European Journal of Chemistry 2020, 11(4), 334-341 | doi: https://doi.org/10.5155/eurjchem.11.4.334-341.2037 | Get rights and content

Issue cover




Crossmark

  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Imino-pyridyl and PPh3 mixed ligand complexes of Cu(I)X (X: I, Br, and Cl): Synthesis, structure, DFT and Hirshfeld surface studies


Jahangir Mondal (1) orcid , Amit Kumar Manna (2) orcid , Goutam Kumar Patra (3,*) orcid

(1) Department of Chemistry, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(2) Department of Chemistry, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(3) Department of Chemistry, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(*) Corresponding Author

Received: 30 Aug 2020 | Revised: 10 Oct 2020 | Accepted: 20 Oct 2020 | Published: 31 Dec 2020 | Issue Date: December 2020

Abstract


Three new halide bridged copper(I)complexes [Cu2(µ-L)(µ-X)2)(PPh3)2]n {X: I (1), Br (2) and Cl (3)} have been synthesized by the reaction of Cu(I)X (X: I, Br and Cl) with PPh3 and the polydentate imino-pyridyl ligand L. Interestingly, copper(I) forms coordination polymers with the ligand L and the co-ligand PPh3. These complexes 1, 2 and 3 have been characterized by elemental analysis, IR, UV-Vis, and NMR spectroscopy. The crystal structure of the complex 2 has been determined by single-crystal X-ray analysis. Crystal data for complex 2: triclinic, space group P-1 (no. 2), a = 9.471(10) Å, b = 11.043(11) Å, c = 13.215(18) Å, α = 65.853(18)°, β = 69.94(2)°, γ = 67.350(14)°, = 1135(2) Å3, Z = 2, T = 296.15 K, μ(MoKα) = 2.806 mm-1, Dcalc = 1.535 g/cm3, 4059 reflections measured (3.462° ≤ 2Θ ≤ 44.818°), 2639 unique (Rint = 0.0637, Rsigma = 0.1621) which were used in all calculations. The final R1 was 0.0700 (I > 2σ(I)) and wR2 was 0.2207 (all data). Hirshfeld surface analysis of the complex 2 showed H···H, N···H and Br···H interactions of 55.9, 14.4 and 4.1%, respectively. MEP of ligand L reflects the whole molecule is reddish yellow in color because of equally distributed electron density over the molecule. For this reason, the ligand is supramolecularly arranged via -{CuI2-µ-X2} rhomboid core in the complex 2. The ligand L is non-emissive at room temperature in dichloromethane, whereas the complexes 1, 2 and 3 are photoluminescent. DFT and Hirshfeld surface studies have also been performed for complex 2.


Announcements


One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and May 31, 2023 (Voucher code: SPONSOR2023).

Editor-in-Chief
European Journal of Chemistry

Keywords


DFT; Imino-pyridyl ligand; X-ray crystal structure; Hirshfeld surface studies; Bridged copper(I) complexes; Copper(I) coordination polymer

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.11.4.334-341.2037

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 672 times | icon graph PDF Article downloaded 307 times

Funding information


The Department of Science and Technology, (File Nos. SR/FST/CSI-264/2014 and EMR/2017/0001789), Government of India, New Delhi.

Citations

/


[1]. Nikita A. Shekhovtsov, Tatyana E. Kokina, Katerina A. Vinogradova, Andrey Y. Panarin, Marianna I. Rakhmanova, Dmitry Y. Naumov, Natalya V. Pervukhina, Elena B. Nikolaenkova, Viktor P. Krivopalov, Rafał Czerwieniec, Mark B. Bushuev
Near-infrared emitting copper(i) complexes with a pyrazolylpyrimidine ligand: exploring relaxation pathways
Dalton Transactions  51(7), 2898, 2022
DOI: 10.1039/D1DT04325K
/


References


[1]. Desiraju, G. R.; In Crystal Engineering: The Design of Organic Solids, Elsevier, Amsterdam, 1989.

[2]. Nangia, A. J. Chem. Sci. 2010, 122, 295-310.
https://doi.org/10.1007/s12039-010-0035-6

[3]. Moulton, B.; Zaworotko, M. J. J. Chem. Rev. 2001, 101, 1629-1658.
https://doi.org/10.1021/cr9900432

[4]. Zaworotko, M. J. Cryst. Growth Des. 2007, 7, 4-9.
https://doi.org/10.1021/cg0680172

[5]. Aakeroy, C. B.; Beatty, A. M.; Tremayne, M. D.; Rowe, M.; Seaton, C. Cryst. Growth Des. 2001, 1, 377-382.
https://doi.org/10.1021/cg015536q

[6]. Aakeroy, C. B.; Champness, N. R.; Janiak, C. Cryst. Eng. Comm. 2010, 12, 22-43.
https://doi.org/10.1039/B919819A

