Synthesis and spectroscopic study of transition metal complexes of tridentate ligand formed by direct condensation of o-vanillin and 2-aminophenol: X-ray structural characterization of the zinc(II) complex

Amadou Gueye; Farba Bouyagui Tamboura; Jean-Marc Planeix; Nathalie Gruber; Mohamed Gaye

doi:10.5155/eurjchem.9.4.281-286.1761

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Published: Dec 31, 2018

DOI: https://doi.org/10.5155/eurjchem.9.4.281-286.1761

Keywords:

Schiff base, Benzaldehyde, Metal complexes, Trigonal bipyramidal, X-ray crystallography, Single crystal structure

Section

Research Article

Issue

Vol. 9 No. 4 (2018): December 2018

Dates

Received 2018-06-09
Accepted 2018-08-28
Published 2018-12-31

Amadou Gueye

Department of Chemistry, University Cheikh Anta Diop, Dakar 12500, Senegal

http://orcid.org/0000-0002-3854-114X

Farba Bouyagui Tamboura

Department of Chemistry, University Alioune DIOP, Bambey 21400, Senegal

http://orcid.org/0000-0002-1108-0718

Jean-Marc Planeix

Laboratoire de Tectonique Moléculaire du Solide (UMR 7140), Chimie de la Matière Complexe, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, F-67008 Strasbourg, France

http://orcid.org/0000-0001-7414-0119

Nathalie Gruber

Laboratoire de Tectonique Moléculaire du Solide (UMR 7140), Chimie de la Matière Complexe, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, F-67008 Strasbourg, France

http://orcid.org/0000-0003-4986-2931

Mohamed Gaye

Department of Chemistry, University Cheikh Anta Diop, Dakar 12500, Senegal

http://orcid.org/0000-0001-8989-1548

Abstract

The reactions of the Schiff base 2-((2-hydroxyphenylimino)methyl)-6-methoxyphenol (H₂L), obtained by direct condensation of 2-aminophenol and 2-hydroxy-3-methoxybenzaldehyde, with some transition metal ions (Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)) afforded complexes of general formulae [M₂(L)₂(solvent)_x] (M: Mn, Co, Ni, Cu or Zn; Solvent: DMSO or H₂O). These compounds were characterized by elemental analysis, UV-Vis, IR, ¹H- and ¹³C-NMR spectroscopies, molar conductivity and room temperature magnetic measurements. The structure of zinc(II) complex has been determined by X-ray crystallography. Crystal data for C₃₂H₃₄N₂O₈S₂Zn₂ (M =769.47 g/mol): Orthorhombic, space group Pbca (no. 61), a = 16.3176(7) Å, b = 9.1247(3) Å, c = 21.8274(10) Å, V = 3250.0(2) Å³, Z = 4, T = 173(2) K, μ(MoKα) = 1.658 mm^-1, D_calc= 1.573 g/cm³, 28116 reflections measured (4.5° ≤ 2Θ ≤ 60.3°), 4457 unique (R_int = 0.0409, R_sigma = 0.0371) which were used in all calculations. The final R₁ was 0.0307(0.0466) and wR₂ was 0.0649 (0.0701) (all data). The coordination sphere of the Zn center is best described as a trigonal bipyramid.

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Gueye, A.; Tamboura, F. B.; Planeix, J.-M.; Gruber, N.; Gaye, M. Synthesis and Spectroscopic Study of Transition Metal Complexes of Tridentate Ligand Formed by Direct Condensation of O-Vanillin and 2-Aminophenol: X-Ray Structural Characterization of the zinc(II) Complex. Eur. J. Chem. 2018, 9, 281-286.

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