Synthesis, spectroscopic studies and X-ray structure determination of two mononuclear copper complexes derived from the Schiff base ligand N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene)ethane-1,2-diamine | European Journal of Chemistry

Default Image

PDF CIF FILE CIF FILE

Published: Sep 30, 2019

DOI: https://doi.org/10.5155/eurjchem.10.3.201-208.1881

Keywords:

Complex, Schiff base, Thiocyanate, Mononuclear, Square pyramidal, Single crystal structure

Section

Research Article

Issue

Vol. 10 No. 3 (2019): September 2019

Dates

Received 2019-04-15
Accepted 2019-07-05
Published 2019-09-30

Crossmark

Pokpa Haba

eMail

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal

http://orcid.org/0000-0002-9935-0515

Adama Sy

eMail

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal

http://orcid.org/0000-0002-3178-0148

Farba Bouyagui Tamboura

eMail

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal

http://orcid.org/0000-0002-1108-0718

Mamour Sarr

eMail

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal

http://orcid.org/0000-0003-1736-951X

Ibrahima Elhadji Thiam

eMail

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal

http://orcid.org/0000-0002-4595-8445

Aliou Hamady Barry

eMail

Department of Chemistry, University of Nouakchott, Nouakchott, 130301, Mauritania

http://orcid.org/0000-0003-4869-2993

Mohamed Lamine Sall

eMail

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal

http://orcid.org/0000-0003-2357-5811

Mohamed Gaye

eMail

Department of Chemistry, University Cheikh Anta Diop, Dakar, 10700, Sénégal

http://orcid.org/0000-0001-8989-1548

Pascal Retailleau

eMail

Institut de Chimie des Substances Naturelles, CNRS UPR 2301, Université Paris-Sud, Université Paris-Saclay, 1, av. de la Terrasse, 91198 Gif-sur-Yvette, France

http://orcid.org/0000-0003-3995-519X

Abstract

Reactions of the Schiff base N,N-dimethyl-N'-((5-methyl-1H-imidazol-4-yl)methylene) ethane-1,2-diamine (HL), synthesised in situ, with chloride or thiocyanate copper (II) salt; afforded two new mononuclear complexes, [Cu(HL)Cl₂]·H₂O (1) and [Cu(HL)(SCN)₂] (2). These compounds have been studied and characterized by elemental analysis, IR and UV-Vis spectroscopies, electrochemistry, molar conductivity and room temperature magnetic measurements. Single crystal X-ray structure determination of the complexes revealed the presence of neutral moieties in the asymmetric unit. The mononuclear (1) crystallises in the monoclinic space group P2₁/c with the following unit cell parameters a = 7.4355(3) Å, b = 7.2952(3) Å, c = 26.2729(11) Å, β = 93.461(4)°, V = 1422.52(10) Å³, Z = 4, R₁ = 0.033 and wR₂ = 0.082 and the mononuclear complex (2) crystallises in the monoclinic space group C2/c with the following unit cell parameters a = 26.2578(7) Å, b = 7.4334(2) Å, c = 16.6237(5) Å, β = 99.089(3)°, V = 3203.95(16) Å³, Z = 8, R₁ = 0.037 and wR₂ = 0.104. In both complexes the ligand acts in tridentate fashion and the coordination environment of the copper atom can be described as distorted square pyramidal. The crystal lattice of the complex 1 is stabilized by electrostatic forces of attraction and O–H···Cl, C–H···O, N–H···Cl, and C–H···Cl, hydrogen bonding interactions while the crystal lattice of the complex 2 is stabilized by N–H···S and C–H···N.

This Abstract was viewed 2075 times |

Article PDF downloaded 868 times

Article CIF FILE downloaded 0 times

Article CIF FILE downloaded 0 times

How to Cite

(1)

Haba, P.; Sy, A.; Tamboura, F. B.; Sarr, M.; Thiam, I. E.; Barry, A. H.; Sall, M. L.; Gaye, M.; Retailleau, P. Synthesis, Spectroscopic Studies and X-Ray Structure Determination of Two Mononuclear Copper Complexes Derived from the Schiff Base Ligand N,N-Dimethyl-N’-(5-Methyl-1H-Imidazol-4-yl)methylene)ethane-1,2-Diamine. Eur. J. Chem. 2019, 10, 201-208.

