European Journal of Chemistry 2021, 12(2), 187-191 | doi: https://doi.org/10.5155/eurjchem.12.2.187-191.2086 | Get rights and content

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X-ray crystal structure analysis of 5-bromospiro[indoline-3,7'-pyrano[3,2-C:5,6-C']dichromene]-2,6',8'-trione


Varun Sharma (1) orcid , Bubun Banerjee (2) orcid , Gurpreet Kaur (3) orcid , Vivek Kumar Gupta (4,*) orcid

(1) Department of Physics, University of Jammu, Jammu Tawi-180006, India
(2) Department of Chemistry, Indus International University, V.P.O Bathu, Distt. Una, Himachal Praesh- 174301, India
(3) Department of Chemistry, Indus International University, V.P.O Bathu, Distt. Una, Himachal Praesh- 174301, India
(4) Department of Physics, University of Jammu, Jammu Tawi-180006, India
(*) Corresponding Author

Received: 27 Jan 2021 | Revised: 27 Feb 2021 | Accepted: 07 Mar 2021 | Published: 30 Jun 2021 | Issue Date: June 2021

Abstract


An analog of spirooxindole[pyrano-bis-2H-l-benzopyran] derivatives namely 5-bromospiro [indoline-3,7'-pyrano[3,2-c:5,6-c']dichromene]-2,6',8'-trione was synthesized via one-pot pseudo three-component reaction of one equivalent of 5-bromoisatin and two equivalents of 4-hydroxycoumarin using mandelic acid as a naturally occurring organo catalyst in aqueous ethanol under reflux conditions. The synthesized compound was characterized by FT-IR, 1H NMR, 13C NMR, and HRMS data. Crystal structure was determined by using single X-ray crystallography technique. It was found that the crystals are triclinic with space group P-1, C108H60Br4N4O29S2: a = 11.8333(6) Å, b = 12.8151(6) Å, c = 17.1798(8) Å, α = 77.317(4)°, β = 74.147(4)°, γ = 66.493(5)°, = 2280.0(2) Å3, Z = 1, T = 149.99(10) K, μ(MoKα) = 1.902 mm-1, Dcalc = 1.647 g/cm3, 11545 reflections measured (3.836° ≤ 2Θ ≤ 50.998°), 8310 unique (Rint = 0.0488, Rsigma = 0.0875) which were used in all calculations. The final R1 was 0.0622 (I > 2σ(I)) and wR2 was 0.1994 (all data). The crystal structure was solved by direct methods and refined by full-matrix least-squares procedure to a final R-value of 0.0622 for 6264 observed reflections. The crystal structure was stabilized by an elaborate system of N-H···O, O-H···O, C-H···π, and π···π interactions involving solvent molecules to form supramolecular structure.


Keywords


Benzopyran; Spirooxindoles; Direct methods; Solvent molecules; Hydrogen bonding; X-ray crystallography

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DOI: 10.5155/eurjchem.12.2.187-191.2086

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Funding information


University of Jammu, Jammu, India, for financial support under Rashtriya Uchchatar Shiksha Abhiyan (RUSA) 2.0 Project. (Ref. No: RUSA/JU/ 2/2019-20/111/3588-3636).

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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Sharma, V.; Banerjee, B.; Kaur, G.; Gupta, V. Eur. J. Chem. 2021, 12(2), 187-191. doi:10.5155/eurjchem.12.2.187-191.2086
Sharma, V.; Banerjee, B.; Kaur, G.; Gupta, V. X-ray crystal structure analysis of 5-bromospiro[indoline-3,7'-pyrano[3,2-C:5,6-C']dichromene]-2,6',8'-trione. Eur. J. Chem. 2021, 12(2), 187-191. doi:10.5155/eurjchem.12.2.187-191.2086
Sharma, V., Banerjee, B., Kaur, G., & Gupta, V. (2021). X-ray crystal structure analysis of 5-bromospiro[indoline-3,7'-pyrano[3,2-C:5,6-C']dichromene]-2,6',8'-trione. European Journal of Chemistry, 12(2), 187-191. doi:10.5155/eurjchem.12.2.187-191.2086
Sharma, Varun, Bubun Banerjee, Gurpreet Kaur, & Vivek Kumar Gupta. "X-ray crystal structure analysis of 5-bromospiro[indoline-3,7'-pyrano[3,2-C:5,6-C']dichromene]-2,6',8'-trione." European Journal of Chemistry [Online], 12.2 (2021): 187-191. Web. 27 Oct. 2021
Sharma, Varun, Banerjee, Bubun, Kaur, Gurpreet, AND Gupta, Vivek. "X-ray crystal structure analysis of 5-bromospiro[indoline-3,7'-pyrano[3,2-C:5,6-C']dichromene]-2,6',8'-trione" European Journal of Chemistry [Online], Volume 12 Number 2 (30 June 2021)

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