European Journal of Chemistry 2018, 9(2), 67-73. doi:10.5155/eurjchem.9.2.67-73.1688

Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand


Mamour Sarr (1) orcid , Mayoro Diop (2) orcid , Ibrahima Elhadj Thiam (3) orcid , Mohamed Gaye (4,*) orcid , Aliou Hamady Barry (5) orcid , Natalia Alvarez (6) orcid , Javier Ellena (7) orcid

(1) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(2) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(3) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(4) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(5) Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania
(6) Facultad de Química, General Flores 2124, UdelaR, Montevideo, 11800, Uruguay
(7) Instituto de Física de São Carlos, Universidade de São Paulo, CP 369, 13.560-970, São Carlos, SP, Brazil
(*) Corresponding Author

Received: 26 Feb 2018, Accepted: 04 Apr 2018, Published: 30 Jun 2018

Abstract


The present investigation describes the synthesis and structural study of a metal-zinc ligand [ZnL.H2O], which was used to generate three dimensional supramolecular complex formulated as [Y{Zn(L)(SCN)}(SCN)2].[Y{Zn(L)(SCN)}2(DMF)2].(NO3). The title compound crystallizes in the triclinic space group P-1 with the following unit cell parameters: a = 14.8987(7) Å, b = 15.6725(8) Å, c = 19.2339(10) Å, a = 94.610(4)°, β = 103.857(4)°, γ = 101.473(4)°, V = 4234.4(4) Å3, Z = 2, R1 = 0.063 and wR2 = 0.96. For this compound, the structure reveals that one heterodinuclear unit [Y{Zn(L)(SCN)}(SCN)2] is co-crystallized with a heterotrinuclear unit [Y{Zn(L)(SCN)}2(DMF)2].(NO3). In the dinuclear moiety, the organic molecule acts as a hexadentate ligand and in the trinuclear unit, it acts as a pentadentate ligand with one of the oxygen methoxy group remaining uncoordinated. In both units the coordination environment of the zinc metal can be described as distorted square pyramidal. In the dinuclear unit the Y(III) is hexacoordinated while it is octacoordinated in the trinuclear unit. The environment of the Y(III) can be described as a distorted octahedral geometry in the dinuclear and as a distorted square antiprism in the trinuclear units respectively.


Keywords


Complex; Antiprism; Co-crystal; Schiff base; Thiocyanate; Heteronuclear

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DOI: 10.5155/eurjchem.9.2.67-73.1688

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[1]. Mamour Sarr, Mayoro Diop, Elhadj Ibrahima Thiam, Mohamed Gaye, Aliou Hamady Barry, James B. Orton, Simon J Coles
A new co-crystal dinuclear/trinuclear ZnII–ZnII/ZnII–SmIII–ZnII complex with a salen-type Schiff base ligand
Acta Crystallographica Section E Crystallographic Communications  74(12), 1862, 2018
DOI: 10.1107/S2056989018016109
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How to cite


Sarr, M.; Diop, M.; Thiam, I.; Gaye, M.; Barry, A.; Alvarez, N.; Ellena, J. Eur. J. Chem. 2018, 9(2), 67-73. doi:10.5155/eurjchem.9.2.67-73.1688
Sarr, M.; Diop, M.; Thiam, I.; Gaye, M.; Barry, A.; Alvarez, N.; Ellena, J. Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand. Eur. J. Chem. 2018, 9(2), 67-73. doi:10.5155/eurjchem.9.2.67-73.1688
Sarr, M., Diop, M., Thiam, I., Gaye, M., Barry, A., Alvarez, N., & Ellena, J. (2018). Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand. European Journal of Chemistry, 9(2), 67-73. doi:10.5155/eurjchem.9.2.67-73.1688
Sarr, Mamour, Mayoro Diop, Ibrahima Elhadj Thiam, Mohamed Gaye, Aliou Hamady Barry, Natalia Alvarez, & Javier Ellena. "Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand." European Journal of Chemistry [Online], 9.2 (2018): 67-73. Web. 21 Sep. 2019
Sarr, Mamour, Diop, Mayoro, Thiam, Ibrahima, Gaye, Mohamed, Barry, Aliou, Alvarez, Natalia, AND Ellena, Javier. "Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand" European Journal of Chemistry [Online], Volume 9 Number 2 (30 June 2018)

DOI Link: https://doi.org/10.5155/eurjchem.9.2.67-73.1688

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