European Journal of Chemistry 2014, 5(3), 536-540 | doi: https://doi.org/10.5155/eurjchem.5.3.536-540.1028 | Get rights and content






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Glycerol-based SO3H-Carbon Catalyst: A green recyclable catalyst for the chemoselective synthesis of pentaerythritol diacetals


Chandrakala Ummadisetti (1,*) , Badari Narayana Prasad Rachapudi (2) , Lakshmi Anu Prabhavathi Devi Bethala (3)

(1) Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India
(2) Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India
(3) Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India
(*) Corresponding Author

Received: 03 Feb 2014 | Revised: 20 Mar 2014 | Accepted: 20 Mar 2014 | Published: 30 Sep 2014 | Issue Date: September 2014

Abstract


Glycerol-based SO3H-functionalized carbon catalyst was demonstrated as an efficient and recyclable green catalyst for the chemoselective synthesis of pentaerythritol diacetals with aromatic aldehydes in the presence of ketones in excellent yields in toluene at 80 °C. In addition, the catalyst also has the capability for the deprotection of pentaerythritol diacetals in methanol at reflux temperature. The recovered catalyst without any pre-treatment was reused for 5 cycles without any deactivation and leaching into the reaction medium under optimum conditions.


Keywords


Reusability; Chemoselectivity; Aromatic aldehydes; Pentaerythritol diacetals; Glycerol-based SO3H-carbon catalyst; Protection and deprotection of diacetals

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DOI: 10.5155/eurjchem.5.3.536-540.1028

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Funding information


Department of Science and Technology (DST), Government of India, New Delhi, India

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How to cite


Ummadisetti, C.; Rachapudi, B.; Bethala, L. Eur. J. Chem. 2014, 5(3), 536-540. doi:10.5155/eurjchem.5.3.536-540.1028
Ummadisetti, C.; Rachapudi, B.; Bethala, L. Glycerol-based SO3H-Carbon Catalyst: A green recyclable catalyst for the chemoselective synthesis of pentaerythritol diacetals. Eur. J. Chem. 2014, 5(3), 536-540. doi:10.5155/eurjchem.5.3.536-540.1028
Ummadisetti, C., Rachapudi, B., & Bethala, L. (2014). Glycerol-based SO3H-Carbon Catalyst: A green recyclable catalyst for the chemoselective synthesis of pentaerythritol diacetals. European Journal of Chemistry, 5(3), 536-540. doi:10.5155/eurjchem.5.3.536-540.1028
Ummadisetti, Chandrakala, Badari Narayana Prasad Rachapudi, & Lakshmi Anu Prabhavathi Devi Bethala. "Glycerol-based SO3H-Carbon Catalyst: A green recyclable catalyst for the chemoselective synthesis of pentaerythritol diacetals." European Journal of Chemistry [Online], 5.3 (2014): 536-540. Web. 25 May. 2020
Ummadisetti, Chandrakala, Rachapudi, Badari, AND Bethala, Lakshmi. "Glycerol-based SO3H-Carbon Catalyst: A green recyclable catalyst for the chemoselective synthesis of pentaerythritol diacetals" European Journal of Chemistry [Online], Volume 5 Number 3 (30 September 2014)

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DOI Link: https://doi.org/10.5155/eurjchem.5.3.536-540.1028

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