

Crystal structure of cis-copper(II) complex with N-(di-n-propylcarbamothioyl)cyclohexanecarboxamide ligand
Ilkay Gumus (1,*)




(1) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(3) Department of Chemistry, Clemson University, Clemson, SC 29634-0973, USA
(4) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey
(*) Corresponding Author
Received: 29 Oct 2016 | Accepted: 28 Nov 2016 | Published: 31 Dec 2016 | Issue Date: December 2016
Abstract
Copper(II) complex, cis-[Cu(L-κ2S,O)2] of N-(di-n-propylcarbamothioyl)cyclohexane carboxamide ligands (HL) has been synthesized and structurally characterized by various spectroscopic techniques and single crystal X-ray diffraction crystallography. The cis-[Cu(L-κ2S,O)2], C28H50CuN4O2S2: Monoclinic, space group P21/n (no. 14), a = 10.025(2) Å, b = 21.724(4) Å, c = 14.848(3) Å, β = 100.60(3)°, Z = 4, Dcalc = 1.259 g/cm3, 22069 reflections measured (5.88° ≤ 2Θ ≤ 50.2°), 5639 unique (Rint = 0.0630, Rsigma = 0.0678) which were used in all calculations. The final R1 was 0.0488 (≥2σ(I)) and wR2 was 0.1277 (all data). Single crystal analysis revealed that a square-planar coordination geometry is formed around the copper atom by two sulphur and two oxygen atoms of the related ligand, which are in a cis configuration.
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DOI: 10.5155/eurjchem.7.4.416-420.1503
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Funding information
This study was supported by the Research Fund of Mersin University in Turkey with Project Number: BAP-SBE TB (CKÖ) 2007-1 YL.
Citations
[1]. Gun Binzet, Ersan Turunc, Ulrich Flörke, Nevzat Külcü, Hakan Arslan
Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide
Journal of Chemistry 2018, 1, 2018
DOI: 10.1155/2018/6108242

[2]. Cemal Koray Ozer, Gun Binzet, Hakan Arslan
Crystal and molecular structure of bis(N-(diethylcarbamothioyl)cyclohexane carboxamido)copper(II) complex
European Journal of Chemistry 11(4), 319, 2020
DOI: 10.5155/eurjchem.11.4.319-323.2047

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DOI Link: https://doi.org/10.5155/eurjchem.7.4.416-420.1503

















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