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Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand
Ilkay Gumus (1,*)
, Cemal Koray Ozer (2) , Don Vanderveer (3) , Hakan Arslan (4) (1) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(3) Department of Chemistry, Clemson University, Clemson, SC 29634-0973, USA
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(*) Corresponding Author
Received: 29 Oct 2016 | Accepted: 28 Nov 2016 | Published: 31 Dec 2016 | Issue Date: December 2016
Abstract
Copper(II) complex, cis-[Cu(L-κ2S,O)2] of N-(di-n-propylcarbamothioyl)cyclohexane carboxamide ligands (HL) has been synthesized and structurally characterized by various spectroscopic techniques and single crystal X-ray diffraction crystallography. The cis-[Cu(L-κ2S,O)2], C28H50CuN4O2S2: Monoclinic, space group P21/n (no. 14), a = 10.025(2) Å, b = 21.724(4) Å, c = 14.848(3) Å, β = 100.60(3)°, Z = 4, Dcalc = 1.259 g/cm3, 22069 reflections measured (5.88° ≤ 2Θ ≤ 50.2°), 5639 unique (Rint = 0.0630, Rsigma = 0.0678) which were used in all calculations. The final R1 was 0.0488 (≥2σ(I)) and wR2 was 0.1277 (all data). Single crystal analysis revealed that a square-planar coordination geometry is formed around the copper atom by two sulphur and two oxygen atoms of the related ligand, which are in a cis configuration.
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DOI: 10.5155/eurjchem.7.4.416-420.1503
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Funding information
This study was supported by the Research Fund of Mersin University in Turkey with Project Number: BAP-SBE TB (CKÖ) 2007-1 YL.
Citations
[1]. Gun Binzet, Ersan Turunc, Ulrich Flörke, Nevzat Külcü, Hakan Arslan
Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide
Journal of Chemistry 2018, 1, 2018
DOI: 10.1155/2018/6108242
References
[1]. Neucki, E. Ber. Dtsch. Chem. Ges., 1873, 6, 598-600.
https://doi.org/10.1002/cber.187300601186
[2]. Hope G. A.; Woods, R.; Boyd, S. E.; Watling, K. Colloids Surf. A, 2004, 232, 129-137.
https://doi.org/10.1016/j.colsurfa.2003.10.011
[3]. Guang-yi, L.; Hong, Z.; Liu-yin, X.; Shuai, W.; Zheng-He, X.; Miner. Eng. 2011, 24, 817-824.
https://doi.org/10.1016/j.mineng.2011.01.009
[4]. Otazo-Sanchez, E.; Perez-Marin, L.; Estevez-Hernandez, O.; Rojas-Lima, S.; Alonso-Chamarro, J. J. Chem. Soc., Perkin Trans. 2001, 2, 2211-2218.
[5]. Wilson, D.; Arada, M. A.; Alegret, S.; DelValle, M.; J. Hazard. Mater. 2010, 181, 140-146.
https://doi.org/10.1016/j.jhazmat.2010.04.107
[6]. Daud, A. I.; Khairul, W. M.; Mohamed, Z. H.; KuBulat, K. J. Sulfur Chem. 2014, 35, 691-699.
https://doi.org/10.1080/17415993.2014.954248
[7]. Yuan, Y. F.; Wang, J. T.; Gimeno, M. C.; Laguna, A.; Jones, P. G. Inorg. Chim. Acta 2001, 324, 309-317.
https://doi.org/10.1016/S0020-1693(01)00661-2
[8]. Zhang, Y. M.; Wei, T. B.; Xian, L.; Gao, L. M. Phosphorus Sulfur Silicon Relat. Elem. 2004, 179, 2007-2013.
https://doi.org/10.1080/10426500490473456
[9]. Zhang, Y. M.; Wei, T. B.; Wang, X. C.; Yang, S. Y. Indian J. Chem. Sect B 1998, 37, 604-606.
[10]. Zhou, W. Q.; Li, B. L.; Zhu, L. M.; Ding, J. G.; Yong, Z.; Lu, L.; Yang, X. J. J. Mol. Struct. 2004, 690, 145-150.
https://doi.org/10.1016/j.theochem.2004.02.011
[11]. Henderson, W.; Nicholson, B. K.; Dinger, M. B.; Bennett, R.L. Inorg. Chim. Acta 2002, 338, 210-218.
https://doi.org/10.1016/S0020-1693(02)01017-4
[12]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt, A. J. Chem. Soc., Dalton Trans. 2000, 24, 4579-4586.
https://doi.org/10.1039/b007589m
[13]. Lipowska, M.; Hayes, B. L.; Hansen, L.; Taylor, A.; Marzilli, L.G. Inorg. Chem. 1996, 35, 4227-4231.
https://doi.org/10.1021/ic9514657
[14]. Beyer, L.; Hoyer, E.; Hennig, H.; Kirmse, R.; Hartmann, H.; Liebscher, J. J. Prakt. Chem. 1975, 317, 829-839.
https://doi.org/10.1002/prac.19753170518
[15]. Beyer, L.; Hoyer, E.; Liebscher, J.; Hartmann, H. Z. Chem. 1981, 21, 81-91.
