European Journal of Chemistry

Glycerol-based SO3H-Carbon Catalyst: A green recyclable catalyst for the chemoselective synthesis of pentaerythritol diacetals

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Published: Sep 30, 2014
DOI: https://doi.org/10.5155/eurjchem.5.3.536-540.1028
Keywords:
Reusability, Chemoselectivity, Aromatic aldehydes, Pentaerythritol diacetals, Glycerol-based SO3H-carbon catalyst, Protection and deprotection of diacetals
Section
Short Communication
Issue
Vol. 5 No. 3 (2014): September 2014
Dates
Received 2014-02-03
Accepted 2014-03-20
Published 2014-09-30


Main Article Content

Chandrakala Ummadisetti
Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India
Badari Narayana Prasad Rachapudi
Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India
Lakshmi Anu Prabhavathi Devi Bethala
Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India

Abstract

Glycerol-based SO3H-functionalized carbon catalyst was demonstrated as an efficient and recyclable green catalyst for the chemoselective synthesis of pentaerythritol diacetals with aromatic aldehydes in the presence of ketones in excellent yields in toluene at 80 °C. In addition, the catalyst also has the capability for the deprotection of pentaerythritol diacetals in methanol at reflux temperature. The recovered catalyst without any pre-treatment was reused for 5 cycles without any deactivation and leaching into the reaction medium under optimum conditions.


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Ummadisetti, C.; Rachapudi, B. N. P.; Bethala, L. A. P. D. Glycerol-Based SO3H-Carbon Catalyst: A Green Recyclable Catalyst for the Chemoselective Synthesis of Pentaerythritol Diacetals. Eur. J. Chem. 2014, 5, 536-540.

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Supporting Agencies

Department of Science and Technology (DST), Government of India, New Delhi, India
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