European Journal of Chemistry 2021, 12(3), 248-255 | doi: https://doi.org/10.5155/eurjchem.12.3.248-255.2091 | Get rights and content

Issue cover




Crossmark

  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand


Jahangir Mondal (1) orcid , Meman Sahu (2) orcid , Bhaskar Sharma (3) orcid , Rakesh Ganguly (4) orcid , Shubhamoy Chowdhury (5) orcid , Goutam Kumar Patra (6,*) orcid

(1) Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(2) Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(3) Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(4) Shiv Nadar University, Greater Noida, Gautam Buddha Nagar, Uttar Pradesh, 201314, India
(5) Department of Chemistry, University of Gour Banga, Malda, West Bengal, 732103, India
(6) Department of Chemistry, Faculty of Physical Sciences, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, 495009, India
(*) Corresponding Author

Received: 29 Jan 2021 | Revised: 14 Mar 2021 | Accepted: 30 Apr 2021 | Published: 30 Sep 2021 | Issue Date: September 2021

Abstract


The synthesis and characterization of an imino-pyridyl ligand N,N'-(butane-1,4-diyl)bis(1-(pyridin-2-yl)methanimine) (L) and its Ag(I)ClO4 complex (I) by various spectroscopic techniques and elemental analyses is presented in this study. X-ray single crystal structure of complex I revealed that in complex I, each Ag(I) ion is tetra coordinated with two pyridine N-atoms and two imine N-atoms of the ligand L, forming a macrocyclic dimeric Ag(I) grid. In the macrocyclic dimer complex I, Ag-Ag separation along the chain is 5.318 Å. The Ag-Npy average distance is 2.396 Å and that of the Ag-Nim is 2.257 Å. The macrocyclic dimer complex I is supramolecularly arranged by π-stacking interactions. Computational, Hirshfeld surface analysis and photophysical studies on ligand L and complex I have also been performed. Crystal data for C32H36Ag2Cl2N8O8 (M =947.33 g/mol): Triclinic, space group P-1 (no. 2), a = 9.1714(12) Å, b = 10.4373(14) Å, c = 10.8297(14) Å, α = 112.317(3)°, β = 91.391(3)°, γ = 92.353(3)°, V = 957.3(2) Å3, Z = 1, T = 293.15 K, μ(MoKα) = 1.220 mm-1, Dcalc = 1.643 g/cm3, 10248 reflections measured (4.07° ≤ 2Θ ≤ 53.098°), 3966 unique (Rint = 0.0280, Rsigma = 0.0331) which were used in all calculations. The final R1 was 0.0722 (I > 2σ(I)) and wR2 was 0.2229 (all data).


Announcements


One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and June 16, 2023 (Voucher code: SPONSOR2023).

Editor-in-Chief
European Journal of Chemistry

Keywords


DFT; Ag(I) dimer; Photophysics; Imino-pyridyl ligand; X-ray crystal structure; Hirshfeld surface studies

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.12.3.248-255.2091

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 608 times | icon graph PDF Article downloaded 145 times

Funding information


Department of Science and Technology (SR/FST/CSI-264/2014 and EMR/ 2017/0001789) and Department of Biotechnology, Government of India, New Delhi, India.

References


[1]. Yamada, S. Coord. Chem. Rev.1999, 190-192, 537-555.
https://doi.org/10.1016/S0010-8545(99)00099-5

[2]. Wang, X.; Qin, C.; Wang, E.; Li, Y.; Hao, N.; Hu, C.; Xu, L. Inorg. Chem. 2004, 43 (6), 1850-1856.
https://doi.org/10.1021/ic035151s

[3]. Qin, C.; Wang, X.; Wang, E.; Xu, L. J. Mol. Struct. 2005, 738 (1-3), 91-98.
https://doi.org/10.1016/j.molstruc.2004.11.039

[4]. Wen, L.; Li, Y.; Dang, D.; Tian, Z.; Ni, Z.; Meng, Q. J. Solid State Chem. 2005, 178 (11), 3336-3341.
https://doi.org/10.1016/j.jssc.2005.07.035

[5]. Majumder, A.; Rosair, G. M.; Mallick, A.; Chattopadhyay, N.; Mitra, S. Polyhedron 2006, 25 (8), 1753-1762.
https://doi.org/10.1016/j.poly.2005.11.029

[6]. Muthu, S.; Ni, Z.; Vittal, J. J. Inorg. Chim. Acta 2005, 358 (3), 595-605.
https://doi.org/10.1016/j.ica.2004.09.038

[7]. Yue, S.-M.; Xu, H.-B.; Ma, J.-F.; Su, Z.-M.; Kan, Y.-H.; Zhang, H.-J. Polyhedron 2006, 25 (3), 635-644.
https://doi.org/10.1016/j.poly.2005.07.021

