European Journal of Chemistry 2022, 13(3), 253-258 | doi: | Get rights and content

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X-ray crystal structure analysis of N'-acetyl-N'-phenyl-2-naphthohydrazide

Varun Sharma (1) orcid , Indrajit Karmakar (2) orcid , Goutam Brahmachari (3) orcid , Vivek Kumar Gupta (4,*) orcid

(1) Department of Physics, University of Jammu, Jammu Tawi-180006, India
(2) Laboratory of Natural Products and Organic Synthesis, Department of Chemistry, Visva-Bharati (A Central University), Santiniketan-731235, West Bengal, India
(3) Laboratory of Natural Products and Organic Synthesis, Department of Chemistry, Visva-Bharati (A Central University), Santiniketan-731235, West Bengal, India
(4) Department of Physics, University of Jammu, Jammu Tawi-180006, India
(*) Corresponding Author

Received: 02 Mar 2022 | Revised: 29 Apr 2022 | Accepted: 11 May 2022 | Published: 30 Sep 2022 | Issue Date: September 2022


N'-Acetyl-N'-phenyl-2-naphthohydrazide, a biologically relevant organic molecule, was synthesized following a reported method and characterized based on its single X-ray crystallographic studies. The present manuscript deals with its detailed molecular interactions and X-ray crystal structure. Its space group is P-1 with the following unit cell parameters: a = 8.9164(7), b = 9.7058(9), c = 17.7384(12) Å, α = 88.308(7)°, β = 89.744(6)°, γ = 86.744(7)° and Z = 2. Crystal structure was solved by direct method and refined by full matrix least squares procedure to a final R value of 0.0580 and to a GOOF value of 1.066. The X-ray diffraction analyses showed that the asymmetric unit contains two crystallographically independent molecules. The crystal structure is stabilized by elaborate network of N-H···O and C-H···O hydrogen bonds along with C-H···π and π···π interactions to form supramolecular structures.


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European Journal of Chemistry


Disorder; Hydrazones; Single-crystal; X-ray diffraction; Hirshfeld surface; Hydrogen bonding

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DOI: 10.5155/eurjchem.13.3.253-258.2235

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Funding information

University of Jammu, Jammu, India, for financial support under the Rashtriya Uchchatar Shiksha Abhiyan (RUSA) 2.0 Project (Ref. No: RUSA/JU/2/2019-20/111/3588-3636).


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Supporting information

The Supplementary Material for this article can be found online at: Supplementary files

How to cite

Sharma, V.; Karmakar, I.; Brahmachari, G.; Gupta, V. Eur. J. Chem. 2022, 13(3), 253-258. doi:10.5155/eurjchem.13.3.253-258.2235
Sharma, V.; Karmakar, I.; Brahmachari, G.; Gupta, V. X-ray crystal structure analysis of N'-acetyl-N'-phenyl-2-naphthohydrazide. Eur. J. Chem. 2022, 13(3), 253-258. doi:10.5155/eurjchem.13.3.253-258.2235
Sharma, V., Karmakar, I., Brahmachari, G., & Gupta, V. (2022). X-ray crystal structure analysis of N'-acetyl-N'-phenyl-2-naphthohydrazide. European Journal of Chemistry, 13(3), 253-258. doi:10.5155/eurjchem.13.3.253-258.2235
Sharma, Varun, Indrajit Karmakar, Goutam Brahmachari, & Vivek Kumar Gupta. "X-ray crystal structure analysis of N'-acetyl-N'-phenyl-2-naphthohydrazide." European Journal of Chemistry [Online], 13.3 (2022): 253-258. Web. 30 May. 2023
Sharma, Varun, Karmakar, Indrajit, Brahmachari, Goutam, AND Gupta, Vivek. "X-ray crystal structure analysis of N'-acetyl-N'-phenyl-2-naphthohydrazide" European Journal of Chemistry [Online], Volume 13 Number 3 (30 September 2022)

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