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Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand
Mamour Sarr (1)
, Mayoro Diop (2) , Ibrahima Elhadj Thiam (3) , Mohamed Gaye (4,*) , Aliou Hamady Barry (5) , Natalia Alvarez (6) , Javier Ellena (7) (1) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(2) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(3) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(4) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(5) Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania
(6) Facultad de Química, General Flores 2124, UdelaR, Montevideo, 11800, Uruguay
(7) Instituto de Física de São Carlos, Universidade de São Paulo, CP 369, 13.560-970, São Carlos, SP, Brazil
(*) Corresponding Author
Received: 26 Feb 2018 | Revised: 04 Apr 2018 | Accepted: 04 Apr 2018 | Published: 30 Jun 2018 | Issue Date: June 2018
Abstract
The present investigation describes the synthesis and structural study of a metal-zinc ligand [ZnL.H2O], which was used to generate three dimensional supramolecular complex formulated as [Y{Zn(L)(SCN)}(SCN)2].[Y{Zn(L)(SCN)}2(DMF)2].(NO3). The title compound crystallizes in the triclinic space group P-1 with the following unit cell parameters: a = 14.8987(7) Å, b = 15.6725(8) Å, c = 19.2339(10) Å, a = 94.610(4)°, β = 103.857(4)°, γ = 101.473(4)°, V = 4234.4(4) Å3, Z = 2, R1 = 0.063 and wR2 = 0.96. For this compound, the structure reveals that one heterodinuclear unit [Y{Zn(L)(SCN)}(SCN)2] is co-crystallized with a heterotrinuclear unit [Y{Zn(L)(SCN)}2(DMF)2].(NO3). In the dinuclear moiety, the organic molecule acts as a hexadentate ligand and in the trinuclear unit, it acts as a pentadentate ligand with one of the oxygen methoxy group remaining uncoordinated. In both units the coordination environment of the zinc metal can be described as distorted square pyramidal. In the dinuclear unit the Y(III) is hexacoordinated while it is octacoordinated in the trinuclear unit. The environment of the Y(III) can be described as a distorted octahedral geometry in the dinuclear and as a distorted square antiprism in the trinuclear units respectively.
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DOI: 10.5155/eurjchem.9.2.67-73.1688
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Funding information
The FONDATION SONATEL, Senegal
Citations
[1]. Mamour Sarr, Mayoro Diop, Elhadj Ibrahima Thiam, Mohamed Gaye, Aliou Hamady Barry, James B. Orton, Simon J Coles
A new co-crystal dinuclear/trinuclear ZnII–ZnII/ZnII–SmIII–ZnII complex with a salen-type Schiff base ligand
Acta Crystallographica Section E Crystallographic Communications 74(12), 1862, 2018
DOI: 10.1107/S2056989018016109
[2]. Pokpa Haba, Adama Sy, Farba Bouyagui Tamboura, Mamour Sarr, Ibrahima Elhadji Thiam, Aliou Hamady Barry, Mohamed Lamine Sall, Mohamed Gaye, Pascal Retailleau
Synthesis, spectroscopic studies and X-ray structure determination of two mononuclear copper complexes derived from the Schiff base ligand N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene)ethane-1,2-diamine
European Journal of Chemistry 10(3), 201, 2019
DOI: 10.5155/eurjchem.10.3.201-208.1881
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DOI Link: https://doi.org/10.5155/eurjchem.9.2.67-73.1688
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European Journal of Chemistry 2018, 9(2), 67-73 | doi: https://doi.org/10.5155/eurjchem.9.2.67-73.1688 | Get rights and content
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