[8]. Carlucci, L.; Ciani, G.; Proserpio, D. M. Coord. Chem. Rev. 2003, 246 (1-2), 247-289.
https://doi.org/10.1016/S0010-8545(03)00126-7

[9]. Beauvais, L. G.; Long, J. R. Inorg. Chem. 2006, 45 (1), 236-243.
https://doi.org/10.1021/ic051087y

[10]. Chandler, B. D.; Cramb, D. T.; Shimizu, G. K. H. J. Am. Chem. Soc. 2006, 128 (32), 10403-10412.
https://doi.org/10.1021/ja060666e

[11]. Gu, Z.-G.; Fang, H.-C.; Yin, P.-Y.; Tong, L.; Ying, Y.; Hu, S.-J.; Li, W.-S.; Cai, Y.-P. Cryst. Growth Des. 2011, 11 (6), 2220-2227.
https://doi.org/10.1021/cg1015753

[12]. Dybtsev, D. N.; Chun, H.; Yoon, S. H.; Kim, D.; Kim, K. J. Am. Chem. Soc. 2004, 126 (1), 32-33.
https://doi.org/10.1021/ja038678c

[13]. Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Angew. Chem. Int. Ed Engl. 2004, 43 (12), 1466-1496.
https://doi.org/10.1002/anie.200300588

[14]. Lee, J.-Y.; Chen, C.-Y.; Lee, H. M.; Passaglia, E.; Vizza, F.; Oberhauser, W. Cryst. Growth Des. 2011, 11 (4), 1230-1237.
https://doi.org/10.1021/cg101453m

[15]. Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34 (4), 319-330.
https://doi.org/10.1021/ar000034b

[16]. Moulton, B.; Zaworotko, M. J. Chem. Rev. 2001, 101 (6), 1629-1658.
https://doi.org/10.1021/cr9900432

[17]. Janiak, C. Dalton Trans. 2003, 14, 2781-2804.
https://doi.org/10.1039/b305705b

[18]. Roesky, H. W.; Andruh, M. Coord. Chem. Rev. 2003, 236 (1-2), 91-119.
https://doi.org/10.1016/S0010-8545(02)00218-7

[19]. Luan, X.-J.; Wang, Y.-Y.; Li, D.-S.; Liu, P.; Hu, H.-M.; Shi, Q.-Z.; Peng, S.-M. Angew. Chem. Int. Ed Engl. 2005, 44 (25), 3864-3867.
https://doi.org/10.1002/anie.200500744

[20]. Ding, B.-B.; Weng, Y.-Q.; Mao, Z.-W.; Lam, C.-K.; Chen, X.-M.; Ye, B.-H. Inorg. Chem. 2005, 44 (24), 8836-8845.
https://doi.org/10.1021/ic051195k

[21]. Angeloni, A.; Crawford, P. C.; Orpen, A. G.; Podesta, T. J.; Shore, B. J. Chemistry 2004, 10 (15), 3783-3791.
https://doi.org/10.1002/chem.200400165

[22]. Balamurugan, V.; Hundal, M. S.; Mukherjee, R. Chemistry 2004, 10 (7), 1683-1690.
https://doi.org/10.1002/chem.200305701

[23]. Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98 (4), 1375-1406.
https://doi.org/10.1021/cr960091b

[24]. Janiak, C.; Scharmann, T. G. Polyhedron 2003, 22 (8), 1123-1133.
https://doi.org/10.1016/S0277-5387(03)00098-6

[25]. Pal, S.; Pal, S. Polyhedron 2003, 22 (6), 867-873.
https://doi.org/10.1016/S0277-5387(03)00008-1

[26]. Patra, G. K.; Pal, P. K.; Mondal, J.; Ghorai, A.; Mukherjee, A.; Saha, R.; Fun, H.-K. Inorg. Chim. Acta 2016, 447, 77-86.
https://doi.org/10.1016/j.ica.2016.03.032

[27]. Mondal, J.; Mukherjee, A.; Patra, G. K. Inorg. Chim. Acta 2017, 463, 44-53.
https://doi.org/10.1016/j.ica.2017.03.031

[28]. Mondal, J.; Pal, P. K.; Mukherjee, A.; Patra, G. K. Inorg. Chim. Acta 2017, 466, 274-284.
https://doi.org/10.1016/j.ica.2017.06.025

[29]. Bruker (2008). SAINT, SMART. Bruker AXS Inc., Madison, Wisconsin, USA.

[30]. Sheldrick, G. M. Acta Crystallogr. A 2008, 64 (1), 112-122.
https://doi.org/10.1107/S0108767307043930

[31]. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32 (4), 837-838.
https://doi.org/10.1107/S0021889899006020

[32]. Frisch, M. J.; Trucks G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; A. J. Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian, Inc. , Gaussian 09, Revision A. 02, Wallingford CT, 2009.

