European Journal of Chemistry

Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex



Main Article Content

Gun Binzet
Ulrich Flörke
Nevzat Külcü
Hakan Arslan

Abstract

We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C24H28Br2NiN4O2S2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P21/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)o and V = 2762.5(6) Å3.  In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.

3_1_37_39_800


icon graph This Abstract was viewed 2427 times | icon graph Article PDF downloaded 712 times icon graph Article CIF FILE downloaded 0 times

How to Cite
(1)
Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Crystal and Molecular Structure of bis(4-Bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) Complex. Eur. J. Chem. 2012, 3, 37-39.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt. A. J. Chem. Soc. Dalton Trans. 2000, 24, 4579-4585.
http://dx.doi.org/10.1039/b007589m

[2]. Sun, C.; Huang, H.; Feng, M.; Shi, X.; Zhang, X.; Zhou, P. Bioorg. Med. Chem. Lett. 2006, 16, 162-166.
http://dx.doi.org/10.1016/j.bmcl.2005.09.033

[3]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R. Eur. J. Chem. 2010, 1(3), 200-205.
http://dx.doi.org/10.5155/eurjchem.1.3.200-205.120

[4]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2010, 1(3), 221-227.
http://dx.doi.org/10.5155/eurjchem.1.3.221-227.124

[5]. Chow, A. W. U. S. Patent No. 4438135. Washington, D. C., USA: U. S. Patent and Trademark Office, 1984.

[6]. Zikan, V.; Sluka, J.; Daněk, J. CS Patent No. 8800122. Prague, Czechoslovakia: Czechoslovak Office for Trademarks and Inventions, 1988.

[7]. Ke, S. Y.; Xue, S. J. Arkivoc 2006, 10, 63-68.

[8]. Ramadas, K.; Suresh, G.; Janarthanan, N.; Masilamani, S. Pestic. Sci. 1998, 52, 145-151.
http://dx.doi.org/10.1002/(SICI)1096-9063(199802)52:2<145::AID-PS677>3.0.CO;2-J

[9]. Griffith, E. A. H.; Spofford III, W. A.; Amma, E. L. Inorg. Chem. 1978, 17, 1913-1917.
http://dx.doi.org/10.1021/ic50185a043

[10]. Sinscough, E. W.; Brodie, A. M. Coord. Chem. Rev. 1978, 27, 59-86.
http://dx.doi.org/10.1016/S0010-8545(00)80353-7

[11]. Doona, C. J; Stanbury, D. M. Inorg. Chem. 1996, 35, 3210-3216.
http://dx.doi.org/10.1021/ic9502077
PMid:11666519

[12]. Wilson, D.; DeLosAngeles, M.; Arada, S.; Alegret, M.; Del Valle, M. Hazard. J. Mater. 2010, 181, 140-146.
http://dx.doi.org/10.1016/j.jhazmat.2010.04.107
PMid:20510508

[13]. Mansuroglu, D. S.; Arslan, H.; VanDerveer, D.; Binzet G. Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(12), 3221-3230.
http://dx.doi.org/10.1080/10426500902979743

[14]. Arslan, H.; Flörke, U.; Külcü, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992

[15]. Mansuroglu, D. S.; Arslan, H.; Flörke, U.; Külcü, N. J. Coord. Chem. 2008, 61, 3134-3146.
http://dx.doi.org/10.1080/00958970802010567

[16]. Binzet, G.; Arslan, H.; Flörke, U.; Külcü, N. J. Coord. Chem. 2009, 62(21), 3454-3462.
http://dx.doi.org/10.1080/00958970903082200

[17]. Ugur, D.; Arslan, H.; Külcü, N. Russ. J. Coord. Chem. 2006, 32, 669-675.
http://dx.doi.org/10.1134/S1070328406090089

[18]. Avsar, G.; Arslan, H.; Haupt, H. J.; Külcü, N. Turk. J. Chem. 2003, 27, 281-285.

[19]. Arslan, H.; Flörke, U.; Külcü, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992

[20]. Arslan, H.; Külcü, N.; Flörke, U. Transit. Metal Chem. 2003, 28, 816-819.
http://dx.doi.org/10.1023/A:1026064232260

[21]. Arslan, H.; Flörke, U.; Külcü, N. J. Chem. Crystallogr. 2003, 33, 919-924.
http://dx.doi.org/10.1023/A:1027429814989

[22]. Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o452-o453.
http://dx.doi.org/10.1107/S1600536809003511
PMid:21582125 PMCid:2968555

[23]. Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o427-o428.
http://dx.doi.org/10.1107/S1600536809003183
PMid:21582014 PMCid:2968358

[24]. Yesilkaynak, T.; Binzet, G.; Emen, F. M.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2010, 1(1), 1-5.
http://dx.doi.org/10.5155/eurjchem.1.1.1-5.3

[25]. Avsar, G.;Kulcu, N.; Arslan, H. Turk. J. Chem. 2002, 26, 607-615.

[26]. Ozpozan, N.; Ozpozan, T.; Arslan, H.; Karipcin, F.; Külcü, N. Thermochim. Acta 1999, 336, 97-103.
http://dx.doi.org/10.1016/S0040-6031(99)00208-7

[27]. Ozpozan, N.; Arslan, H.; Ozpozan, T.; Merdivan, M.; Külcü, N. J. Therm. Anal. Calorim. 2000, 61, 955-965.
http://dx.doi.org/10.1023/A:1010171230450

[28]. Binzet, G.; Arslan, H.; Flörke, U.; Külcü, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395-1406.
http://dx.doi.org/10.1080/00958970500512633

[29]. Arslan, H.; Duran, N.; Borekci, G.; Ozer C. K.; Akbay, C. Molecules 2009, 14(1), 519-527.
http://dx.doi.org/10.3390/molecules14010519
PMid:19169199

[30]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
http://dx.doi.org/10.1107/S0108767307043930
PMid:18156677

[31]. Saeed, S.; Rashid, N.; Jones, P.; Hussain, R. Eur. J. Chem. 2011, 2(1), 77-82.
http://dx.doi.org/10.5155/eurjchem.2.1.77-82.183

[32]. Saeed, A.; Mumtaz, A.; Flörke, U. Eur. J. Chem. 2010, 1(2), 73-75.
http://dx.doi.org/10.5155/eurjchem.1.2.73-75.34

Supporting Agencies

Mersin University Research Fund, Mersin, Turkey (Project No, BAP-FBE-KB(GB)-2006-1).
Most read articles by the same author(s)

Most read articles by the same author(s)

1 2 3 4 5 6 7 8 9 10 > >> 
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).