European Journal of Chemistry 2015, 6(3), 237-241 | doi: https://doi.org/10.5155/eurjchem.6.3.237-241.1265 | Get rights and content






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Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)


Ilkay Gumus (1,*) , Ummuhan Solmaz (2) , Omer Celik (3) , Gun Binzet (4) , Gulten Kavak Balcı (5) , Hakan Arslan (6)

(1) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, 33343, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, 33343, Turkey
(3) Science and Technology Application and Research Center, Dicle University, Diyarbakır, 21280, Turkey
(4) Department of Chemistry, Faculty of Education, Mersin University, Mersin, 33343, Turkey
(5) Department of Physics, Faculty of Sciences, Dicle University, 21280 Diyarbakır, Turkey
(6) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, 33343, Turkey
(*) Corresponding Author

Received: 08 Apr 2015 | Revised: 26 May 2015 | Accepted: 28 May 2015 | Published: 30 Sep 2015 | Issue Date: September 2015

Abstract


cis-Bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II), cis-[Pt(L-O,S)2], was synthesized and characterized by elemental analyses, FT-IR and NMR techniques. The obtained metal complex was also characterized by a single crystal X-ray diffraction study. Molecule formula of the title compound is C24H28F2N4O2PtS2: tetragonal, space group I41/a, a = 19.7530(4) Å, b = 19.7530(4) Å, c = 13.7137(3) Å, = 5350.83(19) Å3, Z = 8, Dcalc = 1.742 g/mm3, 22890 reflections measured (3.62 ≤ 2Θ ≤ 52.72), 2733 (Rint = 0.0272), which were used in all calculations. A square-planar coordination geometry is formed around the Pt atom by two S atoms and two O atoms of the N-(diethylcarbamothioyl)-4-fluorobenzamide ligand which are a cis configuration.


Keywords


Thiourea; Synthesis; Cis-configuration; Benzoyl thiourea; Platinum complex; X-ray single crystal diffraction

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DOI: 10.5155/eurjchem.6.3.237-241.1265

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Funding information


This work was supported by Mersin University Research Fund (Project No: BAP.ECZ.F.TEB.(HA).2010-5A).

Citations

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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Gumus, I.; Solmaz, U.; Celik, O.; Binzet, G.; Balcı, G.; Arslan, H. Eur. J. Chem. 2015, 6(3), 237-241. doi:10.5155/eurjchem.6.3.237-241.1265
Gumus, I.; Solmaz, U.; Celik, O.; Binzet, G.; Balcı, G.; Arslan, H. Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II). Eur. J. Chem. 2015, 6(3), 237-241. doi:10.5155/eurjchem.6.3.237-241.1265
Gumus, I., Solmaz, U., Celik, O., Binzet, G., Balcı, G., & Arslan, H. (2015). Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II). European Journal of Chemistry, 6(3), 237-241. doi:10.5155/eurjchem.6.3.237-241.1265
Gumus, Ilkay, Ummuhan Solmaz, Omer Celik, Gun Binzet, Gulten Kavak Balcı, & Hakan Arslan. "Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)." European Journal of Chemistry [Online], 6.3 (2015): 237-241. Web. 30 May. 2020
Gumus, Ilkay, Solmaz, Ummuhan, Celik, Omer, Binzet, Gun, Balcı, Gulten, AND Arslan, Hakan. "Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)" European Journal of Chemistry [Online], Volume 6 Number 3 (30 September 2015)

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