[16]. Beyer, L.; Richter, R.; Seidelmann, O.; J. Prakt. Chem. Chem. Ztg. 1999, 341, 704.
https://doi.org/10.1002/(SICI)1521-3897(199911)341:8<704::AID-PRAC704>3.0.CO;2-E
[17]. Richter, R.; Beyer, L.; Kaiser, J.; Z. Anorg. Allg. Chem. 1980, 461, 67-73.
https://doi.org/10.1002/zaac.19804610111
[18]. Flores-Centurion, R.; Richter, R.; Angulo-Cornejo, J.; Beyer, L. Bol. Soc. Quim. Peru 1999, 65, 211-215.
[19]. Gomes, J. R. B.; Ribeiro da Silva, M. A. V. Inorg. Chem. Commun. 2003, 6, 149-153.
https://doi.org/10.1016/S1387-7003(02)00704-9
[20]. Schroder, U.; Richter, R.; Beyer, L.; Angulo-Cornejo, J.; Lino-Pacheco, M.; Guillen, A.; Z. Anorg. Allg. Chem. 2003, 629, 1051-1058.
https://doi.org/10.1002/zaac.200300019
[21]. Bruker, SADABS, Bruker AXS Inc., USA, 2007.
[22]. Sheldrick, G. M. Acta Crystr. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930
[23]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Cryst. 2009, 42, 339-341.
https://doi.org/10.1107/S0021889808042726
[24]. Ozer, C. K.; Arslan, H.; VanDerveer, D.; Binzet, G. J. Coord. Chem. 2009, 62, 266-276.
https://doi.org/10.1080/00958970802209623
[25]. Arslan, H.; Kulcu, N.; Florke. U. Transition Met. Chem. 2003, 28, 816-819.
https://doi.org/10.1023/A:1026064232260
[26]. Ozer, C. K., MSc thesis, Mersin University, Mersin, Turkey, 2008.
[27]. Arslan, H.; Duran, N.; Borekci, G.; Ozer, C. K.; Akbay, C. Molecules 2009, 14, 519-527.
https://doi.org/10.3390/molecules14010519
[28]. Al-abbasi, A. A.; Yamin, B. M.; Kassim, M. B. Acta Crystallogr. E 2011, 67, o1891- o1891.
https://doi.org/10.1107/S1600536811025013
[29]. Rauf, M. K.; Ebihara, M.; Badshah, A. Acta Crystallogr. E 2012, 68, o119- o119.
https://doi.org/10.1107/S1600536811052780
[30]. Yamin, B. M.; Osman, U. M. Acta Crystallogr. E 2011, 67, o1286-o1286.
https://doi.org/10.1107/S1600536811014954
[31]. Yang, W.; Zhou, W.Q.; Zhang, Z. J. J. Mol. Struct. 2007, 828, 46-53.
https://doi.org/10.1016/j.molstruc.2006.05.033
[32]. Arslan, H.; Florke, U.; Kulcu, N.; Binzet, G. Spectrochim. Acta A 2007, 68, 1347-1355.
https://doi.org/10.1016/j.saa.2007.02.015
[33]. Yusof, M. S.; Jusoh, R. H.; Khairul, W. M.; Bohari, M.Y. J. Mol. Struct. 2010, 975, 280-284.
https://doi.org/10.1016/j.molstruc.2010.04.037
[34]. Al-Abbasi, A. A.; Yamin, B. M.; Kassim, M. B. Acta Crystallogr. E 2011, 67, 1891-1894.
https://doi.org/10.1107/S1600536811025013
[35]. Mohamadou, A.; Dechamps-Olivier, I.; Barbier, J. P. Polyhedron 1994, 13, 1363-1370.
https://doi.org/10.1016/S0277-5387(00)81702-7
[36]. Arslan, H.; Florke, U.; Kulcu. N. Acta Chim. Slov. 2004, 51, 787-792.
[37]. Dragojlovic, V. Chem Texts 2015, 1-14, DOI: 10.1007/s40828-015-0014-0.
https://doi.org/10.1007/s40828-015-0014-0
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The Supplementary Material for this article can be found online at: Supplementary files
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DOI Link: https://doi.org/10.5155/eurjchem.7.4.416-420.1503
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European Journal of Chemistry 2016, 7(4), 416-420 | doi: https://doi.org/10.5155/eurjchem.7.4.416-420.1503 | Get rights and content
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