European Journal of Chemistry 2014, 5(1), 167-170. doi:10.5155/eurjchem.5.1.167-170.917

SO3H-Carbon derived from glycerol: An efficient and recyclable catalyst for smooth and regioselective azidolysis of oxiranes in water


Vijay Manneganti (1) , Badari Narayana Prasad Rachapudi (2) , Lakshmi Anu Prabhavathi Devi Bethala (3,*)

(1) Centre for Lipid Research, CSIR Indian Institute of Chemical Technology, Hyderabad-500 007, India
(2) Centre for Lipid Research, CSIR Indian Institute of Chemical Technology, Hyderabad-500 007, India
(3) Centre for Lipid Research, CSIR Indian Institute of Chemical Technology, Hyderabad-500 007, India
(*) Corresponding Author

Received: 05 Sep 2013, Accepted: 02 Nov 2013, Published: 31 Mar 2014

Abstract


A series of β-hydroxyazides were effectively synthesized from the regioselective ring opening of oxiranes by azide anion in presence of glycerol-based sulfonic acid functionalized carbon as a novel reusable heterogeneous catalyst in H2O achieving good yields (80-98%). The workup procedure was simple, and the catalyst could be reused over five times without losing its catalytic activity and selectivity.


Keywords


Water; Oxiranes; Azidolysis; Sodium azide; Azidohydrins; Carbon acid catalyst

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DOI: 10.5155/eurjchem.5.1.167-170.917

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[2]. G. Sandhya Rani, Manneganti Vijay, Bethala L. A. Prabhavathi Devi
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[3]. Chandrakala Ummadisetti, Badari Narayana Prasad Rachapudi, Lakshmi Anu Prabhavathi Devi Bethala
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[5]. Siyi Zhang, Junqiao Li, Genzhong Ji, Xuezheng Liang
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How to cite


Manneganti, V.; Rachapudi, B.; Bethala, L. Eur. J. Chem. 2014, 5(1), 167-170. doi:10.5155/eurjchem.5.1.167-170.917
Manneganti, V.; Rachapudi, B.; Bethala, L. SO3H-Carbon derived from glycerol: An efficient and recyclable catalyst for smooth and regioselective azidolysis of oxiranes in water. Eur. J. Chem. 2014, 5(1), 167-170. doi:10.5155/eurjchem.5.1.167-170.917
Manneganti, V., Rachapudi, B., & Bethala, L. (2014). SO3H-Carbon derived from glycerol: An efficient and recyclable catalyst for smooth and regioselective azidolysis of oxiranes in water. European Journal of Chemistry, 5(1), 167-170. doi:10.5155/eurjchem.5.1.167-170.917
Manneganti, Vijay, Badari Narayana Prasad Rachapudi, & Lakshmi Anu Prabhavathi Devi Bethala. "SO3H-Carbon derived from glycerol: An efficient and recyclable catalyst for smooth and regioselective azidolysis of oxiranes in water." European Journal of Chemistry [Online], 5.1 (2014): 167-170. Web. 16 Sep. 2019
Manneganti, Vijay, Rachapudi, Badari, AND Bethala, Lakshmi. "SO3H-Carbon derived from glycerol: An efficient and recyclable catalyst for smooth and regioselective azidolysis of oxiranes in water" European Journal of Chemistry [Online], Volume 5 Number 1 (31 March 2014)

DOI Link: https://doi.org/10.5155/eurjchem.5.1.167-170.917

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