European Journal of Chemistry 2018, 9(2), 67-73 | doi: https://doi.org/10.5155/eurjchem.9.2.67-73.1688 | Get rights and content

Issue cover




Crossmark

  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand


Mamour Sarr (1) orcid , Mayoro Diop (2) orcid , Ibrahima Elhadj Thiam (3) orcid , Mohamed Gaye (4,*) orcid , Aliou Hamady Barry (5) orcid , Natalia Alvarez (6) orcid , Javier Ellena (7) orcid

(1) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(2) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(3) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(4) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Senegal
(5) Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania
(6) Facultad de Química, General Flores 2124, UdelaR, Montevideo, 11800, Uruguay
(7) Instituto de Física de São Carlos, Universidade de São Paulo, CP 369, 13.560-970, São Carlos, SP, Brazil
(*) Corresponding Author

Received: 26 Feb 2018 | Revised: 04 Apr 2018 | Accepted: 04 Apr 2018 | Published: 30 Jun 2018 | Issue Date: June 2018

Abstract


The present investigation describes the synthesis and structural study of a metal-zinc ligand [ZnL.H2O], which was used to generate three dimensional supramolecular complex formulated as [Y{Zn(L)(SCN)}(SCN)2].[Y{Zn(L)(SCN)}2(DMF)2].(NO3). The title compound crystallizes in the triclinic space group P-1 with the following unit cell parameters: a = 14.8987(7) Å, b = 15.6725(8) Å, c = 19.2339(10) Å, a = 94.610(4)°, β = 103.857(4)°, γ = 101.473(4)°, V = 4234.4(4) Å3, Z = 2, R1 = 0.063 and wR2 = 0.96. For this compound, the structure reveals that one heterodinuclear unit [Y{Zn(L)(SCN)}(SCN)2] is co-crystallized with a heterotrinuclear unit [Y{Zn(L)(SCN)}2(DMF)2].(NO3). In the dinuclear moiety, the organic molecule acts as a hexadentate ligand and in the trinuclear unit, it acts as a pentadentate ligand with one of the oxygen methoxy group remaining uncoordinated. In both units the coordination environment of the zinc metal can be described as distorted square pyramidal. In the dinuclear unit the Y(III) is hexacoordinated while it is octacoordinated in the trinuclear unit. The environment of the Y(III) can be described as a distorted octahedral geometry in the dinuclear and as a distorted square antiprism in the trinuclear units respectively.


Keywords


Complex; Antiprism; Co-crystal; Schiff base; Thiocyanate; Heteronuclear

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.9.2.67-73.1688

Links for Article


| | | | | | |

| | | | | | |

| | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 1088 times | icon graph PDF Article downloaded 379 times

Funding information


The FONDATION SONATEL, Senegal

Cited by

Crossref database responds too late...

References


[1]. Costes, J. P.; Dahan, F.; Dupuis, A.; Laurent, J. P. Inorg. Chem. 1997, 36, 4284-4286.
https://doi.org/10.1021/ic970720f

[2]. Costes, J. P.; Dahan, F.; Dupuis, A.; Laurent, J. P. Inorg. Chem. 2000, 39, 169-173.
https://doi.org/10.1021/ic990864p

[3]. Benelli, C.; Gatteschi, D. Chem. Rev. 2002, 102, 2369-2387.
https://doi.org/10.1021/cr010303r

[4]. Sakamoto, M.; Manseki, K.; Okawa, H. Coord. Chem. Rev. 2001, 219-221, 379-414.
https://doi.org/10.1016/S0010-8545(01)00341-1

[5]. Costes, J. P.; Dahan, F.; Wernsdorfer, W. Inorg. Chem. 2006, 45, 5-7.
https://doi.org/10.1021/ic050563h

[6]. Laurent, J. P.; Dahan, F.; Dupuis, A. Inorg. Chem. 2000, 39, 5994-6000.
https://doi.org/10.1021/ic000666u

