European Journal of Chemistry 2012, 3(3), 314-315. doi:10.5155/eurjchem.3.3.314-315.641

Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique


Sainath Zangade (1,*) , Shyam Mokle (2) , Avinash Shinde (3) , Yeshwant Vibhute (4)

(1) Department of Chemistry, Madhavrao Patil Mahavidyalaya, Palam, Prabhani, Maharashtra, 431720, India
(2) Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
(3) Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
(4) Laboratory of Organic Synthesis, Department of Studies in Chemistry, Yeshwant Mahavidyalaya, Nanded, Maharashtra, 431602, India
(*) Corresponding Author

Received: 27 May 2012, Accepted: 02 Jun 2012, Published: 30 Sep 2012

Abstract


Selective electrophilic iodination of 2-acetyl-1-naphthol was achieved using iodine and iodic acid in combination with grinding at room temperature under solvent-free conditions to yield 1-(1-hydroxy-4-iodo-naphthalen-2-yl)-ethanone. Grinding mode of reactions has not only of interest from economical point of view, in many cases they also offer considerable advantages in terms of yield, mild reaction  conditions, selectivity and simplicity of reaction procedure.

3_3_314_315_800


Keywords


Iodine; Iodic acid; Solvent-free; Grinding technique; Selective iodination; 2-Acetyl-1-naphthol

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DOI: 10.5155/eurjchem.3.3.314-315.641

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[1]. Sainath B. Zangade, Shyam S. Mokle, Avinash T. Shinde, Yeshwant B. Vibhute
An atom efficient, green synthesis of 2-pyrazoline derivatives under solvent-free conditions using grinding technique
Green Chemistry Letters and Reviews  6(2), 123, 2013
DOI: 10.1080/17518253.2012.713123
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How to cite


Zangade, S.; Mokle, S.; Shinde, A.; Vibhute, Y. Eur. J. Chem. 2012, 3(3), 314-315. doi:10.5155/eurjchem.3.3.314-315.641
Zangade, S.; Mokle, S.; Shinde, A.; Vibhute, Y. Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique. Eur. J. Chem. 2012, 3(3), 314-315. doi:10.5155/eurjchem.3.3.314-315.641
Zangade, S., Mokle, S., Shinde, A., & Vibhute, Y. (2012). Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique. European Journal of Chemistry, 3(3), 314-315. doi:10.5155/eurjchem.3.3.314-315.641
Zangade, Sainath, Shyam Mokle, Avinash Shinde, & Yeshwant Vibhute. "Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique." European Journal of Chemistry [Online], 3.3 (2012): 314-315. Web. 18 Sep. 2019
Zangade, Sainath, Mokle, Shyam, Shinde, Avinash, AND Vibhute, Yeshwant. "Selective iodination of 2-acetyl-1-naphthol using iodine and iodic acid under solvent-free grinding technique" European Journal of Chemistry [Online], Volume 3 Number 3 (30 September 2012)

DOI Link: https://doi.org/10.5155/eurjchem.3.3.314-315.641

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