European Journal of Chemistry

Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand

Article Sidebar

PDF CIF FILE
Published: Sep 30, 2021
DOI: https://doi.org/10.5155/eurjchem.12.3.248-255.2091
Keywords:
DFT, Ag(I) dimer, Photophysics, Imino-pyridyl ligand, X-ray crystal structure, Hirshfeld surface studies
Section
Research Article
Issue
Vol. 12 No. 3 (2021): September 2021
Dates
Received 2021-01-29
Accepted 2021-04-30
Published 2021-09-30
Crossmark


Main Article Content

Jahangir Mondal
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
https://orcid.org/0000-0001-9867-5193
Meman Sahu
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
https://orcid.org/0000-0001-9397-4805
Bhaskar Sharma
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
https://orcid.org/0000-0001-7944-4955
Rakesh Ganguly
Shiv Nadar University, Greater Noida, Gautam Buddha Nagar, Uttar Pradesh, 201314, India
https://orcid.org/0000-0002-9523-6918
Shubhamoy Chowdhury
Department of Chemistry, University of Gour Banga, Malda, West Bengal, 732103, India
https://orcid.org/0000-0003-1545-9693
Goutam Kumar Patra
Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
https://orcid.org/0000-0003-3151-0284

Abstract

The synthesis and characterization of an imino-pyridyl ligand N,N'-(butane-1,4-diyl)bis(1-(pyridin-2-yl)methanimine) (L) and its Ag(I)ClO4 complex (I) by various spectroscopic techniques and elemental analyses is presented in this study. X-ray single crystal structure of complex I revealed that in complex I, each Ag(I) ion is tetra coordinated with two pyridine N-atoms and two imine N-atoms of the ligand L, forming a macrocyclic dimeric Ag(I) grid. In the macrocyclic dimer complex I, Ag-Ag separation along the chain is 5.318 Å. The Ag-Npy average distance is 2.396 Å and that of the Ag-Nim is 2.257 Å. The macrocyclic dimer complex I is supramolecularly arranged by π-stacking interactions. Computational, Hirshfeld surface analysis and photophysical studies on ligand L and complex I have also been performed. Crystal data for C32H36Ag2Cl2N8O8 (M =947.33 g/mol): Triclinic, space group P-1 (no. 2), a = 9.1714(12) Å, b = 10.4373(14) Å, c = 10.8297(14) Å, α = 112.317(3)°, β = 91.391(3)°, γ = 92.353(3)°, V = 957.3(2) Å3, Z = 1, T = 293.15 K, μ(MoKα) = 1.220 mm-1, Dcalc = 1.643 g/cm3, 10248 reflections measured (4.07° ≤ 2Θ ≤ 53.098°), 3966 unique (Rint = 0.0280, Rsigma = 0.0331) which were used in all calculations. The final R1 was 0.0722 (I > 2σ(I)) and wR2 was 0.2229 (all data).


icon graph This Abstract was viewed 1043 times | icon graph Article PDF downloaded 422 times icon graph Article CIF FILE downloaded 0 times

How to Cite
(1)
Mondal, J.; Sahu, M.; Sharma, B.; Ganguly, R.; Chowdhury, S.; Patra, G. K. Synthesis, Crystal Structure, and Theoretical Studies of a Macrocyclic silver(I) Complex of Imino-Pyridyl Schiff Base Ligand. Eur. J. Chem. 2021, 12, 248-255.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Yamada, S. Coord. Chem. Rev.1999, 190-192, 537-555.
https://doi.org/10.1016/S0010-8545(99)00099-5

[2]. Wang, X.; Qin, C.; Wang, E.; Li, Y.; Hao, N.; Hu, C.; Xu, L. Inorg. Chem. 2004, 43 (6), 1850-1856.
https://doi.org/10.1021/ic035151s

[3]. Qin, C.; Wang, X.; Wang, E.; Xu, L. J. Mol. Struct. 2005, 738 (1-3), 91-98.
https://doi.org/10.1016/j.molstruc.2004.11.039

[4]. Wen, L.; Li, Y.; Dang, D.; Tian, Z.; Ni, Z.; Meng, Q. J. Solid State Chem. 2005, 178 (11), 3336-3341.
https://doi.org/10.1016/j.jssc.2005.07.035