[7]. Han, S. D.; Zhao, J. P.; Chen, Y. Q.; Liu, S. J.; Miao, X. H.; Hu, T. L.; Bu, X. H. Cryst. Growth Des. 2014, 14, 2-5.
https://doi.org/10.1021/cg401335n

[8]. Das, S.; Sorace, L.; Guha, A.; Sanyal, R.; Kara, H.; Caneschi, A.; Zangrando, E.; Das, D. Eur. J. Inorg. Chem. 2014, 17, 2753-2765.
https://doi.org/10.1002/ejic.201301581

[9]. Amatori, S.; Ambrosi, G.; Borgogelli, E.; Fanelli, M.; Formica, M.; Fusi, V.; Giorgi, L.; Macedi, E.; Micheloni, M.; Paoli, P.; Rossi, P.; Tassoni, A. Inorg. Chem. 2014, 53, 4560-4569.
https://doi.org/10.1021/ic5001649

[10]. Aboshyan-Sorgho, L.; Nozary, H.; Aebischer, A.; Bunzli, J. C. G.; Morgantini, P. Y.; Kittilstved, K. R.; Hauser, A.; Eliseeva, S. V.; Petoud, S.; Piguet, C. J. Am. Chem. Soc. 2012, 134, 12675-12684.
https://doi.org/10.1021/ja304009b

[11]. Cancino, P.; Paredes-Garcia, V.; Aliaga, C.; Aguirre, P.; Aravena, D.; Spodine, E. Catal. Sci. Technol. 2017, 7, 231-242.
https://doi.org/10.1039/C6CY02115H

[12]. Yu, T.; Ma, H.; Zhang, C.; Pang, H.; Lia, S.; Liua, H. Dalton Trans. 2013, 42, 16328-16333.
https://doi.org/10.1039/c3dt51983j

[13]. Li, L.; Zou, J. Y.; You, S. Y.; Cui, H. M.; Zeng, G. P.; Cui, J. Z. Dalton Trans. 2017, 46, 16432-16438.
https://doi.org/10.1039/C7DT03545D

[14]. Wen, H. R.; Dong, P. P.; Liu, S. J.; Liao, J. S.; Liang, F. Y.; Liu, C. M. Dalton Trans. 2017, 46, 1153-1162.
https://doi.org/10.1039/C6DT04027F

[15]. Yang, X.; Schipper, D.; Jones, R. A.; Lytwak, L. A.; Holliday, B. J.; Huang, S. J. Am. Chem. Soc. 2013, 135, 8468-8471.
https://doi.org/10.1021/ja4031243

[16]. Marinescu, G.; Maxim, C.; Clerac, R.; Andruh, M. Inorg. Chem. 2015, 54, 5621-5623.
https://doi.org/10.1021/acs.inorgchem.5b00889

[17]. Salmon, L.; Thuery, P.; Riviere, E.; Ephritikhine, M. Inorg. Chem. 2006, 45, 83-93.
https://doi.org/10.1021/ic0512375

[18]. Costes, J. P.; Tomoka, Y.; Masaaki K.; Laure V. Inorg. Chem. 2009, 48, 5555-5561.
https://doi.org/10.1021/ic900142h

[19]. Zheng, Z. P.; Ou, Y. J.; Hong, X. J.; Wei, L. M.; Wan, L. T.; Zhou, W. H.; Zhan, Q. G.; Cai, Y. P. Inorg. Chem. 2014, 53, 9625-9632.
https://doi.org/10.1021/ic501118b

[20]. Ishikawa, N.; Sugita, M.; Wernsdorfer, W. J. Am. Chem. Soc. 2005, 127, 3650-3651.
https://doi.org/10.1021/ja0428661

[21]. Paulovic, J.; Cimpoesu, F.; Ferbinteanu, M.; Hirao, K. J. Am. Chem. Soc. 2004, 126, 3321-3331.
https://doi.org/10.1021/ja030628k

[22]. Mishra, A.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. J. Am. Chem. Soc. 2004, 126, 15648-15649.
https://doi.org/10.1021/ja0452727

[23]. Vigato, P. A.; Tamburini S. Coord. Chem. Rev. 2004, 248, 1717-2128.
https://doi.org/10.1016/j.cct.2003.09.003

[24]. Maurice, R.; Vendier, L.; Costes, J. -P. Inorg. Chem. 2011, 50, 11075-11081.
https://doi.org/10.1021/ic201623e

[25]. Bruker, 2016, APEX3, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.

