European Journal of Chemistry 2016, 7(4), 416-420 | doi: https://doi.org/10.5155/eurjchem.7.4.416-420.1503 | Get rights and content

Issue cover





  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand


Ilkay Gumus (1,*) , Cemal Koray Ozer (2) , Don Vanderveer (3) , Hakan Arslan (4)

(1) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(3) Department of Chemistry, Clemson University, Clemson, SC 29634-0973, USA
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(*) Corresponding Author

Received: 29 Oct 2016 | Accepted: 28 Nov 2016 | Published: 31 Dec 2016 | Issue Date: December 2016

Abstract


Copper(II) complex, cis-[Cu(L-κ2S,O)2] of N-(di-n-propylcarbamothioyl)cyclohexane carboxamide ligands (HL) has been synthesized and structurally characterized by various spectroscopic techniques and single crystal X-ray diffraction crystallography. The cis-[Cu(L-κ2S,O)2], C28H50CuN4O2S2: Monoclinic, space group P21/n (no. 14), a = 10.025(2) Å, b = 21.724(4) Å, c = 14.848(3) Å, β = 100.60(3)°, Z = 4, Dcalc = 1.259 g/cm3, 22069 reflections measured (5.88° ≤ 2Θ ≤ 50.2°), 5639 unique (Rint = 0.0630, Rsigma = 0.0678) which were used in all calculations. The final R1 was 0.0488 (≥2σ(I)) and wR2 was 0.1277 (all data). Single crystal analysis revealed that a square-planar coordination geometry is formed around the copper atom by two sulphur and two oxygen atoms of the related ligand, which are in a cis configuration.


Keywords


Thioureas; Cis-complex; Copper complex; Single crystal structure; Carboxamide derivatives; Cyclohexanecarboxamide

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.7.4.416-420.1503

Links for Article


| | | | | | |

| | | | | | |

| | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 827 times | icon graph PDF Article downloaded 305 times

Funding information


This study was supported by the Research Fund of Mersin University in Turkey with Project Number: BAP-SBE TB (CKÖ) 2007-1 YL.

Citations

/


[1]. Gun Binzet, Ersan Turunc, Ulrich Flörke, Nevzat Külcü, Hakan Arslan
Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide
Journal of Chemistry  2018, 1, 2018
DOI: 10.1155/2018/6108242
/

[2]. Cemal Koray Ozer, Gun Binzet, Hakan Arslan
Crystal and molecular structure of bis(N-(diethylcarbamothioyl)cyclohexane carboxamido)copper(II) complex
European Journal of Chemistry  11(4), 319, 2020
DOI: 10.5155/eurjchem.11.4.319-323.2047
/

References


[1]. Neucki, E. Ber. Dtsch. Chem. Ges., 1873, 6, 598-600.
https://doi.org/10.1002/cber.187300601186

[2]. Hope G. A.; Woods, R.; Boyd, S. E.; Watling, K. Colloids Surf. A, 2004, 232, 129-137.
https://doi.org/10.1016/j.colsurfa.2003.10.011

[3]. Guang-yi, L.; Hong, Z.; Liu-yin, X.; Shuai, W.; Zheng-He, X.; Miner. Eng. 2011, 24, 817-824.
https://doi.org/10.1016/j.mineng.2011.01.009

[4]. Otazo-Sanchez, E.; Perez-Marin, L.; Estevez-Hernandez, O.; Rojas-Lima, S.; Alonso-Chamarro, J. J. Chem. Soc., Perkin Trans. 2001, 2, 2211-2218.

[5]. Wilson, D.; Arada, M. A.; Alegret, S.; DelValle, M.; J. Hazard. Mater. 2010, 181, 140-146.
https://doi.org/10.1016/j.jhazmat.2010.04.107

[6]. Daud, A. I.; Khairul, W. M.; Mohamed, Z. H.; KuBulat, K. J. Sulfur Chem. 2014, 35, 691-699.
https://doi.org/10.1080/17415993.2014.954248

[7]. Yuan, Y. F.; Wang, J. T.; Gimeno, M. C.; Laguna, A.; Jones, P. G. Inorg. Chim. Acta 2001, 324, 309-317.
https://doi.org/10.1016/S0020-1693(01)00661-2

[8]. Zhang, Y. M.; Wei, T. B.; Xian, L.; Gao, L. M. Phosphorus Sulfur Silicon Relat. Elem. 2004, 179, 2007-2013.
https://doi.org/10.1080/10426500490473456

[9]. Zhang, Y. M.; Wei, T. B.; Wang, X. C.; Yang, S. Y. Indian J. Chem. Sect B 1998, 37, 604-606.

[10]. Zhou, W. Q.; Li, B. L.; Zhu, L. M.; Ding, J. G.; Yong, Z.; Lu, L.; Yang, X. J. J. Mol. Struct. 2004, 690, 145-150.
https://doi.org/10.1016/j.theochem.2004.02.011

[11]. Henderson, W.; Nicholson, B. K.; Dinger, M. B.; Bennett, R.L. Inorg. Chim. Acta 2002, 338, 210-218.
https://doi.org/10.1016/S0020-1693(02)01017-4

[12]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt, A. J. Chem. Soc., Dalton Trans. 2000, 24, 4579-4586.
https://doi.org/10.1039/b007589m

[13]. Lipowska, M.; Hayes, B. L.; Hansen, L.; Taylor, A.; Marzilli, L.G. Inorg. Chem. 1996, 35, 4227-4231.
https://doi.org/10.1021/ic9514657

[14]. Beyer, L.; Hoyer, E.; Hennig, H.; Kirmse, R.; Hartmann, H.; Liebscher, J. J. Prakt. Chem. 1975, 317, 829-839.
https://doi.org/10.1002/prac.19753170518

[15]. Beyer, L.; Hoyer, E.; Liebscher, J.; Hartmann, H. Z. Chem. 1981, 21, 81-91.

