European Journal of Chemistry 2019, 10(3), 201-208 | doi: https://doi.org/10.5155/eurjchem.10.3.201-208.1881 | Get rights and content

Issue cover




Crossmark

  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis, spectroscopic studies and X-ray structure determination of two mononuclear copper complexes derived from the Schiff base ligand N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene)ethane-1,2-diamine


Pokpa Haba (1) orcid , Adama Sy (2) orcid , Farba Bouyagui Tamboura (3) orcid , Mamour Sarr (4) orcid , Ibrahima Elhadji Thiam (5) orcid , Aliou Hamady Barry (6) orcid , Mohamed Lamine Sall (7) orcid , Mohamed Gaye (8,*) orcid , Pascal Retailleau (9) orcid

(1) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(2) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(3) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(4) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(5) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(6) Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania
(7) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(8) Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal
(9) Institut de Chimie des Substances Naturelles, CNRS UPR 2301, Université Paris-Sud, Université Paris-Saclay, 1, av. de la Terrasse, 91198 Gif-sur-Yvette, France
(*) Corresponding Author

Received: 15 Apr 2019 | Revised: 02 Jul 2019 | Accepted: 05 Jul 2019 | Published: 30 Sep 2019 | Issue Date: September 2019

Abstract


Reactions of the Schiff base N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene) ethane-1,2-diamine (HL), synthesised in situ, with chloride or thiocyanate copper (II) salt; afforded two new mononuclear complexes, [Cu(HL)Cl2]·H2O (1) and [Cu(HL)(SCN)2] (2). These compounds have been studied and characterized by elemental analysis, IR and UV-Vis spectroscopies, electrochemistry, molar conductivity and room temperature magnetic measurements. Single crystal X-ray structure determination of the complexes revealed the presence of neutral moieties in the asymmetric unit. The mononuclear (1) crystallises in the monoclinic space group P21/c with the following unit cell parameters a = 7.4355(3) Å, b = 7.2952(3) Å, c = 26.2729(11) Å, β = 93.461(4)°, V = 1422.52(10) Å3, Z = 4, R1 = 0.033 and wR2 = 0.082 and the mononuclear complex (2) crystallises in the monoclinic space group C2/c with the following unit cell parameters a = 26.2578(7) Å, b = 7.4334(2) Å, c = 16.6237(5) Å, β = 99.089(3)°, V = 3203.95(16) Å3, Z = 8, R1 = 0.037 and wR2 = 0.104. In both complexes the ligand acts in tridentate fashion and the coordination environment of the copper atom can be described as distorted square pyramidal. The crystal lattice of the complex 1 is stabilized by electrostatic forces of attraction and O–H···Cl, C–H···O, N–H···Cl, and C–H···Cl, hydrogen bonding interactions while the crystal lattice of the complex 2 is stabilized by N–H···S and C–H···N.


Announcements


Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.

1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization or a DFT study between September 15, 2023 and October 31, 2023 (Voucher code: FALL2023).

2. A 50% discount will be applied to the article processing fee for submissions made between September 15, 2023 and October 31, 2023 by authors who have at least one publication in the European Journal of Chemistry (Voucher code: AUTHOR-3-2023).

3. Young writers will not be charged for the article processing fee between September 15, 2023 and October 31, 2023 (Voucher code: YOUNG2023).

Editor-in-Chief
European Journal of Chemistry

Keywords


Complex; Schiff base; Thiocyanate; Mononuclear; Square pyramidal; Single crystal structure

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.10.3.201-208.1881

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 1634 times | icon graph PDF Article downloaded 568 times

Funding information


FONDATION SONATEL, http://fondationsonatel.sn/

Citations

/


References


[1]. Li, H. G.; Yang, Z. Y.; Qin, D. D. Inorg. Chem. Commun. 2009, 12, 494-497.
https://doi.org/10.1016/j.inoche.2009.04.003