Share

Links for Article

Crossref - Scopus - Google - European PMC

Crossref

Scopus

Google Scholar

Europe PMC

References

[1]. Li, H. G.; Yang, Z. Y.; Qin, D. D. Inorg. Chem. Commun. 2009, 12, 494-497.
https://doi.org/10.1016/j.inoche.2009.04.003

[2]. Konar, S.; Jana, A.; Das, K.; Ray, S.; Chatterjee, S.; Golen, J. A.; Rheingold, A. L.; Kar, S. K. Polyhedron 2011, 30, 2801-2808.
https://doi.org/10.1016/j.poly.2011.08.018

[3]. Konar, S.; Jana, A.; Das, K.; Ray, S.; Chatterjee, S.; Kar, S. K. Inorg. Chim. Acta 2013, 395, 1-10.
https://doi.org/10.1016/j.ica.2012.10.013

[4]. Feng, X. D.; Zhang, R.; Wang, X. Y.; Zhang, X. X.; Wang, J. X.; Xing, Y. H.; Sun, L. X. Polyhedron 2015, 90, 69-76.
https://doi.org/10.1016/j.poly.2015.01.038

[5]. Valentova, J.; Varenyi, S.; Herich, P.; Baran, P.; Bilkova, A.; Kozisek, J.; Habala, L. Inorg. Chim. Acta 2018, 480, 16-26.
https://doi.org/10.1016/j.ica.2018.04.058

[6]. Mandal, S.; Das, M.; Das, P.; Samanta, A.; Butcher, R. J.; Saha, M.; Alswaidan, I. A.; Rhyman, L.; Ramasami, P.; Saha, N. C. J. Mol. Struct. 2019, 1178, 100-111.
https://doi.org/10.1016/j.molstruc.2018.09.095

[7]. Saha, N. C.; Mandal, S.; Das, M.; Khatun, N.; Mitra, D.; Samanta, A.; Slawin, A. M. Z.; Butcher, R. J.; Saha, R. Polyhedron 2014, 68, 122-130.
https://doi.org/10.1016/j.poly.2013.10.016

[8]. Zarei, L.; Asadi, Z.; Dusek, M.; Eigner, V. J. Photoch. Photobio. A 2019, 374, 145-160.
https://doi.org/10.1016/j.jphotochem.2019.02.001

[9]. Kruger, P. E.; Moubaraki, B.; Murray K. S. Polyhedron 1997, 16, 2659-2665.
https://doi.org/10.1016/S0277-5387(96)00596-7

[10]. Puterova-Tokarova, Z.; Mrazova, V.; Boca, R. Polyhedron 2013, 61, 87-93.
https://doi.org/10.1016/j.poly.2013.05.045

[11]. Okeke, U. C.; Gultneh, Y.; Otchere, R.; Butcher, R. J. Inorg. Chem. Commun. 2018, 97, 1-6.
https://doi.org/10.1016/j.inoche.2018.08.024

[12]. Bhattacharjee, A.; Dey, S.; Roy, P. Inorg. Chim. Acta 2019, 490, 93-103.
https://doi.org/10.1016/j.ica.2019.03.005

[13]. Jawoor, S. S.; Patil, S. A.; Kumbar, M.; Ramawadgi, P. B. J. Mol. Struct. 2018, 1164, 378-385.
https://doi.org/10.1016/j.molstruc.2018.03.084

[14]. Tohidiyan, Z.; Sheikhshoaie, I.; Khaleghi, M.; Mague, J. T. J. Mol. Struct. 2017, 1134, 706-714.
https://doi.org/10.1016/j.molstruc.2017.01.026

[15]. Alothman, A. A.; Al-Farraj, E. S.; Al-Onazi, W. A.; Almarhoon, Z. M.; Al-Mohaimeed, A. M. Arab. J. Chem. 2019, https://doi.org/10.1016/ j.arabjc.2019.02.003

[16]. Mahmood, K.; Hashmi, W.; Ismail, H.; Mirza, B.; Twamley, B.; Akhter, Z.; Rozas, I.; Baker, R. J. Polyhedron 2019, 157, 326-334.
https://doi.org/10.1016/j.poly.2018.10.020

[17]. Ainscough, E. W.; Brodie, A. M.; Dobbs, A. J.; Ranford, J. D.; Waters, J. M. Inorg. Chim. Acta 1998, 267, 27-38.

