/10.1021/cr00052a002
[3]. Alonso, F.; Beletskaya, I. P.; Yus, M. Chem. Rev. 2002, 102, 4009-4092.
http://dx.doi.org/10.1021/cr0102967
PMid:12428984
[4]. Olivera, R.; San Martin, R.; Dominguez, E. Tetrahedron Lett. 2000, 41, 4357-4360.
http://dx.doi.org/10.1016/S0040-4039(00)00622-5
[5]. Noda, Y.; Kashima, M. Tetrahedron Lett. 1997, 38, 6225-6228.
http://dx.doi.org/10.1016/S0040-4039(97)01431-7
[6]. Zupan, M.; Iskra, J.; Stavber, S. Tetahedron Lett. 1997, 38, 6305-6306.
http://dx.doi.org/10.1016/S0040-4039(97)01414-7
[7]. Carreno, M. C.; Ruano, J. G.; Sanz, G.; Toledo, M. A.; Urbano, A. Tetrahedron Lett. 1996, 37, 4081-4084.
http://dx.doi.org/10.1016/0040-4039(96)00738-1
[8]. Akhlaghinia, B.; Rahmani, M. J. Turk. Chem. 2009, 33, 67-72.
[9]. Orito, K.; Hatakeyama, T.; Takeo, M. Synthesis 1995, 1273-1277.
http://dx.doi.org/10.1055/s-1995-4089
[10]. Hubig, S. M.; Jung, W.; Kochi, J. K. J. Org. Chem. 1994, 59, 6233-6244.
http://dx.doi.org/10.1021/jo00100a025
[11]. Barluenga, J.; Gonzalez, J. M.; Garcia-Martin, M. A.; Campos, P. J.; Asensia, G. J. Org. Chem. 1993, 58, 2058-2060.
http://dx.doi.org/10.1021/jo00060a020
[12]. Olah, G. A.; Wang, D.; Sandford, G.; Prakash, G. K. S. J. Org. Chem. 1993, 58, 3194-3195.
http://dx.doi.org/10.1021/jo00063a052
[13]. Sy, W. W. Tetrahedron Lett. 1993, 34, 6223-6224.
http://dx.doi.org/10.1016/S0040-4039(00)73715-4
[14]. Bachki, A.; Foubelo, F.; Yus, M. Tetrahedron 1994, 50, 5139-5146.
http://dx.doi.org/10.1016/S0040-4020(01)90424-7
[15]. Edgar, K. J.; Falling, S. N. J. Org. Chem. 1990, 55, 5287-5291.
http://dx.doi.org/10.1021/jo00305a026
[16]. Zangade, S.; Mokle, S.; Chavan, S.; Vibhute, Y. Orbital Elec. J. Chem. 2011, 3, 144-149.
[17]. Zangade, S.; Shinde, A.; Patil, A.; Vibhute, Y. Eur. J. Chem. 2012, 3, 208-210.
http://dx.doi.org/10.5155/eurjchem.3.2.208-210.581
[18]. Zangade, S.; Shinde, A.; Vibhute, A.; Vibhute, Y. Pak. J. Chem. 2012, 2, 18-23.
[19]. Shinde, A. T.; Zangade, S. B.; Chavan, S. B.; Vibhute, A. Y.; Nalwar, Y. S.; Vibhute, Y. B. Synth. Commun. 2010, 40, 3506-3513.
http://dx.doi.org/10.1080/00397910903457332
[20]. Bose, A. K.; Pednekar, S.; Ganguly, S. N.; Chakraborty, G.; Manhas, M. S. Tetrahedron Lett. 2004, 45, 8351-8353.
http://dx.doi.org/10.1016/j.tetlet.2004.09.064
How to cite
DOI Link: https://doi.org/10.5155/eurjchem.3.3.314-315.641
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2012, 3(3), 314-315 | doi: https://doi.org/10.5155/eurjchem.3.3.314-315.641 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2019 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2019 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 4614 Lavista road, Tucker, GA, 30084, USA. Registered in USA.