[7]. Kitaura, R.; Fujimoto, K.; Noro, S.; Kondo, M.; Kitagawa, S. Angew. Chem. 2002, 114, 141-143.
https://doi.org/10.1002/1521-3757(20020104)114:1<141::AID-ANGE141>3.0.CO;2-D

[8]. Habib, H. A.; Hoffmann, A.; Hoppe, H. A.; Steinfeld, G. Inorg. Chem. 2009, 48, 2166-2180.
https://doi.org/10.1021/ic802069k

[9]. Caballero, A. B.; Rodriguez-Dieguez, A.; Vieth, J. K.; Salas, J. M.; Janiak, C. Inorg. Chim. Acta 2011, 376, 674-678.
https://doi.org/10.1016/j.ica.2011.07.008

[10]. Smith, C. S.; Mann, K. R. Chem. Mater. 2009, 21, 5042-5049.
https://doi.org/10.1021/cm901109n

[11]. Sun, L. N.; Yu, J. B.; Peng, H. S.; Zhang, J. Z.; Shi, L. Y.; Wolfbeis, O. S. J. Phys. Chem. C 2010, 114, 12642-12648.
https://doi.org/10.1021/jp1028323

[12]. Wang, Y. M.; Teng, F.; Hou, Y. B.; Xu, Z.; Wang, Y. S.; Fu, W. F. Appl. Phys. Lett. 2005, 87, 233512-233515.
https://doi.org/10.1063/1.2139987

[13]. Tsuboyama, A.; Kuge, K.; Furugori, M.; Okada, S.; Hoshino, M.; Ueno, K. Inorg. Chem. 2007, 46, 1992-2001.
https://doi.org/10.1021/ic0608086

[14]. Wei, Z. W.; Sun, L. N.; Liu, J. L.; Zhang, J. Z.; Yang, H. R.; Yang, Y.; Shi, L. Y. Biomaterials 2014, 35, 387-392.
https://doi.org/10.1016/j.biomaterials.2013.09.110

[15]. Liu, Z.; Sun, L. N.; Li, F. Y.; Liu, Q.; Shi, L. Y.; Zhang, D. S.; Yuan, S.; Liu, T.; Qiu, Y. N. J. Mater. Chem. 2011, 21, 17615-17618.
https://doi.org/10.1039/c1jm13871e

[16]. Armaroli, N.; Accorsi, G.; Holler, M.; Moudam, O.; Nierengarten, J. F.; Zhou, Z.; Wegh, R.; Welter, R. T. Adv. Mater. 2006, 18, 1313-1316.
https://doi.org/10.1002/adma.200502365

[17]. Zhang, Q.; Zhou, Q.; Cheng, Y.; Wang, L.; Ma, D.; Jing, X.; Wang, F. Adv. Mater. 2004, 16, 432-436.
https://doi.org/10.1002/adma.200306414

[18]. Nishikawa, M.; Nomoto, K.; Kume, S.; Inoue, K.; Sakai, M.; Fuji, M.; Nishihara, H. J. J. Am. Chem. Soc. 2010, 13, 9579-9581.
https://doi.org/10.1021/ja103718e

[19]. McCormick, T.; Jia, W. L.; Wang, S. Inorg. Chem. 2006, 45, 147-155.
https://doi.org/10.1021/ic051412h

[20]. Cuttell, D. G.; Kuang, S. M.; Fanwick, P. E.; McMillin, D. R.; Walton, R. A.; J. Am. Chem. Soc. 2002, 124, 6-7.
https://doi.org/10.1021/ja012247h

[21]. Smith, C. S.; Branham, C. W.; Marquardt, B. J.; Mann, K. R. J. Am. Chem. Soc. 2010, 132, 14079-14085.
https://doi.org/10.1021/ja103112m

[22]. Mondal, J.; Mukherjee, A.; Patra, G. K.; Inorg. Chim. Acta 2017, 463, 44-53.
https://doi.org/10.1016/j.ica.2017.03.031

[23]. Mondal, J.; Pal, P. K.; Mukherjee, A.; Patra, G. K. Inorg. Chim. Acta 2017, 466, 274-284.
https://doi.org/10.1016/j.ica.2017.06.025

[24]. Ghorai, A.; Mondal, J.; Patra, G. K. J. Mol. Struct. 2015, 1097, 52-60.
https://doi.org/10.1016/j.molstruc.2015.05.010

[25]. Mondal, J.; Ghorai, A.; Singh, S. K.; Saha, R.; Patra, G. K. J. Mol. Struct. 2016, 1108, 315-324.
https://doi.org/10.1016/j.molstruc.2015.12.028

[26]. Hyde, S.; Andersson, S.; Larsson, K.; Blum, Z.; Landh, T.; Lidin, S.; Ninham, B. W. The Language of Shape, Elsevier, Amsterdam, 1997.

