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Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands
Ebru Keskin (1)
, Ummuhan Solmaz (2) , Gun Binzet (3) , Ilkay Gumus (4,*) , Hakan Arslan (5) (1) Advanced Technology Research and Application Center, Mersin University, Mersin, TR-33343, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(3) Department of Chemistry, Faculty of Education, Mersin University, Mersin, TR-33343, Turkey
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(5) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33343, Turkey
(*) Corresponding Author
Received: 16 Jul 2018 | Revised: 12 Oct 2018 | Accepted: 15 Oct 2018 | Published: 31 Dec 2018 | Issue Date: December 2018
Abstract
Thiourea derivatives [N-(di-n-propylcarbamothioyl)-4-fluorobenzamide (HL1) and N-(di-n-propylcarbamothioyl)-4-bromobenzamide (HL2)] and their platinum complexes have been successfully synthesized and structurally characterized by spectroscopic 1H NMR, 13C NMR, COSY, HMQC, and FT-IR techniques. The structure of both complexes was also confirmed by single crystal X-ray diffraction studies. The study of X-ray single crystal diffraction shows that the supramolecular aggregation of the complexes is stabilized via weak interactions as well as stacking interactions such as C-H⋅⋅⋅π and π⋅⋅⋅π. The cis-[Pt(L1-S,O)2 showed C–H⋯π and π⋯π stacking interactions, whereas only C–H⋯π stacking interaction was observed in cis-[Pt(L2-S,O)2]. In addition, the strong classical and non-classical intermolecular hydrogen bonds are not found in the prepared complexes. Therefore, it can be said that the C–H⋯π and π⋯π stacking interactions play an important role in the formation of supramolecular structures of the complexes.
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DOI: 10.5155/eurjchem.9.4.360-368.1774
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This work was supported by the Mersin University Research Fund [Project No: 2016-AP4-1426].
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DOI Link: https://doi.org/10.5155/eurjchem.9.4.360-368.1774
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European Journal of Chemistry 2018, 9(4), 360-368 | doi: https://doi.org/10.5155/eurjchem.9.4.360-368.1774 | Get rights and content
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