[18]. Anuradha; Kumari, S.; Pathak, D. D. Tetrahedron Lett. 2015, 56, 4135-4142.
https://doi.org/10.1016/j.tetlet.2015.05.049

[19]. Solomon, E. I.; Heppner, D. E.; Johnston, E. M.; Ginsbach, J. W.; Cirera, J.; Qayyum, M.; Kieber-Emmons, M. T.; Kjaergaard, C. H.; Hadt, R. G.; Tian, L. Chem. Rev. 2014, 114, 3659-3853.
https://doi.org/10.1021/cr400327t

[20]. Tamboura, F. B.; Gaye, M.; Sall, A. S.; Barry, A. H.; Jouini, T. Inorg. Chem. Commun. 2002, 5, 235-238.
https://doi.org/10.1016/S1387-7003(02)00348-9

[21]. Casas, J. S.; Castellano, E. E.; Barros, F. J. G.; Sanchez, A.; Gonzales, A. S.; Sordo, J.; Zuckerman-Schpector, J. J. Organomet. Chem. 1996, 519, 209-216.
https://doi.org/10.1016/S0022-328X(96)06246-8

[22]. Abuhijleh, A. L. J. Mol. Struct. 2010, 980, 201-207.
https://doi.org/10.1016/j.molstruc.2010.07.014

[23]. Puchonova, M.; Matejova, S.; Jorik, V.; Salitros, I.; Svorc, L.; Mazur, M.; Moncol, J.; Valigura, D. Polyhedron 2018, 151, 152-159.
https://doi.org/10.1016/j.poly.2018.05.036

[24]. Sheldrick, G. M. Acta Crystallogr. A 2015, 71, 3-8.
https://doi.org/10.1107/S2053273314026370

[25]. Sheldrick, G. M. Acta Crystallogr. C 2015, 71, 3-8.
https://doi.org/10.1107/S2053273314026370

[26]. Farrugia, L. J. J. Appl. Crystallogr. 2012, 45, 849-854.
https://doi.org/10.1107/S0021889812029111

[27]. Singh, A. K.; Pandey, O. P.; Sengupta, S. K. Spectrochim. Acta. A 2013, 113, 393-399.
https://doi.org/10.1016/j.saa.2013.04.045

[28]. Saghatforoush, L. A.; Hosseinpour, S.; Bezpalko, M. W.; Kassel, W. S. Inorg. Chim. Acta 2019, 484, 527-534.
https://doi.org/10.1016/j.ica.2018.04.053

[29]. Handy, J. V.; Ayala, G.; Pike, R. D. Inorg. Chim. Acta 2017, 456, 64-75.
https://doi.org/10.1016/j.ica.2016.11.013

[30]. Sadhu, M. H.; Solanki, A.; Kumar, S. B. Polyhedron 2015, 100, 206-214.
https://doi.org/10.1016/j.poly.2015.07.067

[31]. Safaei, E.; Bahrami, H.; Pevec, A.; Kozlevcar, B.; Jaglicic, Z. J. Mol. Struct. 2017, 1133, 526-533.
https://doi.org/10.1016/j.molstruc.2016.11.076

[32]. Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J.; Verschoor, G. C. J. Chem. Soc. Dalton 1984, 1349-1356.
https://doi.org/10.1039/DT9840001349

[33]. Avci, D.; Alturk, S.; Sonmez, F.; Tamer, O.; Basoglu, A.; Atalay, Y.; Kurt, B. Z.; Dege, N. Tetrahedron 2018, 74, 7198-7208.
https://doi.org/10.1016/j.tet.2018.10.054

[34]. Fujisawa, K.; Tobita, K.; Sakuma, S.; Savard, D.; Leznoff, D. B. Inorg. Chim. Acta 2019, 486, 582-588.
https://doi.org/10.1016/j.ica.2018.10.036

[35]. Castillo, I.; Ugalde-Saldivar, V. M.; Rodriguez Solano, L. A.; Sanchez Eguia, B. N.; Zeglio, E.; Nordlander, E. Dalton Trans. 2012, 41, 9394-9404.
https://doi.org/10.1039/c2dt30756a

[36]. Mendoza, A.; Mendoza-Diaz, G.; Pedraza-Reyes, M.; Bernes, S. Z. Anorg. Allg. Chem. 2013, 639, 1455-1460.
https://doi.org/10.1002/zaac.201300082

[37]. Driessen, W. L.; Rehorst, D.; Reedijk, J.; Mutikainen, I.; Turpeinen, U. Inorg. Chim. Acta 2003, 355, 64-68.
https://doi.org/10.1016/S0020-1693(03)00224-X