[2]. Konar, S.; Jana, A.; Das, K.; Ray, S.; Chatterjee, S.; Golen, J. A.; Rheingold, A. L.; Kar, S. K. Polyhedron 2011, 30, 2801-2808.
https://doi.org/10.1016/j.poly.2011.08.018

[3]. Konar, S.; Jana, A.; Das, K.; Ray, S.; Chatterjee, S.; Kar, S. K. Inorg. Chim. Acta 2013, 395, 1-10.
https://doi.org/10.1016/j.ica.2012.10.013

[4]. Feng, X. D.; Zhang, R.; Wang, X. Y.; Zhang, X. X.; Wang, J. X.; Xing, Y. H.; Sun, L. X. Polyhedron 2015, 90, 69-76.
https://doi.org/10.1016/j.poly.2015.01.038

[5]. Valentova, J.; Varenyi, S.; Herich, P.; Baran, P.; Bilkova, A.; Kozisek, J.; Habala, L. Inorg. Chim. Acta 2018, 480, 16-26.
https://doi.org/10.1016/j.ica.2018.04.058

[6]. Mandal, S.; Das, M.; Das, P.; Samanta, A.; Butcher, R. J.; Saha, M.; Alswaidan, I. A.; Rhyman, L.; Ramasami, P.; Saha, N. C. J. Mol. Struct. 2019, 1178, 100-111.
https://doi.org/10.1016/j.molstruc.2018.09.095

[7]. Saha, N. C.; Mandal, S.; Das, M.; Khatun, N.; Mitra, D.; Samanta, A.; Slawin, A. M. Z.; Butcher, R. J.; Saha, R. Polyhedron 2014, 68, 122-130.
https://doi.org/10.1016/j.poly.2013.10.016

[8]. Zarei, L.; Asadi, Z.; Dusek, M.; Eigner, V. J. Photoch. Photobio. A 2019, 374, 145-160.
https://doi.org/10.1016/j.jphotochem.2019.02.001

[9]. Kruger, P. E.; Moubaraki, B.; Murray K. S. Polyhedron 1997, 16, 2659-2665.
https://doi.org/10.1016/S0277-5387(96)00596-7

[10]. Puterova-Tokarova, Z.; Mrazova, V.; Boca, R. Polyhedron 2013, 61, 87-93.
https://doi.org/10.1016/j.poly.2013.05.045

[11]. Okeke, U. C.; Gultneh, Y.; Otchere, R.; Butcher, R. J. Inorg. Chem. Commun. 2018, 97, 1-6.
https://doi.org/10.1016/j.inoche.2018.08.024

[12]. Bhattacharjee, A.; Dey, S.; Roy, P. Inorg. Chim. Acta 2019, 490, 93-103.
https://doi.org/10.1016/j.ica.2019.03.005

[13]. Jawoor, S. S.; Patil, S. A.; Kumbar, M.; Ramawadgi, P. B. J. Mol. Struct. 2018, 1164, 378-385.
https://doi.org/10.1016/j.molstruc.2018.03.084

[14]. Tohidiyan, Z.; Sheikhshoaie, I.; Khaleghi, M.; Mague, J. T. J. Mol. Struct. 2017, 1134, 706-714.
https://doi.org/10.1016/j.molstruc.2017.01.026

[15]. Alothman, A. A.; Al-Farraj, E. S.; Al-Onazi, W. A.; Almarhoon, Z. M.; Al-Mohaimeed, A. M. Arab. J. Chem. 2019, https://doi.org/10.1016/ j.arabjc.2019.02.003

[16]. Mahmood, K.; Hashmi, W.; Ismail, H.; Mirza, B.; Twamley, B.; Akhter, Z.; Rozas, I.; Baker, R. J. Polyhedron 2019, 157, 326-334.
https://doi.org/10.1016/j.poly.2018.10.020

[17]. Ainscough, E. W.; Brodie, A. M.; Dobbs, A. J.; Ranford, J. D.; Waters, J. M. Inorg. Chim. Acta 1998, 267, 27-38.