[16]. Beyer, L.; Richter, R.; Seidelmann, O.; J. Prakt. Chem. Chem. Ztg. 1999, 341, 704.
https://doi.org/10.1002/(SICI)1521-3897(199911)341:8<704::AID-PRAC704>3.0.CO;2-E

[17]. Richter, R.; Beyer, L.; Kaiser, J.; Z. Anorg. Allg. Chem. 1980, 461, 67-73.
https://doi.org/10.1002/zaac.19804610111

[18]. Flores-Centurion, R.; Richter, R.; Angulo-Cornejo, J.; Beyer, L. Bol. Soc. Quim. Peru 1999, 65, 211-215.

[19]. Gomes, J. R. B.; Ribeiro da Silva, M. A. V. Inorg. Chem. Commun. 2003, 6, 149-153.
https://doi.org/10.1016/S1387-7003(02)00704-9

[20]. Schroder, U.; Richter, R.; Beyer, L.; Angulo-Cornejo, J.; Lino-Pacheco, M.; Guillen, A.; Z. Anorg. Allg. Chem. 2003, 629, 1051-1058.
https://doi.org/10.1002/zaac.200300019

[21]. Bruker, SADABS, Bruker AXS Inc., USA, 2007.

[22]. Sheldrick, G. M. Acta Crystr. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

[23]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Cryst. 2009, 42, 339-341.
https://doi.org/10.1107/S0021889808042726

[24]. Ozer, C. K.; Arslan, H.; VanDerveer, D.; Binzet, G. J. Coord. Chem. 2009, 62, 266-276.
https://doi.org/10.1080/00958970802209623

[25]. Arslan, H.; Kulcu, N.; Florke. U. Transition Met. Chem. 2003, 28, 816-819.
https://doi.org/10.1023/A:1026064232260

[26]. Ozer, C. K., MSc thesis, Mersin University, Mersin, Turkey, 2008.

[27]. Arslan, H.; Duran, N.; Borekci, G.; Ozer, C. K.; Akbay, C. Molecules 2009, 14, 519-527.
https://doi.org/10.3390/molecules14010519

[28]. Al-abbasi, A. A.; Yamin, B. M.; Kassim, M. B. Acta Crystallogr. E 2011, 67, o1891- o1891.
https://doi.org/10.1107/S1600536811025013

[29]. Rauf, M. K.; Ebihara, M.; Badshah, A. Acta Crystallogr. E 2012, 68, o119- o119.
https://doi.org/10.1107/S1600536811052780

[30]. Yamin, B. M.; Osman, U. M. Acta Crystallogr. E 2011, 67, o1286-o1286.
https://doi.org/10.1107/S1600536811014954

[31]. Yang, W.; Zhou, W.Q.; Zhang, Z. J. J. Mol. Struct. 2007, 828, 46-53.
https://doi.org/10.1016/j.molstruc.2006.05.033

[32]. Arslan, H.; Florke, U.; Kulcu, N.; Binzet, G. Spectrochim. Acta A 2007, 68, 1347-1355.
https://doi.org/10.1016/j.saa.2007.02.015

[33]. Yusof, M. S.; Jusoh, R. H.; Khairul, W. M.; Bohari, M.Y. J. Mol. Struct. 2010, 975, 280-284.
https://doi.org/10.1016/j.molstruc.2010.04.037

[34]. Al-Abbasi, A. A.; Yamin, B. M.; Kassim, M. B. Acta Crystallogr. E 2011, 67, 1891-1894.
https://doi.org/10.1107/S1600536811025013

[35]. Mohamadou, A.; Dechamps-Olivier, I.; Barbier, J. P. Polyhedron 1994, 13, 1363-1370.
https://doi.org/10.1016/S0277-5387(00)81702-7

[36]. Arslan, H.; Florke, U.; Kulcu. N. Acta Chim. Slov. 2004, 51, 787-792.

[37]. Dragojlovic, V. Chem Texts 2015, 1-14, DOI: 10.1007/s40828-015-0014-0.
https://doi.org/10.1007/s40828-015-0014-0


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Gumus, I.; Ozer, C.; Vanderveer, D.; Arslan, H. Eur. J. Chem. 2016, 7(4), 416-420. doi:10.5155/eurjchem.7.4.416-420.1503
Gumus, I.; Ozer, C.; Vanderveer, D.; Arslan, H. Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand. Eur. J. Chem. 2016, 7(4), 416-420. doi:10.5155/eurjchem.7.4.416-420.1503
Gumus, I., Ozer, C., Vanderveer, D., & Arslan, H. (2016). Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand. European Journal of Chemistry, 7(4), 416-420. doi:10.5155/eurjchem.7.4.416-420.1503
Gumus, Ilkay, Cemal Koray Ozer, Don Vanderveer, & Hakan Arslan. "Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand." European Journal of Chemistry [Online], 7.4 (2016): 416-420. Web. 5 Mar. 2021
Gumus, Ilkay, Ozer, Cemal, Vanderveer, Don, AND Arslan, Hakan. "Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand" European Journal of Chemistry [Online], Volume 7 Number 4 (31 December 2016)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.7.4.416-420.1503

CrossRef | Scilit | GrowKudos | Researchgate | Publons | Microsoft | scibey | Scite | Lens | OUCI

WorldCat Paperbuzz Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2016, 7(4), 416-420 | doi: https://doi.org/10.5155/eurjchem.7.4.416-420.1503 | Get rights and content

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c)




© Copyright 2010 - 2021 • Atlanta Publishing House LLC • All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2021 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.