European Journal of Chemistry

Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)



Main Article Content

Ilkay Gumus
Ummuhan Solmaz
Omer Celik
Gun Binzet
Gulten Kavak Balcı
Hakan Arslan

Abstract

cis-Bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II), cis-[Pt(L-O,S)2], was synthesized and characterized by elemental analyses, FT-IR and NMR techniques. The obtained metal complex was also characterized by a single crystal X-ray diffraction study. Molecule formula of the title compound is C24H28F2N4O2PtS2: tetragonal, space group I41/a, a = 19.7530(4) Å, b = 19.7530(4) Å, c = 13.7137(3) Å, = 5350.83(19) Å3, Z = 8, Dcalc = 1.742 g/mm3, 22890 reflections measured (3.62 ≤ 2Θ ≤ 52.72), 2733 (Rint = 0.0272), which were used in all calculations. A square-planar coordination geometry is formed around the Pt atom by two S atoms and two O atoms of the N-(diethylcarbamothioyl)-4-fluorobenzamide ligand which are a cis configuration.


icon graph This Abstract was viewed 1973 times | icon graph Article PDF downloaded 956 times icon graph Article CIF FILE downloaded 0 times

How to Cite
(1)
Gumus, I.; Solmaz, U.; Celik, O.; Binzet, G.; Balcı, G. K.; Arslan, H. Synthesis, Characterization and Crystal Structure of Cis-bis[4-Fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II). Eur. J. Chem. 2015, 6, 237-241.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Katritzky, A. R.; Gordeev, M. F. J. Chem. Soc. Perkin 1991, 1, 2199-2203.
http://dx.doi.org/10.1039/p19910002199

[2]. Saeed, S.; Rashid, N.; Jones, P.; Hussain R. Eur. J. Chem. 2011, 2, 77-82.
http://dx.doi.org/10.5155/eurjchem.2.1.77-82.183

[3]. Gunasekaran, N.; Jerome, P.; Ng, S. W. J. Mol. Catal. A. 2012, 353-354, 156-162.
http://dx.doi.org/10.1016/j.molcata.2011.11.019

[4]. Gunasekaran, N.; Remya, N.; Radhakrishnan, S.; Karvembu, R. J. Coord. Chem. 2011, 64, 491-501.
http://dx.doi.org/10.1080/00958972.2010.548007

[5]. Gunasekaran, N.; Karvembu, R. Inorg. Chem. Commun. 2010, 13, 952-955.
http://dx.doi.org/10.1016/j.inoche.2010.05.004

[6]. Duan, L. P.; Xue, J.; Xu, L. L.; Zhang, H. B. Molecules 2010, 15, 6941-6947.
http://dx.doi.org/10.3390/molecules15106941

[7]. Saeed, A.; Rafique, H.; Hameed, A.; Rasheed, S. Pharm. Chem. J. 2008, 42, 191-195.
http://dx.doi.org/10.1007/s11094-008-0094-x

[8]. Cunha, S.; Macedo, F. C.; Costa, G. A. N.; Rodrigues, M. T.; Verde, R B. V.; Souza, N. L. C.; Vencato, I.; Lariucci, C.; Sa, F. P. Monatsh. Chem. 2007, 138, 511-516.
http://dx.doi.org/10.1007/s00706-007-0600-y

[9]. Diþu, L. M.; Mihaescu, G.; Chifiriuc, C.; Bleotu, C.; Morusciag, L.; Niþulescu, G. M.; Missir, A. Roum. Arch. Microbiol. Immunol. 2010, 69, 41-47.

[10]. Limban, C.; Missir, A. V.; Chirita, I. C.; Badiceanu, C. D.; Draghici, C.; Balostescu, M. C.; Stamatoiu, O. Rev. Roum. Chim. 2008, 53, 595-602.

[11]. Limban, C.; Missir, A. V.; Chirita, I. C.; Neagu, A. F.; Draghici, C.; Chifiriuc, M. C. Rev. Chim (Bucharest) 2011, 62, 168-173.