[38]. Thomas Steiner, T. Crystallogr. Rev. 2003, 9, 177-228.
https://doi.org/10.1080/08893110310001621772

[39]. Sadhu, M. H.; Kumar, S. B. J. Mol. Struct. 2018, 1164, 239-247.
https://doi.org/10.1016/j.molstruc.2018.03.040

[40]. Sarr, M.; Diop, M.; Thiam, I.; Gaye, M.; Barry, A.; Alvarez, N.; Ellena, J. Eur. J. Chem. 2018, 9(2), 67-73.
https://doi.org/10.5155/eurjchem.9.2.67-73.1688

[41]. Anson, F. C.; Collins, T. J.; Richmond, T. G.; Santarsiero, B. D.; Toth, J. E.; Treco B. G. R. T. J. Am. Chem. Soc. 1987, 109, 2974-2919.
https://doi.org/10.1021/ja00244a020

Supporting Agencies

FONDATION SONATEL, http, //fondationsonatel.sn/

Most read articles by the same author(s)

Most read articles by the same author(s)

Amadou Gueye, Farba Bouyagui Tamboura, Jean-Marc Planeix, Nathalie Gruber, Mohamed Gaye, Synthesis and spectroscopic study of transition metal complexes of tridentate ligand formed by direct condensation of o-vanillin and 2-aminophenol: X-ray structural characterization of the zinc(II) complex , European Journal of Chemistry: Vol. 9 No. 4 (2018): December 2018
Mamour Sarr, Mayoro Diop, Ibrahima Elhadj Thiam, Mohamed Gaye, Aliou Hamady Barry, Natalia Alvarez, Javier Ellena, Co-crystal structure of a dinuclear (Zn-Y) and a trinuclear (Zn-Y-Zn) complexes derived from a Schiff base ligand , European Journal of Chemistry: Vol. 9 No. 2 (2018): June 2018
Mbosse Ndiaye Gueye, Moussa Dieng, Djiby Lo, Ibrahima Elhadji Thiam, Aliou Hamady Barry, Mohamed Gaye, Abdou Salam Sall, Pascal Retailleau, Synthesis, physical studies and crystal structure determination of Y(III) and Er(III) complexes of 1-(pyridin-2-yl)-2-(pyridine-2-ylmethylene)hydrazine , European Journal of Chemistry: Vol. 8 No. 2 (2017): June 2017
Thierno Moussa Seck, Fatou Dieng Faye, Aissatou Alioune Gaye, Ibrahima Elhadji Thiam, Ousmane Diouf, Mohamed Gaye, Pascal Retailleau, Synthesis of mono and bis-substituted asymmetrical compounds, (1-(pyridin-2-yl)ethylidene)carbonohydrazide and 1-(2'-hydroxybenzylidene)-5-(1'-pyridylethylidene)carbonohydrazone: Structural characterization and antioxidant activity study , European Journal of Chemistry: Vol. 11 No. 4 (2020): December 2020
Moussa Faye, Mouhamadou Moustapha Sow, Papa Aly Gaye, Moussa Dieng, Mohamed Gaye, Crystal structures of bis-{N-[1-(pyridin-2-yl-κN)ethylidene]nicotine hydrazide-κ2N’,O}cobalt(II)bis(perchlorate) dihydrate and bis-{N'-[1-(pyridin-2-yl-κN)ethylidene]nicotinohydrazide-κ2N',O}copper(II) perchlorate , European Journal of Chemistry: Vol. 12 No. 2 (2021): June 2021
Modou Lo, Andrea Martínez, Hugo Santalla, Fátima Garrido, Aliou Hamady Barry, Mohamed Gaye, Synthesis and X-ray crystallography of (1R,3aR,7aR)-1-((S)-1-((2R,5S)-5-(3-hydroxypentan-3-yl)tetrahydrofuran-2-yl)ethyl)-7a-methyloctahydro-4H-inden-4-one , European Journal of Chemistry: Vol. 8 No. 3 (2017): September 2017
Cheikh Ndoye, Gregory Excoffier, Gorgui Awa Seck, Ousmane Diouf, IbraIbrahima Elhadji Thiam, Mamadou Sidibe, Mohamed Gaye, Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate, bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II) , European Journal of Chemistry: Vol. 13 No. 2 (2022): June 2022

TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).