

The oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV): A kinetic and mechanistic study
Jinhuan Shan (1,*)


(1) College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
(2) College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
(*) Corresponding Author
Received: 22 Nov 2013 | Revised: 02 Jan 2014 | Accepted: 04 Jan 2014 | Published: 30 Jun 2014 | Issue Date: June 2014
Abstract
The kinetics of oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV) (DPN) had been studied spectrophotometrically in alkaline medium in the temperature range of 293.2 to 313.2 K. The reaction rate showed first order dependence on DPN, 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol. It was found that the pseudo-first-order rate constant kobs increased with an increase in concentration of OH- and a decrease in concentration of IO4-. There was a positive salt effect and no free radicals were detected. A plausible mechanism is proposed and the rate equations derived from the mechanism can explain all the experimental observations.
Keywords
Full Text:
PDF

DOI: 10.5155/eurjchem.5.2.237-240.981
Links for Article
| | | | | | |
| | | | | | |
| | |
Related Articles
Article Metrics


Funding information
College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
References
[1]. Shan, J. H.; Li, Y.; Huo, S. H.; Yin, C. H. J. Chem. 2013, 2013, Article ID 627324.
[2]. Shan, J. H.; Li, Y. Eur. J. Chem. 2013, 4(3), 203-206.
http://dx.doi.org/10.5155/eurjchem.4.3.203-206.778
[3]. Shan, J. H.; Liu, Y. P.; Zhang, J. Y. Chinese J. Chem. 2011, 29(4), 639-642.
http://dx.doi.org/10.1002/cjoc.201190134
[4]. Shan, J. H.; Liu, Y. P.; Shen, H. X.; Zhang, J. Y.; Yang, Y. F. Int. J. Chem. 2011, 3(2), 111-116.
http://dx.doi.org/10.5539/ijc.v3n2p111
[5]. Naik, K. M.; Nandibewoor, S. T. Oxid. Commun. 2012, 35, 545-559.
[6]. Shan, J. H.; Wang, X. Q.; Zhao, N. Chinese J. Chem. 2010, 28(7), 1081-1084.
http://dx.doi.org/10.1002/cjoc.201090189
[7]. Ragunatharaddi, R. H.; Nagaraj, P. S.; Sharanappa, T. N. J. Phys. Org. Chem. 2009, 22(3), 234-240.
http://dx.doi.org/10.1002/poc.1460
[8]. Jayant, I. G.; Sanjeevaraddi, R. S.; Sharanappa, T. N. Catal. Sci. Technol. 2012, 2, 2549-2557.
http://dx.doi.org/10.1039/c2cy20336g
[9]. Shan, J. H.; Liu, H. M.; Huo, S. Y.; Fan, Y.; Shen, S. G. Trans. Met. Chem. 2006, 31, 999-1002.
http://dx.doi.org/10.1007/s11243-006-0099-9
[10]. Shan, J. H.; Shen, H. X.; Song, C. Y.; Wang, H. Y.; Wang, X. Q. Chem. J. Inter. 2009, 11(3),10
[11]. Shan, J. H.; Wei, H. Y.; Wang, L.; Liu, B. S.; Shen, S. G.; Sun, H. W. Indian J. Chem. 2001, 40(A), 865-869.
[12]. Shan, J. H.; Shen, H. X.; Wang, H. Y.; Wang, X. Q. Oxid. Commun. 2012, 35(3), 583-390.
[13]. Yang, C. Y.; Zhang, Z. J.; Wang, J. L. Microchim. Acta 2009, 167, 91-96.
http://dx.doi.org/10.1007/s00604-009-0223-6
[14]. Chandraiah, U.; Murthy, C. P.; Sushama, Indian J. Chem. 1989, 28(A), 162-164.
[15]. Murthy, C. P.; Sethuram, B.; Rao, T. N. Z. Phys. Chem. (Leipzig) 1986, 267, 1212-1218.
[16]. Mahesh, R. T.; Pol, P. D.; Nandibewoor, S. T. Monatsh. Chem. 2003, 134, 1341-1352.
http://dx.doi.org/10.1007/s00706-003-0608-x
[17]. Aveston, J. J. Chem. Soc. 1969, A, 273-275.
[18]. Crouthamel, C. E.; Meek, H. V.; Martin, D. S. J. Am. Chem. Soc. 1949, 71, 3031-3035
http://dx.doi.org/10.1021/ja01177a026
[19]. Crouthamel, C. E.; Hayes, A. M.; Martin, D. S. J. Am. Chem. Soc. 1951, 73, 82-87
http://dx.doi.org/10.1021/ja01145a030
[20]. Mukherjee, H. G.; Mandal, B.; De, S. Indian J. Chem. 1984, 23(A), 426-428.
[21]. Shan, J. H.; Liu, T. Y. Acta Chim. Sinica 1994, 52, 114.
[22]. Keerti, M. N.; Sharanappa, T. N. J. Sulfur. Chem. 2011, 32(2), 123-136.
http://dx.doi.org/10.1080/17415993.2011.554836
[23]. Feigl, F. Spot Tests in organic analysis, Elsevier Publishing Co., New York, NY, USA, 1956.
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.5.2.237-240.981

















European Journal of Chemistry 2014, 5(2), 237-240 | doi: https://doi.org/10.5155/eurjchem.5.2.237-240.981 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2021 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2021 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.