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Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands


Ebru Keskin (1) orcid , Ummuhan Solmaz (2) orcid , Gun Binzet (3) orcid , Ilkay Gumus (4,*) orcid , Hakan Arslan (5) orcid

(1) Advanced Technology Research and Application Center, Mersin University, Mersin, TR-33343, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(3) Department of Chemistry, Faculty of Education, Mersin University, Mersin, TR-33343, Turkey
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(5) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(*) Corresponding Author

Received: 16 Jul 2018 | Revised: 12 Oct 2018 | Accepted: 15 Oct 2018 | Published: 31 Dec 2018 | Issue Date: December 2018

Abstract


Thiourea derivatives [N-(di-n-propylcarbamothioyl)-4-fluorobenzamide (HL1) and N-(di-n-propylcarbamothioyl)-4-bromobenzamide (HL2)] and their platinum complexes have been successfully synthesized and structurally characterized by spectroscopic 1H NMR, 13C NMR, COSY, HMQC, and FT-IR techniques. The structure of both complexes was also confirmed by single crystal X-ray diffraction studies. The study of X-ray single crystal diffraction shows that the supramolecular aggregation of the complexes is stabilized via weak interactions as well as stacking interactions such as C-H⋅⋅⋅π and π⋅⋅⋅π. The cis-[Pt(L1-S,O)2 showed C–H⋯π and π⋯π stacking interactions, whereas only C–H⋯π stacking interaction was observed in cis-[Pt(L2-S,O)2]. In addition, the strong classical and non-classical intermolecular hydrogen bonds are not found in the prepared complexes. Therefore, it can be said that the C–H⋯π and π⋯π stacking interactions play an important role in the formation of supramolecular structures of the complexes.


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European Journal of Chemistry

Keywords


Thiourea; Synthesis; Platinum complexes; Benzamide derivative; Supramolecular structure; Single crystal X‐ray diffraction

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DOI: 10.5155/eurjchem.9.4.360-368.1774

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Funding information


This work was supported by the Mersin University Research Fund [Project No: 2016-AP4-1426].

Citations

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[1]. Urage Zahra, Aamer Saeed, Tanzeela Abdul Fattah, Ulrich Flörke, Mauricio F. Erben
Recent trends in chemistry, structure, and various applications of 1-acyl-3-substituted thioureas: a detailed review
RSC Advances  12(20), 12710, 2022
DOI: 10.1039/D2RA01781D
/

[2]. Ummuhan Solmaz, Simay Ince, Mustafa Kemal Yilmaz, Hakan Arslan
Conversion of monodentate benzoylthiourea palladium(II) complex to bidentate coordination mode: Synthesis, crystal structure and catalytic activity in the Suzuki-Miyaura cross-coupling reaction
Journal of Organometallic Chemistry  973-974, 122374, 2022
DOI: 10.1016/j.jorganchem.2022.122374
/

[3]. U. Solmaz, E. Keskin, I. Gumus, P. K. Cevik, G. Binzet, H. Arslan
PLATINUM(II) COMPLEX CONTAINING N-(BIS (-2,4-DIMETHOXY-BENZYL)CARBAMOTHIOYL)- 4-METHYLBENZAMIDE LIGAND: SYNTHESIS, CRYSTAL STRUCTURE, HIRSHFELD SURFACE ANALYSIS, AND ANTIMICROBIAL ACTIVITY
Journal of Structural Chemistry  63(1), 62, 2022
DOI: 10.1134/S0022476622010073
/

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How to cite


Keskin, E.; Solmaz, U.; Binzet, G.; Gumus, I.; Arslan, H. Eur. J. Chem. 2018, 9(4), 360-368. doi:10.5155/eurjchem.9.4.360-368.1774
Keskin, E.; Solmaz, U.; Binzet, G.; Gumus, I.; Arslan, H. Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands. Eur. J. Chem. 2018, 9(4), 360-368. doi:10.5155/eurjchem.9.4.360-368.1774
Keskin, E., Solmaz, U., Binzet, G., Gumus, I., & Arslan, H. (2018). Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands. European Journal of Chemistry, 9(4), 360-368. doi:10.5155/eurjchem.9.4.360-368.1774
Keskin, Ebru, Ummuhan Solmaz, Gun Binzet, Ilkay Gumus, & Hakan Arslan. "Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands." European Journal of Chemistry [Online], 9.4 (2018): 360-368. Web. 6 Jul. 2022
Keskin, Ebru, Solmaz, Ummuhan, Binzet, Gun, Gumus, Ilkay, AND Arslan, Hakan. "Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands" European Journal of Chemistry [Online], Volume 9 Number 4 (31 December 2018)

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