[27]. Spackman, M. A.; McKinnon, J. J. CrystEngComm 2002, 4, 378-392.
https://doi.org/10.1039/B203191B

[28]. McKinnon, J. J.; Fabbiani, F. P. A.; Spackman, M. A. Cryst. Growth Des. 2007, 7, 755-769.
https://doi.org/10.1021/cg060773k

[29]. Moggach, S. A.; Parsons S.; Wood, P. A. Crystallogr. Rev. 2008, 14, 143-184.
https://doi.org/10.1080/08893110802037945

[30]. Parkin, A.; Barr, G.; Dong, W.; Gilmore, C. J.; Jayatilaka, D.; McKinnon, J. J.; Spackman, M. A.; Wilson, C. C. CrystEngComm 2007, 9, 648-652.
https://doi.org/10.1039/b704177b

[31]. Barr, G.; Dong, W.; Gilmore, C. J.; Parkin, A.; Wilson, C. C. J. Appl. Crystallogr. 2005, 38, 833-841.
https://doi.org/10.1107/S0021889805021308

[32]. Clark, T. E.; Makha, M.; Sobolev, A. N.; Raston, C. L. Cryst. Growth Des. 2008, 8, 890-896.
https://doi.org/10.1021/cg070632y

[33]. Mukherjee, A.; Dutta, A.; Jana, A. D.; Patra, G. K. Inorg. Chim. Acta 2013, 404, 131-143.
https://doi.org/10.1016/j.ica.2013.04.012

[34]. Bruker, SMART, SAINT. Bruker AXS Inc., Madison, Wisconsin, USA, 2012.

[35]. G. M. Sheldrick, Acta Cryst. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

[36]. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837-838.
https://doi.org/10.1107/S0021889899006020

[37]. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheese-man, J. R.; Montgomery Jr. , J. A.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Strat-mann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W. , Ayala, P. Y.; Morokuma, K.; Voth, G.; Salvador, A. P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Ste-fanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; John-son, B.; Chen, W.; Wong, M. W.; Gonzalez, C. , Pople, J. A.; Gaussian 09W, Gaussian, Inc. , Wallingford, CT, 2009.

[38]. Dennington, R.; Keith, T. A.; Millam, J. M. GaussView, Version 5, Semichem Inc., Shawnee Mission, KS, 2009.

[39]. Norret, M.; Makha, M.; Sobolev, A. N.; Raston, C. L. New J. Chem. 2008, 32, 808-812.
https://doi.org/10.1039/b718937k

[40]. Meng, X. Applications of Hirshfeld surfaces to ionic and mineral crystals, PhD. Thesis, University of New England, 2004.

[41]. Pendas, A. M.; Luana, V.; Pueyo, L.; Francisco E.; Sanchez, P. M. J. Chem. Phys. 2002, 117, 1017-1023.
https://doi.org/10.1063/1.1483851

[42]. Desiraju, G. R. Angew. Chem. Int. Ed. 2007, 46, 8342-8356.
https://doi.org/10.1002/anie.200700534

[43]. Schmidt, G. M. J. Pure Appl. Chem. 1971, 27, 647-678.
https://doi.org/10.1351/pac197127040647

[44]. Sebastin, S.; Sundaraganesan, N. Spectrochim. Acta A 2010, 75, 941-952.
https://doi.org/10.1016/j.saa.2009.11.030


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Mondal, J.; Manna, A.; Patra, G. Eur. J. Chem. 2020, 11(4), 334-341. doi:10.5155/eurjchem.11.4.334-341.2037
Mondal, J.; Manna, A.; Patra, G. Imino-pyridyl and PPh3 mixed ligand complexes of Cu(I)X (X: I, Br, and Cl): Synthesis, structure, DFT and Hirshfeld surface studies. Eur. J. Chem. 2020, 11(4), 334-341. doi:10.5155/eurjchem.11.4.334-341.2037
Mondal, J., Manna, A., & Patra, G. (2020). Imino-pyridyl and PPh3 mixed ligand complexes of Cu(I)X (X: I, Br, and Cl): Synthesis, structure, DFT and Hirshfeld surface studies. European Journal of Chemistry, 11(4), 334-341. doi:10.5155/eurjchem.11.4.334-341.2037
Mondal, Jahangir, Amit Kumar Manna, & Goutam Kumar Patra. "Imino-pyridyl and PPh3 mixed ligand complexes of Cu(I)X (X: I, Br, and Cl): Synthesis, structure, DFT and Hirshfeld surface studies." European Journal of Chemistry [Online], 11.4 (2020): 334-341. Web. 28 May. 2023
Mondal, Jahangir, Manna, Amit, AND Patra, Goutam. "Imino-pyridyl and PPh3 mixed ligand complexes of Cu(I)X (X: I, Br, and Cl): Synthesis, structure, DFT and Hirshfeld surface studies" European Journal of Chemistry [Online], Volume 11 Number 4 (31 December 2020)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.11.4.334-341.2037


CrossRef | Scilit | GrowKudos | Researchgate | Publons | ScienceGate | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2020, 11(4), 334-341 | doi: https://doi.org/10.5155/eurjchem.11.4.334-341.2037 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c) 2020 Authors

Creative Commons License
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).



© Copyright 2010 - 2023  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.