[12]. Nitulescu, G.; Draghici, C.; Chifiriuc, M.; Marutescu, L.; Bleotu, C.; Missir, A. Med. Chem. Res. 2012, 21, 308-314.
http://dx.doi.org/10.1007/s00044-010-9541-9

[13]. Binzet, G.; Kulcu, N.; Florke, U.; Arslan, H. J. Coord. Chem. 2009, 62, 3454-3462.
http://dx.doi.org/10.1080/00958970903082200

[14]. Gale, P. A.; Garcia-Garrido, S. E.; Garric, J. Chem. Soc. Rev. 2008, 37, 151-190.
http://dx.doi.org/10.1039/B715825D

[15]. Doyle, A. G.; Jacobsen, E. N. Chem. Rev. 2007, 107, 5713-5743.
http://dx.doi.org/10.1021/cr068373r

[16]. Svetlana, B. T. Eur. J. Org. Chem. 2007, 2007, 1701-1716.

[17]. Boiocchi, M.; Del Boca, L.; Gomez, D. E.; Fabbrizzi, L.; Licchelli, M.; Monzani, E. J. Am. Chem. Soc. 2004, 126, 16507-16514.
http://dx.doi.org/10.1021/ja045936c

[18]. Bonizzoni, M.; Fabbrizzi, L.; Taglietti, A.; Tiengo, F. Eur. J. Org. Chem. 2006, 2006, 3567-3574.

[19]. Chen, H. L.; Guo, Z. F.; Lu, Z. L. Org. Lett. 2012, 14, 5070-5073.
http://dx.doi.org/10.1021/ol302313x

[20]. Liu, W. X.; Yang, R.; Li, A. F.; Li, Z.; Gao, Y. F.; Luo, X. X.; Ruan, Y. B.; Jiang, Y. B. Org. Biomol. Chem. 2009, 7, 4021-4028.
http://dx.doi.org/10.1039/b910255h

[21]. Zhang, Y.; Qin, J.; Lin, Q.; Wei, T. J. Fluorine Chem. 2006, 127, 1222-1227.
http://dx.doi.org/10.1016/j.jfluchem.2006.06.018

[22]. Zhang, Y. M.; Cao, C.; Wei, W.; Xie, T. B. Chin. J. Chem. 2007, 25, 709-713.
http://dx.doi.org/10.1002/cjoc.200790133

[23]. Henderson, W.; Kemmitt, R. D. W.; Mason, S.; Moore, M. R.; Fawcett, J.; Russell, D. R. Dalton Trans. 1992, 1, 59-66.
http://dx.doi.org/10.1039/dt9920000059

[24]. Lipowska, M.; Hayes, B. L.; Hansen, L.; Taylor, A.; Marzilli, L. G. Inorg. Chem. 1996, 35, 4227-4231.
http://dx.doi.org/10.1021/ic9514657

[25]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt, A. Dalton Trans. 2000, 4579-4586.
http://dx.doi.org/10.1039/b007589m

[26]. Hu, J. H.; Fan, X. H.; Du, X. L.; Wei, T. B. Phosphorus Sulfur 2010, 185, 2558-2562.
http://dx.doi.org/10.1080/10426501003752187

[27]. Merdivan, M.; Karipcin, F.; Kulcu, N.; Aygun, R. S. J. Therm. Anal. Calorim. 1999, 58, 551-557.
http://dx.doi.org/10.1023/A:1010140125400

[28]. Binzet, G.; Arslan, H.; Florke, U.; Kulcu, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395-1406.
http://dx.doi.org/10.1080/00958970500512633

[29]. Mansuroglu, D. S.; Arslan, H.; Florke, U.; Kulcu, N. J. Coord. Chem. 2008, 61, 3134-3146.
http://dx.doi.org/10.1080/00958970802010567

[30]. Fitzl, G.; Beyer, L.; Sieler, R.; Richter, R.; Kaiser, J.; Hoyer, E. Z. Anorg. Allg. Chem. 1977, 433, 237-241.
http://dx.doi.org/10.1002/zaac.19774330127

[31]. Ozer, C. K.; Arslan, H.; Vanderveer, D.; Binzet, G. J. Coord. Chem. 2009, 62, 266-276.
http://dx.doi.org/10.1080/00958970802209623

[32]. Koch, K. R.; Sacht, C.; Grimmbacher, T.; Bourne, S. S. Afr. J. Chem. 1995, 48, 71-77.

