European Journal of Chemistry 2016, 7(4), 416-420. doi:10.5155/eurjchem.7.4.416-420.1503

Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand


Ilkay Gumus (1,*) , Cemal Koray Ozer (2) , Don Vanderveer (3) , Hakan Arslan (4)

(1) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(3) Department of Chemistry, Clemson University, Clemson, SC 29634-0973, USA
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(*) Corresponding Author

Received: 29 Oct 2016, Accepted: 28 Nov 2016, Published: 31 Dec 2016

Abstract


Copper(II) complex, cis-[Cu(L-κ2S,O)2] of N-(di-n-propylcarbamothioyl)cyclohexane carboxamide ligands (HL) has been synthesized and structurally characterized by various spectroscopic techniques and single crystal X-ray diffraction crystallography. The cis-[Cu(L-κ2S,O)2], C28H50CuN4O2S2: Monoclinic, space group P21/n (no. 14), a = 10.025(2) Å, b = 21.724(4) Å, c = 14.848(3) Å, β = 100.60(3)°, Z = 4, Dcalc = 1.259 g/cm3, 22069 reflections measured (5.88° ≤ 2Θ ≤ 50.2°), 5639 unique (Rint = 0.0630, Rsigma = 0.0678) which were used in all calculations. The final R1 was 0.0488 (≥2σ(I)) and wR2 was 0.1277 (all data). Single crystal analysis revealed that a square-planar coordination geometry is formed around the copper atom by two sulphur and two oxygen atoms of the related ligand, which are in a cis configuration.


Keywords


Thioureas; Cis-complex; Copper complex; Single crystal structure; Carboxamide derivatives; Cyclohexanecarboxamide

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DOI: 10.5155/eurjchem.7.4.416-420.1503

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[1]. Gun Binzet, Ersan Turunc, Ulrich Flörke, Nevzat Külcü, Hakan Arslan
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DOI: 10.1155/2018/6108242
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How to cite


Gumus, I.; Ozer, C.; Vanderveer, D.; Arslan, H. Eur. J. Chem. 2016, 7(4), 416-420. doi:10.5155/eurjchem.7.4.416-420.1503
Gumus, I.; Ozer, C.; Vanderveer, D.; Arslan, H. Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand. Eur. J. Chem. 2016, 7(4), 416-420. doi:10.5155/eurjchem.7.4.416-420.1503
Gumus, I., Ozer, C., Vanderveer, D., & Arslan, H. (2016). Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand. European Journal of Chemistry, 7(4), 416-420. doi:10.5155/eurjchem.7.4.416-420.1503
Gumus, Ilkay, Cemal Koray Ozer, Don Vanderveer, & Hakan Arslan. "Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand." European Journal of Chemistry [Online], 7.4 (2016): 416-420. Web. 17 Sep. 2019
Gumus, Ilkay, Ozer, Cemal, Vanderveer, Don, AND Arslan, Hakan. "Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand" European Journal of Chemistry [Online], Volume 7 Number 4 (31 December 2016)

DOI Link: https://doi.org/10.5155/eurjchem.7.4.416-420.1503

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