European Journal of Chemistry

Preparation of La0.7Ca0.3Mn0.95Fe0.05O3 perovskites by different methods: Catalytic activity towards the hydroxylation of benzene

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Published: Sep 30, 2013
DOI: https://doi.org/10.5155/eurjchem.4.3.272-276.772
Keywords:
XRD, SEM, Benzene, Perovskites, Hydroxylation, Catalytic activity
Section
Research Article
Issue
Vol. 4 No. 3 (2013): September 2013
Dates
Received 2013-03-16
Accepted 2013-06-08
Published 2013-09-30


Main Article Content

Ahmed Imam Hanafy
Chemistry Department, Faculty of Science, Al-Azhar University, Nasr City, 11884, Cairo, Egypt
Ibraheem Othman Ali
Chemistry Department, Faculty of Science, Al-Azhar University, Nasr City, 11884, Cairo, Egypt
Zeinhom Mohamed El-Bahy
Chemistry Department, Faculty of Science, Taif University, 21985, Taif, Saudi Arabia
Khaled Hussein Mahmoud
Physics Department, Faculty of Science, Taif University, Taif, 21985, Saudi Arabia

Abstract

Nanoparticles of the La0.7Ca0.3Mn0.95Fe0.05O3 perovskites were synthesized by various wet chemical routes, namely, co-precipitation, oxalate-gel and citrate-gel methods. Phase formation and crystal structure of the synthesized powders were examined by the X-ray diffraction (XRD). The morphology was evaluated by the scan electron microscopy (SEM). Infrared transmission spectroscopy revealed that stretching and bending modes were influenced by the preparation methods. The citrate gel method yielded better powder properties. The prepared perovskite samples were used in the oxidation of benzene. The highest activity for the catalytic oxidation of benzene to phenol in presence of hydrogen peroxide (H2O2) was obtained with the citrate-gel prepared sample.

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Hanafy, A. I.; Ali, I. O.; El-Bahy, Z. M.; Mahmoud, K. H. Preparation of La0.7Ca0.3Mn0.95Fe0.05O3 Perovskites by Different Methods: Catalytic Activity towards the Hydroxylation of Benzene. Eur. J. Chem. 2013, 4, 272-276.

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References

[1]. Ahn, K. H.; Wu, X. W.; Liu, K.; Chien, C. L. Phys. Rev. B 1996, 54, 15299-15302.
http://dx.doi.org/10.1103/PhysRevB.54.15299

[2]. Canulescu, S.; Lippert, T. H.; Wokaun, A.; Robert, R.; Logvinovich, D.; Weidenkaff, A.; Dobeli, M.; Schneider, M. Prog. Sol. Stat. Chem. 2007, 35, 241-248.
http://dx.doi.org/10.1016/j.progsolidstchem.2007.01.023

[3]. Ziese, M.; Semmelhack, H. C.; Han, K. H.; Sena, S. P.; Blythe, H. J. J. Appl. Phys. 2002, 91, 9930-9937.

[4]. Zener, C. Phys. Rev. 1951, 82, 403-405.
http://dx.doi.org/10.1103/PhysRev.82.403

[5]. Zhang, H. M.; Teraoka, Y.; Yamazoe, N. Chem. Lett. 1987, 16, 665-668.
http://dx.doi.org/10.1246/cl.1987.665

[6]. Arai, H.; Yamada, T.; Eguchi, K.; Seiyama, T. Appl. Catal. 1986, 26, 265-276.
http://dx.doi.org/10.1016/S0166-9834(00)82556-7

[7]. Seiyama, T.; Tejuka, L. G.; Fierro, J. I. G. (Eds.), Properties and Applications of Perovskite-type Oxides, Marcel-Dekker, NY, 1993, pp. 215.

[8]. Tejuka, L. G.; Fierro, J. L.; Tascon, J. M. D. Adv. Catal. 1989, 36, 237-248.
http://dx.doi.org/10.1016/S0360-0564(08)60019-X

[9]. Voorhoeve, R. J. H.; Advanced Materials in Catalysis, Academic Press, NY, 1977, pp. 129.