[5]. Majumder, A.; Rosair, G. M.; Mallick, A.; Chattopadhyay, N.; Mitra, S. Polyhedron 2006, 25 (8), 1753-1762.
https://doi.org/10.1016/j.poly.2005.11.029

[6]. Muthu, S.; Ni, Z.; Vittal, J. J. Inorg. Chim. Acta 2005, 358 (3), 595-605.
https://doi.org/10.1016/j.ica.2004.09.038

[7]. Yue, S.-M.; Xu, H.-B.; Ma, J.-F.; Su, Z.-M.; Kan, Y.-H.; Zhang, H.-J. Polyhedron 2006, 25 (3), 635-644.
https://doi.org/10.1016/j.poly.2005.07.021

[8]. Carlucci, L.; Ciani, G.; Proserpio, D. M. Coord. Chem. Rev. 2003, 246 (1-2), 247-289.
https://doi.org/10.1016/S0010-8545(03)00126-7

[9]. Beauvais, L. G.; Long, J. R. Inorg. Chem. 2006, 45 (1), 236-243.
https://doi.org/10.1021/ic051087y

[10]. Chandler, B. D.; Cramb, D. T.; Shimizu, G. K. H. J. Am. Chem. Soc. 2006, 128 (32), 10403-10412.
https://doi.org/10.1021/ja060666e

[11]. Gu, Z.-G.; Fang, H.-C.; Yin, P.-Y.; Tong, L.; Ying, Y.; Hu, S.-J.; Li, W.-S.; Cai, Y.-P. Cryst. Growth Des. 2011, 11 (6), 2220-2227.
https://doi.org/10.1021/cg1015753

[12]. Dybtsev, D. N.; Chun, H.; Yoon, S. H.; Kim, D.; Kim, K. J. Am. Chem. Soc. 2004, 126 (1), 32-33.
https://doi.org/10.1021/ja038678c

[13]. Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Angew. Chem. Int. Ed Engl. 2004, 43 (12), 1466-1496.
https://doi.org/10.1002/anie.200300588

[14]. Lee, J.-Y.; Chen, C.-Y.; Lee, H. M.; Passaglia, E.; Vizza, F.; Oberhauser, W. Cryst. Growth Des. 2011, 11 (4), 1230-1237.
https://doi.org/10.1021/cg101453m

[15]. Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34 (4), 319-330.
https://doi.org/10.1021/ar000034b

[16]. Moulton, B.; Zaworotko, M. J. Chem. Rev. 2001, 101 (6), 1629-1658.
https://doi.org/10.1021/cr9900432

[17]. Janiak, C. Dalton Trans. 2003, 14, 2781-2804.
https://doi.org/10.1039/b305705b

[18]. Roesky, H. W.; Andruh, M. Coord. Chem. Rev. 2003, 236 (1-2), 91-119.
https://doi.org/10.1016/S0010-8545(02)00218-7

[19]. Luan, X.-J.; Wang, Y.-Y.; Li, D.-S.; Liu, P.; Hu, H.-M.; Shi, Q.-Z.; Peng, S.-M. Angew. Chem. Int. Ed Engl. 2005, 44 (25), 3864-3867.
https://doi.org/10.1002/anie.200500744

[20]. Ding, B.-B.; Weng, Y.-Q.; Mao, Z.-W.; Lam, C.-K.; Chen, X.-M.; Ye, B.-H. Inorg. Chem. 2005, 44 (24), 8836-8845.
https://doi.org/10.1021/ic051195k

[21]. Angeloni, A.; Crawford, P. C.; Orpen, A. G.; Podesta, T. J.; Shore, B. J. Chemistry 2004, 10 (15), 3783-3791.
https://doi.org/10.1002/chem.200400165

[22]. Balamurugan, V.; Hundal, M. S.; Mukherjee, R. Chemistry 2004, 10 (7), 1683-1690.
https://doi.org/10.1002/chem.200305701

[23]. Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98 (4), 1375-1406.
https://doi.org/10.1021/cr960091b

[24]. Janiak, C.; Scharmann, T. G. Polyhedron 2003, 22 (8), 1123-1133.
https://doi.org/10.1016/S0277-5387(03)00098-6

[25]. Pal, S.; Pal, S. Polyhedron 2003, 22 (6), 867-873.
https://doi.org/10.1016/S0277-5387(03)00008-1

