European Journal of Chemistry 2013, 4(2), 157-161 | doi: https://doi.org/10.5155/eurjchem.4.2.157-161.752 | Get rights and content






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Synthesis, characterization and catalytic activity of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes of 4-((3-formyl-4-hydroxyphenyl)diazenyl)-N-(4-methyloxazol-2-yl) benzenesulfonamide


Ahmed Imam Hanafy (1,*) , Ali Mostafa Ali Hassan (2) , Sayed Ahmed Shama (3) , Hamdy Khamees Thabet (4) , Hany Mohammad Zaky El-alfy (5)

(1) Chemistry Department, Faculty of Science, Taif University, 21985, Taif, Saudi Arabia
(2) Chemistry Department, Faculty of Science, Al-Azhar University, Nasr City, 11884, Cairo, Egypt
(3) Chemistry Department, Faculty of Science Benha University, 13518, Benha, Egypt
(4) Chemistry Department, Faculty of Science and Arts, Northern Border University, 91911, Rafha, Saudi Arabia
(5) Chemistry Department, Faculty of Science Benha University, 13518, Benha, Egypt
(*) Corresponding Author

Received: 17 Feb 2013 | Revised: 12 Mar 2013 | Accepted: 20 Mar 2013 | Published: 30 Jun 2013 | Issue Date: June 2013

Abstract


The sulfonamide derivative, 4-((3-formyl-4-hydroxyphenyl)diazenyl)-N-(4-methyloxazol-2-yl) benzenesulfonamide (FDMB), was synthesized and characterized. Additionally, its Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes were prepared and their structures were investigated by elemental analysis, thermal analysis and (IR, electronic and EPR) spectroscopy. The mode of binding indicates that the ligand binds to the metal ion through carbonyl oxygen and OH phenolic with displacement of its proton. The Co(II) complex was applied for the hydrolysis of nerve agent-like compound, bis-(p-nitrophenyl) phosphate (BNPP). The results showed a significant rate enhancement of 2.5 million fold with respect to the auto-hydrolysis of BNPP under the same conditions.

4_2_157_161

Keywords


EPR; Hydrolysis; Nitrophenol; Sulfonamide; Methyloxazol; Phosphoester

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DOI: 10.5155/eurjchem.4.2.157-161.752

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Taif University, 21985, Taif, Saudi Arabia

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[1]. J. R. Anacona, Gabriela Ortega
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DOI: 10.1080/15533174.2013.840793
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How to cite


Hanafy, A.; Hassan, A.; Shama, S.; Thabet, H.; El-alfy, H. Eur. J. Chem. 2013, 4(2), 157-161. doi:10.5155/eurjchem.4.2.157-161.752
Hanafy, A.; Hassan, A.; Shama, S.; Thabet, H.; El-alfy, H. Synthesis, characterization and catalytic activity of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes of 4-((3-formyl-4-hydroxyphenyl)diazenyl)-N-(4-methyloxazol-2-yl) benzenesulfonamide. Eur. J. Chem. 2013, 4(2), 157-161. doi:10.5155/eurjchem.4.2.157-161.752
Hanafy, A., Hassan, A., Shama, S., Thabet, H., & El-alfy, H. (2013). Synthesis, characterization and catalytic activity of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes of 4-((3-formyl-4-hydroxyphenyl)diazenyl)-N-(4-methyloxazol-2-yl) benzenesulfonamide. European Journal of Chemistry, 4(2), 157-161. doi:10.5155/eurjchem.4.2.157-161.752
Hanafy, Ahmed, Ali Mostafa Ali Hassan, Sayed Ahmed Shama, Hamdy Khamees Thabet, & Hany Mohammad Zaky El-alfy. "Synthesis, characterization and catalytic activity of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes of 4-((3-formyl-4-hydroxyphenyl)diazenyl)-N-(4-methyloxazol-2-yl) benzenesulfonamide." European Journal of Chemistry [Online], 4.2 (2013): 157-161. Web. 5 Dec. 2020
Hanafy, Ahmed, Hassan, Ali, Shama, Sayed, Thabet, Hamdy, AND El-alfy, Hany. "Synthesis, characterization and catalytic activity of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes of 4-((3-formyl-4-hydroxyphenyl)diazenyl)-N-(4-methyloxazol-2-yl) benzenesulfonamide" European Journal of Chemistry [Online], Volume 4 Number 2 (30 June 2013)

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DOI Link: https://doi.org/10.5155/eurjchem.4.2.157-161.752

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