[18]. Anuradha; Kumari, S.; Pathak, D. D. Tetrahedron Lett. 2015, 56, 4135-4142.
https://doi.org/10.1016/j.tetlet.2015.05.049

[19]. Solomon, E. I.; Heppner, D. E.; Johnston, E. M.; Ginsbach, J. W.; Cirera, J.; Qayyum, M.; Kieber-Emmons, M. T.; Kjaergaard, C. H.; Hadt, R. G.; Tian, L. Chem. Rev. 2014, 114, 3659-3853.
https://doi.org/10.1021/cr400327t

[20]. Tamboura, F. B.; Gaye, M.; Sall, A. S.; Barry, A. H.; Jouini, T. Inorg. Chem. Commun. 2002, 5, 235-238.
https://doi.org/10.1016/S1387-7003(02)00348-9

[21]. Casas, J. S.; Castellano, E. E.; Barros, F. J. G.; Sanchez, A.; Gonzales, A. S.; Sordo, J.; Zuckerman-Schpector, J. J. Organomet. Chem. 1996, 519, 209-216.
https://doi.org/10.1016/S0022-328X(96)06246-8

[22]. Abuhijleh, A. L. J. Mol. Struct. 2010, 980, 201-207.
https://doi.org/10.1016/j.molstruc.2010.07.014

[23]. Puchonova, M.; Matejova, S.; Jorik, V.; Salitros, I.; Svorc, L.; Mazur, M.; Moncol, J.; Valigura, D. Polyhedron 2018, 151, 152-159.
https://doi.org/10.1016/j.poly.2018.05.036

[24]. Sheldrick, G. M. Acta Crystallogr. A 2015, 71, 3-8.
https://doi.org/10.1107/S2053273314026370

[25]. Sheldrick, G. M. Acta Crystallogr. C 2015, 71, 3-8.
https://doi.org/10.1107/S2053273314026370

[26]. Farrugia, L. J. J. Appl. Crystallogr. 2012, 45, 849-854.
https://doi.org/10.1107/S0021889812029111

[27]. Singh, A. K.; Pandey, O. P.; Sengupta, S. K. Spectrochim. Acta. A 2013, 113, 393-399.
https://doi.org/10.1016/j.saa.2013.04.045

[28]. Saghatforoush, L. A.; Hosseinpour, S.; Bezpalko, M. W.; Kassel, W. S. Inorg. Chim. Acta 2019, 484, 527-534.
https://doi.org/10.1016/j.ica.2018.04.053

[29]. Handy, J. V.; Ayala, G.; Pike, R. D. Inorg. Chim. Acta 2017, 456, 64-75.
https://doi.org/10.1016/j.ica.2016.11.013

[30]. Sadhu, M. H.; Solanki, A.; Kumar, S. B. Polyhedron 2015, 100, 206-214.
https://doi.org/10.1016/j.poly.2015.07.067

[31]. Safaei, E.; Bahrami, H.; Pevec, A.; Kozlevcar, B.; Jaglicic, Z. J. Mol. Struct. 2017, 1133, 526-533.
https://doi.org/10.1016/j.molstruc.2016.11.076

[32]. Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J.; Verschoor, G. C. J. Chem. Soc. Dalton 1984, 1349-1356.
https://doi.org/10.1039/DT9840001349

[33]. Avci, D.; Alturk, S.; Sonmez, F.; Tamer, O.; Basoglu, A.; Atalay, Y.; Kurt, B. Z.; Dege, N. Tetrahedron 2018, 74, 7198-7208.
https://doi.org/10.1016/j.tet.2018.10.054

[34]. Fujisawa, K.; Tobita, K.; Sakuma, S.; Savard, D.; Leznoff, D. B. Inorg. Chim. Acta 2019, 486, 582-588.
https://doi.org/10.1016/j.ica.2018.10.036

[35]. Castillo, I.; Ugalde-Saldivar, V. M.; Rodriguez Solano, L. A.; Sanchez Eguia, B. N.; Zeglio, E.; Nordlander, E. Dalton Trans. 2012, 41, 9394-9404.
https://doi.org/10.1039/c2dt30756a

