European Journal of Chemistry

A new potentiometric sensor based on molecularly imprinted polymer for analysis of a veterinary drug imidocarb dipropionate



Main Article Content

Mohammed Rizk
Safaa Shafik Toubar
Hossam Ezz El-Din Sayour
Dalia Mohamed
Rehab Moussa Touny

Abstract

A new potentiometric sensor based on molecularly imprinted polymer (MIP) was fabricated for the recognition and determination of imidocarb dipropionate. The MIP was synthesized using imidocarb as the template material, methacrylic acid as a functional monomer, and ethylene glycol dimethacrylate as a cross linking agent. The sensor showed a high selectivity and a sensitive response to the template molecule in aqueous solution. The MIP-electrode exhibited a near-Nernstian response in a wide concentration range 10-5 - 10-2 M with a lower detection limit of 2×10-6 M. The potentiometric conditions were carefully studied and all measuring parameters were optimized including pH, buffer type, plasticizer type, response time and stability. The applicability of the sensor was tested through potentiometric determination of imidocarb dipropionate in pure drug as well as in pharmaceutical formulation. The proposed method was statistically compared with a reported one showing no significant difference regarding accuracy and precision, which assured a good reliable novel sensor for imidocarb estimation.


icon graph This Abstract was viewed 2518 times | icon graph Article PDF downloaded 993 times

How to Cite
(1)
Rizk, M.; Toubar, S. S.; Sayour, H. E. E.-D.; Mohamed, D.; Touny, R. M. A New Potentiometric Sensor Based on Molecularly Imprinted Polymer for Analysis of a Veterinary Drug Imidocarb Dipropionate. Eur. J. Chem. 2014, 5, 18-23.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Chow, C. F.; Lam, M. H. W.; Leung, M. K. P. Anal. Chim. Acta 2002, 466, 17-30.
http://dx.doi.org/10.1016/S0003-2670(02)00520-2

[2]. Martin-Esteban, A. Anal. Bioanal. Chem. 2004, 378, 1875-1875.
http://dx.doi.org/10.1007/s00216-004-2502-8

[3]. Roche, P. J. R.; Ng, S. M.; Narayanaswamy, R.; Goddard, N.; Page, K. M. Sens. Actuators B Chem. 2009, 139, 22-29.
http://dx.doi.org/10.1016/j.snb.2008.07.029

[4]. He, C. Y.; Liu, F.; Li, K. A.; Liu, H. W. Anal. Lett. 2006, 39, 275-286.
http://dx.doi.org/10.1080/00032710500476946

[5]. Yang, H. H.; Zhang, S. Q.; Tan, F.; Zhuang, Z. X.; Wang, X. R. J. Am. Chem. Soc. 2005, 127, 1378-1379.
http://dx.doi.org/10.1021/ja0467622

[6]. Chai, C.; Liu, G.; Li, F.; Liu, X.; Yao, B.; Wang, L. Anal. Chim. Acta 2010, 675, 185-190.
http://dx.doi.org/10.1016/j.aca.2010.07.012

[7]. Kriz, D.; Mosbach, K. Anal. Chim. Acta 1995, 300, 71-75.
http://dx.doi.org/10.1016/0003-2670(94)00368-V

[8]. Chen,P.; Nien, P.; Wu, C.; Wu, T.; Lin, C.; Ho, K. Anal. Chim. Acta 2009, 643, 38-44.
http://dx.doi.org/10.1016/j.aca.2009.04.004

[9]. Chen, P.; Vittal, R.; Nien, P.; Liou, G.; Ho, K. Talanta 2010, 80, 1145-1151.
http://dx.doi.org/10.1016/j.talanta.2009.08.041

[10]. Sadeghi, S.; Motaharian, A.; Moghaddam, A. Z. Sens. Actuators B Chem. 2012, 168, 336-344.
http://dx.doi.org/10.1016/j.snb.2012.04.031