[33]. Dennington, R.; Keith, T.; Millam, J.; Gaussview. Version 5; Semichem Inc: Shawnee Mission, KS, 2009.

[34]. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82 (1), 299-310.
https://doi.org/10.1063/1.448975

[35]. Barone, V.; Cossi, M. J. Phys. Chem. A 1998, 102 (11), 1995-2001.
https://doi.org/10.1021/jp9716997

[36]. Tomasi, J.; Mennucci, B.; Cammi, R. Chem. Rev. 2005, 105 (8), 2999-3093.
https://doi.org/10.1021/cr9904009

[37]. Norret, M.; Makha, M.; Sobolev, A. N.; Raston, C. L. New J. Chem. 2008, 32 (5), 808-812.
https://doi.org/10.1039/b718937k

[38]. Spackman, M. A.; McKinnon, J. J. CrystEngComm 2002, 4 (66), 378-392.
https://doi.org/10.1039/B203191B

[39]. Meng, X. X. Applications of Hirshfeld surfaces to ionic and mineral crystals, Ph.D. Thesis, University of New England, 2004.

[40]. Pendás, A. M.; Luaña, V.; Pueyo, L.; Francisco, E.; Mori-Sánchez, P. J. Chem. Phys. 2002, 117 (3), 1017-1023.
https://doi.org/10.1063/1.1483851

[41]. Hyde, S.; Andersson, S.; Larsson, K.; Blum, Z.; Landh, T.; Lidin, S.; Ninham, B. W. The Language of Shape; Elsevier: Amsterdam, 1997.

[42]. Nishikawa, M.; Nomoto, K.; Kume, S.; Inoue, K.; Sakai, M.; Fujii, M.; Nishihara, H. J. Am. Chem. Soc. 2010, 132 (28), 9579-9581.
https://doi.org/10.1021/ja103718e

[43]. Desiraju, G. R. Angew. Chem. Int. Ed Engl. 2007, 46 (44), 8342-8356.
https://doi.org/10.1002/anie.200700534

[44]. Schmidt, G. M. J. Pure Appl. Chem. 1971, 27 (4), 647-678.
https://doi.org/10.1351/pac197127040647

[45]. Sebastian, S.; Sundaraganesan, N. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2010, 75 (3), 941-952.
https://doi.org/10.1016/j.saa.2009.11.030

[46]. Luque, F. J.; López, J. M.; Orozco, M. Theor. Chem. Acc. 2000, 103 (3-4), 343-345.
https://doi.org/10.1007/s002149900013

[47]. Bhattacharya, A.; Naskar, J. P.; Majumder, S.; Ganguly, R.; Mitra, P.; Chowdhury, S. Inorg. Chim. Acta 2015, 425, 124-133.
https://doi.org/10.1016/j.ica.2014.10.004

[48]. Sahu, M.; Manna, A. K.; Chowdhury, S.; Patra, G. K. RSC Adv. 2020, 10 (73), 44860-44875.
https://doi.org/10.1039/D0RA09023A


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Mondal, J.; Sahu, M.; Sharma, B.; Ganguly, R.; Chowdhury, S.; Patra, G. Eur. J. Chem. 2021, 12(3), 248-255. doi:10.5155/eurjchem.12.3.248-255.2091
Mondal, J.; Sahu, M.; Sharma, B.; Ganguly, R.; Chowdhury, S.; Patra, G. Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand. Eur. J. Chem. 2021, 12(3), 248-255. doi:10.5155/eurjchem.12.3.248-255.2091
Mondal, J., Sahu, M., Sharma, B., Ganguly, R., Chowdhury, S., & Patra, G. (2021). Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand. European Journal of Chemistry, 12(3), 248-255. doi:10.5155/eurjchem.12.3.248-255.2091
Mondal, Jahangir, Meman Sahu, Bhaskar Sharma, Rakesh Ganguly, Shubhamoy Chowdhury, & Goutam Kumar Patra. "Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand." European Journal of Chemistry [Online], 12.3 (2021): 248-255. Web. 4 Jun. 2023
Mondal, Jahangir, Sahu, Meman, Sharma, Bhaskar, Ganguly, Rakesh, Chowdhury, Shubhamoy, AND Patra, Goutam. "Synthesis, crystal structure, and theoretical studies of a macrocyclic silver(I) complex of imino-pyridyl Schiff base ligand" European Journal of Chemistry [Online], Volume 12 Number 3 (30 September 2021)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.12.3.248-255.2091


CrossRef | Scilit | GrowKudos | Researchgate | Publons | ScienceGate | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2021, 12(3), 248-255 | doi: https://doi.org/10.5155/eurjchem.12.3.248-255.2091 | Get rights and content

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c) 2021 Authors

Creative Commons License
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).


© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.