European Journal of Chemistry 2011, 2(4), 495-498 | doi: https://doi.org/10.5155/eurjchem.2.4.495-498.413 | Get rights and content






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An efficient synthesis of quinoxalines catalyzed by monoammonium salt of 12-tungstophosphoric acid


Vijayalakshmi Kunkuma (1) , Lakshmi Anu Prabhavathi Devi Bethala (2,*) , Yadagiri Bhongiri (3) , Badari Narayana Prasad Rachapudi (4) , Seetharamanjaneya Sai Prasad Potharaju (5)

(1) Centre for Lipid Research, Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500007, India
(2) Centre for Lipid Research, Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500007, India
(3) Centre for Lipid Research, Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500007, India
(4) Centre for Lipid Research, Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500007, India
(5) Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500007, India
(*) Corresponding Author

Received: 28 Feb 2011 | Revised: 03 May 2011 | Accepted: 03 May 2011 | Published: 31 Dec 2011 | Issue Date: December 2011

Abstract


Monoammonium salt of 12-tungstophosphoric acid [(NH4)H2PW12O40] catalyst was used for the synthesis of biologically important quinoxaline derivatives in excellent yields from various aromatic 1,2-dicarbonyl and 1,2-diamines. The methodology has the advantages of mild reaction conditions with simple workup procedure, even for the synthesis of quinoxaline derivatives from sterically hindered diamine.

2_4_495_498_800


Keywords


Quinoxalines; Benzil; 1,2-Phenylenediamines; 12-Tungstophosphoric acid; Heteropoly acids; Dichloroethane

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DOI: 10.5155/eurjchem.2.4.495-498.413

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Funding information


Council of Scientific and Industrial Research (CSIR), India

Citations

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[3]. Debasish Bandyopadhyay, Jessica Cruz, Liza D Morales, Hadi D Arman, Erica Cuate, Young S Lee, Bimal K Banik, Dae J Kim
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[4]. K. K. Durga Rao Viswanadham, Muktapuram Prathap Reddy, Pochampalli Sathyanarayana, Owk Ravi, Ruchir Kant, Surendar Reddy Bathula
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[6]. Joana A. Pereira, Ana M. Pessoa, M. Natália D.S. Cordeiro, Rúben Fernandes, Cristina Prudêncio, João Paulo Noronha, Mónica Vieira
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[8]. M. Esmaeilpour, A.R. Sardarian
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How to cite


Kunkuma, V.; Bethala, L.; Bhongiri, Y.; Rachapudi, B.; Potharaju, S. Eur. J. Chem. 2011, 2(4), 495-498. doi:10.5155/eurjchem.2.4.495-498.413
Kunkuma, V.; Bethala, L.; Bhongiri, Y.; Rachapudi, B.; Potharaju, S. An efficient synthesis of quinoxalines catalyzed by monoammonium salt of 12-tungstophosphoric acid. Eur. J. Chem. 2011, 2(4), 495-498. doi:10.5155/eurjchem.2.4.495-498.413
Kunkuma, V., Bethala, L., Bhongiri, Y., Rachapudi, B., & Potharaju, S. (2011). An efficient synthesis of quinoxalines catalyzed by monoammonium salt of 12-tungstophosphoric acid. European Journal of Chemistry, 2(4), 495-498. doi:10.5155/eurjchem.2.4.495-498.413
Kunkuma, Vijayalakshmi, Lakshmi Anu Prabhavathi Devi Bethala, Yadagiri Bhongiri, Badari Narayana Prasad Rachapudi, & Seetharamanjaneya Sai Prasad Potharaju. "An efficient synthesis of quinoxalines catalyzed by monoammonium salt of 12-tungstophosphoric acid." European Journal of Chemistry [Online], 2.4 (2011): 495-498. Web. 6 Jul. 2020
Kunkuma, Vijayalakshmi, Bethala, Lakshmi, Bhongiri, Yadagiri, Rachapudi, Badari, AND Potharaju, Seetharamanjaneya. "An efficient synthesis of quinoxalines catalyzed by monoammonium salt of 12-tungstophosphoric acid" European Journal of Chemistry [Online], Volume 2 Number 4 (31 December 2011)

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