[26]. Patra, G. K.; Pal, P. K.; Mondal, J.; Ghorai, A.; Mukherjee, A.; Saha, R.; Fun, H.-K. Inorg. Chim. Acta 2016, 447, 77-86.
https://doi.org/10.1016/j.ica.2016.03.032

[27]. Mondal, J.; Mukherjee, A.; Patra, G. K. Inorg. Chim. Acta 2017, 463, 44-53.
https://doi.org/10.1016/j.ica.2017.03.031

[28]. Mondal, J.; Pal, P. K.; Mukherjee, A.; Patra, G. K. Inorg. Chim. Acta 2017, 466, 274-284.
https://doi.org/10.1016/j.ica.2017.06.025

[29]. Bruker (2008). SAINT, SMART. Bruker AXS Inc., Madison, Wisconsin, USA.

[30]. Sheldrick, G. M. Acta Crystallogr. A 2008, 64 (1), 112-122.
https://doi.org/10.1107/S0108767307043930

[31]. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32 (4), 837-838.
https://doi.org/10.1107/S0021889899006020

[32]. Frisch, M. J.; Trucks G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; A. J. Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian, Inc. , Gaussian 09, Revision A. 02, Wallingford CT, 2009.

[33]. Dennington, R.; Keith, T.; Millam, J.; Gaussview. Version 5; Semichem Inc: Shawnee Mission, KS, 2009.

[34]. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82 (1), 299-310.
https://doi.org/10.1063/1.448975

[35]. Barone, V.; Cossi, M. J. Phys. Chem. A 1998, 102 (11), 1995-2001.
https://doi.org/10.1021/jp9716997

[36]. Tomasi, J.; Mennucci, B.; Cammi, R. Chem. Rev. 2005, 105 (8), 2999-3093.
https://doi.org/10.1021/cr9904009

[37]. Norret, M.; Makha, M.; Sobolev, A. N.; Raston, C. L. New J. Chem. 2008, 32 (5), 808-812.
https://doi.org/10.1039/b718937k

[38]. Spackman, M. A.; McKinnon, J. J. CrystEngComm 2002, 4 (66), 378-392.
https://doi.org/10.1039/B203191B

[39]. Meng, X. X. Applications of Hirshfeld surfaces to ionic and mineral crystals, Ph.D. Thesis, University of New England, 2004.

[40]. Pendás, A. M.; Luaña, V.; Pueyo, L.; Francisco, E.; Mori-Sánchez, P. J. Chem. Phys. 2002, 117 (3), 1017-1023.
https://doi.org/10.1063/1.1483851

[41]. Hyde, S.; Andersson, S.; Larsson, K.; Blum, Z.; Landh, T.; Lidin, S.; Ninham, B. W. The Language of Shape; Elsevier: Amsterdam, 1997.

[42]. Nishikawa, M.; Nomoto, K.; Kume, S.; Inoue, K.; Sakai, M.; Fujii, M.; Nishihara, H. J. Am. Chem. Soc. 2010, 132 (28), 9579-9581.
https://doi.org/10.1021/ja103718e

[43]. Desiraju, G. R. Angew. Chem. Int. Ed Engl. 2007, 46 (44), 8342-8356.
https://doi.org/10.1002/anie.200700534

[44]. Schmidt, G. M. J. Pure Appl. Chem. 1971, 27 (4), 647-678.
https://doi.org/10.1351/pac197127040647

[45]. Sebastian, S.; Sundaraganesan, N. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2010, 75 (3), 941-952.
https://doi.org/10.1016/j.saa.2009.11.030

[46]. Luque, F. J.; López, J. M.; Orozco, M. Theor. Chem. Acc. 2000, 103 (3-4), 343-345.
https://doi.org/10.1007/s002149900013

[47]. Bhattacharya, A.; Naskar, J. P.; Majumder, S.; Ganguly, R.; Mitra, P.; Chowdhury, S. Inorg. Chim. Acta 2015, 425, 124-133.
https://doi.org/10.1016/j.ica.2014.10.004

[48]. Sahu, M.; Manna, A. K.; Chowdhury, S.; Patra, G. K. RSC Adv. 2020, 10 (73), 44860-44875.
https://doi.org/10.1039/D0RA09023A

Supporting Agencies

Department of Science and Technology (SR/FST/CSI-264/2014 and EMR/ 2017/0001789) and Department of Biotechnology, Government of India, New Delhi, India.
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).