[10]. Seiyama, T.; Yamazoe, N.; Eguchi, E.Ind. Eng. Chem. Prod. Res. Dev. 1985, 24, 19-27.
http://dx.doi.org/10.1021/i300017a005

[11]. Liang, J. J.; Weng, H. S. Ind. Eng. Chem. Res. 1993, 32, 2563-2572.
http://dx.doi.org/10.1021/ie00023a020

[12]. Busca, G.; Daturi, M.; Finocchio, E.; Lorenzelli, V.; Ramis, G.; Willey, R. J. Catal. Today 1997, 33, 239-249.
http://dx.doi.org/10.1016/S0920-5861(96)00112-5

[13]. Royer, S.; Berube, F.; Kaliaguine, S. Appl. Catal. A: Gen. 2005, 282, 273-284.
http://dx.doi.org/10.1016/j.apcata.2004.12.018

[14]. Alifanti, M.; Kirchnerova, J.; Delmon, B. Appl. Catal. A: Gen. 2003, 245, 232-243.
http://dx.doi.org/10.1016/S0926-860X(02)00644-0

[15]. Barnard, K. R.; Foger, K.; Turney, T. W.; Williams, R. D. J. Catal. 1990, 125, 265-275
http://dx.doi.org/10.1016/0021-9517(90)90302-Z

[16]. Bragg, W. H.; Bragg, W. L. Nature 1913, 91, 557-560.
http://dx.doi.org/10.1038/091557a0

[17]. Greenberg, A. E.; Clesceri, L. S.; Eaton, A. D. (Eds.), Standard Methods for the Examination of Water and Wastewater, 17thed., American Public Health Association (APHA), Washington, DC, 1989.

[18]. Tor, A.; Cengeloglu, Y.; Aydin, M. E.; Ersoz, M. J. Colloid Interface Sci. 2006, 300, 498-503.

[19]. Pecchi, G.; Campos, C.; Pena, O.; Cadus, L. E. J. Mol. Catal. A 2008, 282, 158-166.
http://dx.doi.org/10.1016/j.molcata.2007.12.022

[20]. Bashir, J.; Shaheen, R.; Siddique, M.; Azad, A. K.; Eriksen, J.; Rundlof, H. J. Physica B 2006, 385-386, 126-129.
http://dx.doi.org/10.1016/j.physb.2006.05.296

[21]. Bontempi, E.; Garzella, C.; Valetti, S.; Depero, L. E. J. Eur. Ceram. Soc. 2003, 23, 2135-2142.
http://dx.doi.org/10.1016/S0955-2219(03)00026-8

[22]. Rousseau, S.; Loridant, S.; Delichere, P.; Boreave, A.; Deloume, J. P.; Vernoux, P. Appl. Catal. B 2009, 88, 438-447.
http://dx.doi.org/10.1016/j.apcatb.2008.10.022

[23]. Kundaliya, D. C.; Vija, R.; Kulkarnia, R. G.; Tulapurkar, A. A.; Pinto, R.; Malik, S. K.; Yelon, W. B. J. Magn. Magn. Mater. 2003, 264, 62-69
http://dx.doi.org/10.1016/S0304-8853(03)00138-0

[24]. Liu, L.; Liu, B.; Dong, L.; Zhu, J.; Wan, H.; Sun, K.; Zhao, B.; Zhu, H.; Dong, L.; Chen, Y. Appl. Catal. B 2009, 90, 578-586.
http://dx.doi.org/10.1016/j.apcatb.2009.04.019

[25]. Yang, W. D.; Chang, Y. H.; Huang, S. H. J. Eur. Ceram. Soc. 2005, 25, 3611-3618.
http://dx.doi.org/10.1016/j.jeurceramsoc.2004.09.028

[26]. Nagabhushana, B. M.; Chakradhar, R. P. S.; Ramesh, K. P.; Prasad, V.; Shivakumara, C.; Chandrappa, G. T. Physica B 2008, 403, 3360-3364.
http://dx.doi.org/10.1016/j.physb.2008.04.047

[27]. Rostamnejadi, A.; Salamati, H.; Kameli, P.; Ahmadvand, H. J.Magn. Magn. Mater. 2009, 321, 3126-3131.
http://dx.doi.org/10.1016/j.jmmm.2009.05.035

[28]. Mars, P.; Krevelen, D. V. Chem. Eng. Sci. Suppl. 1954, 3, 41-59.
http://dx.doi.org/10.1016/S0009-2509(54)80005-4

[29]. Hammami, R.; Ben Aissa, S.; Batis, H. Appl. Catal. A 2009, 353, 145-153.
http://dx.doi.org/10.1016/j.apcata.2008.10.048

[30]. Chammingkwan, P.; Hoelderich, W. F.; Mongkhonsi, T.; Kanchanawanichakul, P. Appl. Catal. A 2009, 352, 1-9.
http://dx.doi.org/10.1016/j.apcata.2008.09.009

Supporting Agencies

Taif University Research Program (1-433-1694), Taif University, 21985, Taif, Saudi Arabia
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