[11]. Tarley, C. R. T.; Kubota, L. T. Anal. Chim. Acta 2005, 548, 11-19.
http://dx.doi.org/10.1016/j.aca.2005.05.055

[12]. Say, R.; Gultekin, A.; Ozcan, A. A.; Denizli, A.; Ersoz, A. Anal. Chim. Acta 2009, 640, 82-86.
http://dx.doi.org/10.1016/j.aca.2009.03.022

[13]. Kobayashi, T.; Murawaki, Y.; Reddy, P. S.; Abe, M.; Fujii, N. Anal. Chim. Acta 2001, 435, 141-149.
http://dx.doi.org/10.1016/S0003-2670(00)01281-2

[14]. Hao, H. X.; Zhou, H.; Chang, J.; Zhu, J.; Wei, T. X. Chin. Chem. Lett. 2011, 22, 477-480.
http://dx.doi.org/10.1016/j.cclet.2010.11.004

[15]. Sadeghi, S.; Fathi, F.; Abbasifar, J. Sens. Actuators B Chem. 2007, 122, 58-164.

[16]. Tonelli, D.; Ballarin, B.; Guadagnini, L.; Mignani, A.; Scavetta, E. Electrochim. Acta. 2011, 56, 7149-7154.
http://dx.doi.org/10.1016/j.electacta.2011.05.076

[17]. Coldham, N. G.; Moore, A. S.; Dave, M.; Graham, P. J.; Sivapathasundardm, S.; Lake, B. G.; Sauer, M. J. Drug Metab. Disp. I995, 23, 501-505.

[18]. Edelhofer, R.; Muller, A.; Schuh, M.; Obritzhauser, W.; Kanout, A. Parasitol. Res. 2004, 92, 433-435.
http://dx.doi.org/10.1007/s00436-003-1060-x

[19]. Kuttler, K. L.; Johnson, L. W. Vet. Parasitol. 1986, 21, 107-118.
http://dx.doi.org/10.1016/0304-4017(86)90151-2

[20]. Tarbin, J. A.; Shearer, G. J. Chromatogr. B. Biomed. Sci. Appl. 1992, 577, 376-381.
http://dx.doi.org/10.1016/0378-4347(92)80263-P

[21]. Ishii, R.; Takahashi, K.; Matsumoto, R. Shokuhin Eiseigaku Zasshi 2010, 52, 34-39.
http://dx.doi.org/10.3358/shokueishi.52.34

[22]. Lehner, A. F.; Hitron, J. A.; May, J.; Hughes, C.; Eisenberg, R.; Schwint, N.; Knowles, D. P.; Timoney, P.; Tobin, T. J. Anal. Toxicol. 2011, 35, 199-204.
http://dx.doi.org/10.1093/anatox/35.4.199

[23]. Koichi, I.; Mari, N.; Tomoaki, H.; Hisao, O. J. Liq. Chromatogr. Relat. Technol. 2011, 34, 2149-2156.
http://dx.doi.org/10.1080/10826076.2011.585484

[24]. Duffy, D.J.; Das, K.; Hsu, S. L.; Penelle, J.; Rotello, V. M.; Stidham, H. D. J. Am. Chem. Soc. 2002, 124, 8290-8296.
http://dx.doi.org/10.1021/ja0201146

[25]. Katz, A.; Davis, M. E. Macromolecules 1999, 32, 4113-4121.
http://dx.doi.org/10.1021/ma981445z

[26]. Umezawa, Y.; Umezawa, K.; Sato, H. Pure Appl. Chem. 1995, 67, 507-518.
http://dx.doi.org/10.1351/pac199567030507

[27]. Miller, J. C.; Miller, J. N. Statistics for Analytical Chemistry, fifth edition, Wiley, New York, 2005, p. 256.

Supporting Agencies

Most read articles by the same author(s)

Most read articles by the same author(s)

TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).