European Journal of Chemistry 2016, 7(4), 448-453. doi:10.5155/eurjchem.7.4.448-453.1509

Preparation, characterization and crystal structure of dinuclear zinc(II) carboxylate complex with 1-(pyridin-4-yl)ethanone and 4-methylbenzoate based ligands


Efdal Cimen (1) , Ilkay Gumus (2,*) , Omer Celik (3) , Ebru Keskin (4) , Hakan Arslan (5)

(1) Department of Chemistry and Chemical Process Technology, Kars Vocational School, Kafkas University, Kars, TR-36100, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33344, Turkey
(3) Science and Technology Applied and Research Center, Dicle University, Sur, Diyarbakir, TR-21280, Turkey
(4) Advanced Technology Research and Application Center, Mersin University, Mersin, TR-33343, Turkey
(5) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR-33344, Turkey
(*) Corresponding Author

Received: 13 Nov 2016, Accepted: 03 Dec 2016, Published: 31 Dec 2016

Abstract


The centrosymmetric binuclear complex, [Zn2(C8H7O2)4(C7H7NO)2], has been synthesized and characterized by FT-IR and NMR methods. The obtained Zn(II) metal complex has been also characterized by a single crystal X-ray diffraction study. Crystal data for C46H42N2O10Zn2: Monoclinic, Space group P21/c (no. 14), a = 10.4827(3) Å, b = 8.6141(2) Å, c = 24.7582(6) Å, β = 101.066(1) °, V = 2194.07(10) Å3, Z = 4, Dcalc = 1.383 g/cm3, 22545 reflections measured (3.96° ≤ 2Θ ≤ 52.74°), 4465 unique (Rint = 0.0388, Rsigma = 0.0333) which were used in all calculations. The final R1 was 0.0489 (I ≥ 2s(I)) and wR2 was 0.1533 (all data). The four nearest oxygen atoms around each zinc ion form a distorted square-planar arrangement, and the distorted square-pyramidal coordination is completed by the nitrogen atom of the 1-(pyridin-4-yl)ethanone compound.


Keywords


Synthesis; Zinc complex; Zinc carboxylate; Crystal structure; Centrosymmetric; Dinuclear zinc(II) complex

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DOI: 10.5155/eurjchem.7.4.448-453.1509

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How to cite


Cimen, E.; Gumus, I.; Celik, O.; Keskin, E.; Arslan, H. Eur. J. Chem. 2016, 7(4), 448-453. doi:10.5155/eurjchem.7.4.448-453.1509
Cimen, E.; Gumus, I.; Celik, O.; Keskin, E.; Arslan, H. Preparation, characterization and crystal structure of dinuclear zinc(II) carboxylate complex with 1-(pyridin-4-yl)ethanone and 4-methylbenzoate based ligands. Eur. J. Chem. 2016, 7(4), 448-453. doi:10.5155/eurjchem.7.4.448-453.1509
Cimen, E., Gumus, I., Celik, O., Keskin, E., & Arslan, H. (2016). Preparation, characterization and crystal structure of dinuclear zinc(II) carboxylate complex with 1-(pyridin-4-yl)ethanone and 4-methylbenzoate based ligands. European Journal of Chemistry, 7(4), 448-453. doi:10.5155/eurjchem.7.4.448-453.1509
Cimen, Efdal, Ilkay Gumus, Omer Celik, Ebru Keskin, & Hakan Arslan. "Preparation, characterization and crystal structure of dinuclear zinc(II) carboxylate complex with 1-(pyridin-4-yl)ethanone and 4-methylbenzoate based ligands." European Journal of Chemistry [Online], 7.4 (2016): 448-453. Web. 20 Nov. 2019
Cimen, Efdal, Gumus, Ilkay, Celik, Omer, Keskin, Ebru, AND Arslan, Hakan. "Preparation, characterization and crystal structure of dinuclear zinc(II) carboxylate complex with 1-(pyridin-4-yl)ethanone and 4-methylbenzoate based ligands" European Journal of Chemistry [Online], Volume 7 Number 4 (31 December 2016)

DOI Link: https://doi.org/10.5155/eurjchem.7.4.448-453.1509

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