[33]. Williams, J. A. G. Top. Curr. Chem. 2007, 281, 205- 268.
http://dx.doi.org/10.1007/128_2007_134

[34]. Lu, W.; Mi, B. X.; Chan, M. C. W.; Hui, Z.; Che, C. M.; Zhu, N.; Lee, S. T. J. Am. Chem. Soc. 2004, 126, 4958-4971.
http://dx.doi.org/10.1021/ja0317776

[35]. Evans, R. C.; Douglas, P.; Winscom, C. J. Coord. Chem. Rev. 2006, 250, 2093-2126.
http://dx.doi.org/10.1016/j.ccr.2006.02.007

[36]. Laskar, I. R.; Hsu, S. F.; Chen, T. M. Polyhedron 2005, 24, 881-888.
http://dx.doi.org/10.1016/j.poly.2005.02.009

[37]. McMillin, D. R.; Moore, J. J. Coord. Chem. Rev. 2002, 229, 113-121.
http://dx.doi.org/10.1016/S0010-8545(02)00041-3

[38]. Siu, P. K. M., Ma, D. L.; Che, C. M. Chem. Commun. 2005, 8, 1025-1027.

[39]. Kennedy, F.; Shavaleev, N. M.; Koullourou, T.; Bell, Z. R.; Jeffery, J. K.; Faulkner, S.; Ward, M. D. Dalton Trans. 2007, 15, 1492-1499.
http://dx.doi.org/10.1039/b616423d

[40]. Thomas, S. W.; Yagi, S.; Swager, T. M. J. Mater. Chem. 2005, 15, 2829-2835.
http://dx.doi.org/10.1039/b503539b

[41]. Yang, Q. Z.; Wu, L. Z.; Zhang, H.; Chen, B.; Wu, Z. W.; Zhang, L. P.; Tung, C. H. Inorg. Chem. 2004, 43, 5195-5197.
http://dx.doi.org/10.1021/ic049815p

[42]. Bruker, SADABS. Bruker AXS Inc., Madison, Wisconsin, USA, 2007.

[43]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
http://dx.doi.org/10.1107/S0108767307043930

[44]. Farrugia, L. J. ORTEP-3 for Windows-a version of ORTEP-III with a graphical user interface (GUI). J. Appl. Cryst. 1997, 30, 565-566.
http://dx.doi.org/10.1107/S0021889897003117

[45]. Selvakumaran, N.; Ng, S. W.; Tiekink, E. R. T.; Karvembu, R. Inor. Chim. Acta 2011, 376, 278-284.
http://dx.doi.org/10.1016/j.ica.2011.06.031

[46]. Reilly, B. O.; Plutin, A. M.; Perez, H.; Calderon, O.; Ramos, R.; Martinez, R.; Toscano, R. A.; Duque, J.; Rodriguez-Solla, H.; Martinez-Alvarez, R.; Suarez, M.; Martin, N. Polyhedron 2012, 36, 133-140.
http://dx.doi.org/10.1016/j.poly.2012.02.008

[47]. Binzet, G.; Florke, U.; N. Kulcu, H. Arslan. Acta Cryst. E 2009, 65, o427-o428.
http://dx.doi.org/10.1107/S1600536809003183

[48]. Morsali, A.; Masoomi, M. Y. Coord. Chem. Rev. 2009, 253, 1882-1905.
http://dx.doi.org/10.1016/j.ccr.2009.02.018

[49]. Arslan, H.; Kulcu, N. Trans. Metal Chem. 2003, 28, 816-819.
http://dx.doi.org/10.1023/A:1026064232260

[50]. Arslan, H.; Florke, U.; Kulcu, N.; Kayhan, E. Turk. J. Chem. 2006, 30, 429-440.

[51]. Dauglass, I. B.; Dains, F. B. J. Am. Chem. Soc. 1934, 56, 719-721.
http://dx.doi.org/10.1021/ja01318a057

Supporting Agencies

This work was supported by Mersin University Research Fund (Project No, BAP.ECZ.F.TEB.(HA).2010-5A).
Most read articles by the same author(s)

Most read articles by the same author(s)

<< < 1 2 3 4 5 6 7 8 9 10 > >> 
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).