[36]. Mendoza, A.; Mendoza-Diaz, G.; Pedraza-Reyes, M.; Bernes, S. Z. Anorg. Allg. Chem. 2013, 639, 1455-1460.
https://doi.org/10.1002/zaac.201300082

[37]. Driessen, W. L.; Rehorst, D.; Reedijk, J.; Mutikainen, I.; Turpeinen, U. Inorg. Chim. Acta 2003, 355, 64-68.
https://doi.org/10.1016/S0020-1693(03)00224-X

[38]. Thomas Steiner, T. Crystallogr. Rev. 2003, 9, 177-228.
https://doi.org/10.1080/08893110310001621772

[39]. Sadhu, M. H.; Kumar, S. B. J. Mol. Struct. 2018, 1164, 239-247.
https://doi.org/10.1016/j.molstruc.2018.03.040

[40]. Sarr, M.; Diop, M.; Thiam, I.; Gaye, M.; Barry, A.; Alvarez, N.; Ellena, J. Eur. J. Chem. 2018, 9(2), 67-73.
https://doi.org/10.5155/eurjchem.9.2.67-73.1688

[41]. Anson, F. C.; Collins, T. J.; Richmond, T. G.; Santarsiero, B. D.; Toth, J. E.; Treco B. G. R. T. J. Am. Chem. Soc. 1987, 109, 2974-2919.
https://doi.org/10.1021/ja00244a020


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Haba, P.; Sy, A.; Tamboura, F.; Sarr, M.; Thiam, I.; Barry, A.; Sall, M.; Gaye, M.; Retailleau, P. Eur. J. Chem. 2019, 10(3), 201-208. doi:10.5155/eurjchem.10.3.201-208.1881
Haba, P.; Sy, A.; Tamboura, F.; Sarr, M.; Thiam, I.; Barry, A.; Sall, M.; Gaye, M.; Retailleau, P. Synthesis, spectroscopic studies and X-ray structure determination of two mononuclear copper complexes derived from the Schiff base ligand N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene)ethane-1,2-diamine. Eur. J. Chem. 2019, 10(3), 201-208. doi:10.5155/eurjchem.10.3.201-208.1881
Haba, P., Sy, A., Tamboura, F., Sarr, M., Thiam, I., Barry, A., Sall, M., Gaye, M., & Retailleau, P. (2019). Synthesis, spectroscopic studies and X-ray structure determination of two mononuclear copper complexes derived from the Schiff base ligand N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene)ethane-1,2-diamine. European Journal of Chemistry, 10(3), 201-208. doi:10.5155/eurjchem.10.3.201-208.1881
Haba, Pokpa, Adama Sy, Farba Bouyagui Tamboura, Mamour Sarr, Ibrahima Elhadji Thiam, Aliou Hamady Barry, Mohamed Lamine Sall, Mohamed Gaye, & Pascal Retailleau. "Synthesis, spectroscopic studies and X-ray structure determination of two mononuclear copper complexes derived from the Schiff base ligand N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene)ethane-1,2-diamine." European Journal of Chemistry [Online], 10.3 (2019): 201-208. Web. 30 Nov. 2023
Haba, Pokpa, Sy, Adama, Tamboura, Farba, Sarr, Mamour, Thiam, Ibrahima, Barry, Aliou, Sall, Mohamed, Gaye, Mohamed, AND Retailleau, Pascal. "Synthesis, spectroscopic studies and X-ray structure determination of two mononuclear copper complexes derived from the Schiff base ligand N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene)ethane-1,2-diamine" European Journal of Chemistry [Online], Volume 10 Number 3 (30 September 2019)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.10.3.201-208.1881


CrossRef | Scilit | GrowKudos | Researchgate | Publons | ScienceGate | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2019, 10(3), 201-208 | doi: https://doi.org/10.5155/eurjchem.10.3.201-208.1881 | Get rights and content

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c) 2019 Authors

Creative Commons License
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).


© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.