[26]. Sheldrick, G. M. Acta Cryst. A 2015, 71, 3-8.
https://doi.org/10.1107/S2053273314026370

[27]. Sheldrick, G. M. Acta Cryst. C 2015, 71, 3-8.
https://doi.org/10.1107/S2053229614024218

[28]. Farrugia, L. J. J. Appl. Cryst. 2012, 45, 849-854.
https://doi.org/10.1107/S0021889812029111

[29]. Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J.; Verschoor, G. C. J. Chem. Soc. Dalton Trans. 1984, 1349-1356.
https://doi.org/10.1039/DT9840001349

[30]. Geary, W. J. Coord. Chem. Rev. 1971, 7, 81-122.
https://doi.org/10.1016/S0010-8545(00)80009-0

[31]. Masoudias, A.; Montazerozohori, M.; Naghiha, R.; Assoud, A.; McArdle, P.; Shalamzari, M. S. Mater. Sci. Eng., C 2016, 61, 809-823.
https://doi.org/10.1016/j.msec.2016.01.017

[32]. Basak, S.; Sen, S.; Banerjee, S.; Mitra, S.; Rosair, G.; Rodriguez, M. T. G. Polyhedron 2007, 26, 5104-5112.
https://doi.org/10.1016/j.poly.2007.07.025

[33]. Li, H. H.; You, Z. L.; Zhang, C. L.; Yang, M.; Gao, L. N.; Wang, L. Inorg. Chem. Commun. 2013, 29, 118-122.
https://doi.org/10.1016/j.inoche.2012.12.023

[34]. Sutter, J. P.; Dhers, S.; Costes, J. P.; Duhayon, C. C. R. Chimie 2008, 11, 1200-1206.
https://doi.org/10.1016/j.crci.2008.04.015


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Sarr, M.; Diop, M.; Thiam, I.; Gaye, M.; Barry, A.; Alvarez, N.; Ellena, J. Eur. J. Chem. 2018, 9(2), 67-73. doi:10.5155/eurjchem.9.2.67-73.1688
Sarr, M.; Diop, M.; Thiam, I.; Gaye, M.; Barry, A.; Alvarez, N.; Ellena, J. Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand. Eur. J. Chem. 2018, 9(2), 67-73. doi:10.5155/eurjchem.9.2.67-73.1688
Sarr, M., Diop, M., Thiam, I., Gaye, M., Barry, A., Alvarez, N., & Ellena, J. (2018). Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand. European Journal of Chemistry, 9(2), 67-73. doi:10.5155/eurjchem.9.2.67-73.1688
Sarr, Mamour, Mayoro Diop, Ibrahima Elhadj Thiam, Mohamed Gaye, Aliou Hamady Barry, Natalia Alvarez, & Javier Ellena. "Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand." European Journal of Chemistry [Online], 9.2 (2018): 67-73. Web. 17 Jun. 2021
Sarr, Mamour, Diop, Mayoro, Thiam, Ibrahima, Gaye, Mohamed, Barry, Aliou, Alvarez, Natalia, AND Ellena, Javier. "Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand" European Journal of Chemistry [Online], Volume 9 Number 2 (30 June 2018)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.9.2.67-73.1688

CrossRef | Scilit | GrowKudos | Researchgate | Publons | Microsoft | scibey | Scite | Lens | OUCI

WorldCat Paperbuzz Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2018, 9(2), 67-73 | doi: https://doi.org/10.5155/eurjchem.9.2.67-73.1688 | Get rights and content

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c) 2018 Authors

Creative Commons License
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).


© Copyright 2010 - 2021 • Atlanta Publishing House LLC • All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2021 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.