Synthesis and spectroscopic study of transition metal complexes of tridentate ligand formed by direct condensation of o-vanillin and 2-aminophenol: X-ray structural characterization of the zinc(II) complex

Amadou Gueye; Farba Bouyagui Tamboura; Jean-Marc Planeix; Nathalie Gruber; Mohamed Gaye

doi:10.5155/eurjchem.9.4.281-286.1761

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Published: Dec 31, 2018

DOI: https://doi.org/10.5155/eurjchem.9.4.281-286.1761

Keywords:

Schiff base, Benzaldehyde, Metal complexes, Trigonal bipyramidal, X-ray crystallography, Single crystal structure

Section

Research Article

Issue

Vol. 9 No. 4 (2018): December 2018

Dates

Received 2018-06-09
Accepted 2018-08-28
Published 2018-12-31

Amadou Gueye

Department of Chemistry, University Cheikh Anta Diop, Dakar 12500, Senegal

http://orcid.org/0000-0002-3854-114X

Farba Bouyagui Tamboura

Department of Chemistry, University Alioune DIOP, Bambey 21400, Senegal

http://orcid.org/0000-0002-1108-0718

Jean-Marc Planeix

Laboratoire de Tectonique Moléculaire du Solide (UMR 7140), Chimie de la Matière Complexe, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, F-67008 Strasbourg, France

http://orcid.org/0000-0001-7414-0119

Nathalie Gruber

Laboratoire de Tectonique Moléculaire du Solide (UMR 7140), Chimie de la Matière Complexe, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, F-67008 Strasbourg, France

http://orcid.org/0000-0003-4986-2931

Mohamed Gaye

Department of Chemistry, University Cheikh Anta Diop, Dakar 12500, Senegal

http://orcid.org/0000-0001-8989-1548

Abstract

The reactions of the Schiff base 2-((2-hydroxyphenylimino)methyl)-6-methoxyphenol (H₂L), obtained by direct condensation of 2-aminophenol and 2-hydroxy-3-methoxybenzaldehyde, with some transition metal ions (Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)) afforded complexes of general formulae [M₂(L)₂(solvent)_x] (M: Mn, Co, Ni, Cu or Zn; Solvent: DMSO or H₂O). These compounds were characterized by elemental analysis, UV-Vis, IR, ¹H- and ¹³C-NMR spectroscopies, molar conductivity and room temperature magnetic measurements. The structure of zinc(II) complex has been determined by X-ray crystallography. Crystal data for C₃₂H₃₄N₂O₈S₂Zn₂ (M =769.47 g/mol): Orthorhombic, space group Pbca (no. 61), a = 16.3176(7) Å, b = 9.1247(3) Å, c = 21.8274(10) Å, V = 3250.0(2) Å³, Z = 4, T = 173(2) K, μ(MoKα) = 1.658 mm^-1, D_calc= 1.573 g/cm³, 28116 reflections measured (4.5° ≤ 2Θ ≤ 60.3°), 4457 unique (R_int = 0.0409, R_sigma = 0.0371) which were used in all calculations. The final R₁ was 0.0307(0.0466) and wR₂ was 0.0649 (0.0701) (all data). The coordination sphere of the Zn center is best described as a trigonal bipyramid.

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Gueye, A.; Tamboura, F. B.; Planeix, J.-M.; Gruber, N.; Gaye, M. Synthesis and Spectroscopic Study of Transition Metal Complexes of Tridentate Ligand Formed by Direct Condensation of O-Vanillin and 2-Aminophenol: X-Ray Structural Characterization of the zinc(II) Complex. Eur. J. Chem. 2018, 9, 281-286.

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References

[1]. Novoa, N.; Justaud, F.; Hamon, P.; Roisnel, T.; Cador, O.; Guennic, B. L.; Manzur, C.; Carrillo, D.; Hamon, J. R. Polyhedron 2015, 86, 81-88.
https://doi.org/10.1016/j.poly.2014.05.032

[2]. Saha, S.; Jana, S.; Gupta, S.; Ghosh, A.; Nayek, H. P. Polyhedron 2016, 107, 183-189.
https://doi.org/10.1016/j.poly.2016.01.034

[3]. Akila, E.; Usharani, M.; Ramachandran, S.; Jayaseelan, P.; Velraj, G.; Rajavel, R. Arabian J. Chem. 2017, 10, S2950-S2960.
https://doi.org/10.1016/j.arabjc.2013.11.031

[4]. Minelli, M.; Hart-Cooper, W.; Sinnwell, J. G.; Blumberg, D. T.; Guzei, I. A.; Spencer, L. C.; Vazquez, J. P. S.; Peralta, A. S.; Torres, M. S. Polyhedron 2018, 146, 26-34.
https://doi.org/10.1016/j.poly.2018.02.017

[5]. Baran, P.; Boca, R.; Breza, M.; Elias, H.; Fuess, H.; Jorik, V.; Klement, R.; Svobodae, I. Polyhedron 2002, 21, 1561-1571.
https://doi.org/10.1016/S0277-5387(02)01020-3

[6]. Capan, A.; Urus, S.; Sonmez, M. J. Saudi Chem. Soc. 2018, 22(6), 757-766.
https://doi.org/10.1016/j.jscs.2017.12.007

[7]. Samper, K. G.; Marker, S. C.; Bayon, P.; MacMillan, S. N.; Keresztes, I.; Palacios, O.; Wilson, J. J. J. Inorg. Biochem. 2017, 177, 335-343.
https://doi.org/10.1016/j.jinorgbio.2017.07.035

[8]. Kavitha, P.; Saritha, M.; Reddy, K. L. Spectrochim. Acta A 2013, 102, 159-168.
https://doi.org/10.1016/j.saa.2012.10.037

[9]. Ali, O. A. M.; El-Medani, S. M.; Ahmed, D. A.; Nassar, D. A. J. Mol. Struct. 2014, 1074, 713-722.
https://doi.org/10.1016/j.molstruc.2014.05.035

[10]. Shabbir, M.; Akhter, Z.; Ashraf, A. R.; Ismail, H.; Habib, A.; Mirza, B. J. Mol. Struct. 2017, 1149, 720-726.
https://doi.org/10.1016/j.molstruc.2017.08.050

[11]. Panja, A. Polyhedron 2012, 43, 22-30.
https://doi.org/10.1016/j.poly.2012.05.041

[12]. Kose, M.; Goring, P.; Lucas, P.; Mckee, V. Inorg. Chim. Acta 2015, 435, 232-238.
https://doi.org/10.1016/j.ica.2015.07.010

[13]. Ebrahimipour, S. Y.; Abaszadeh, M.; Castro, J.; Seifi, M. Polyhedron 2014, 79, 138-150.
https://doi.org/10.1016/j.poly.2014.04.069

[14]. Briseno-Ortega, H.; Juarez-Guerra, L.; Rojas-Lima, S.; Mendoza-Huizar, L. H.; Vazquez-Garcia, R. A.; Farfan, N.; Arcos-Ramos, R.; Santillan, R.; Lopez-Ruiza, H. J. Mol. Struct. 2018, 1157, 119-126.
https://doi.org/10.1016/j.molstruc.2017.12.059

[15]. Dey, S. K.; Mukherjee, A. Coord. Chem. Rev. 2016, 310, 80-115.
https://doi.org/10.1016/j.ccr.2015.11.002

[16]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.;Puschmann, H. J. Appl. Cryst. 2009, 42, 339-341.
https://doi.org/10.1107/S0021889808042726

[17]. Sheldrick, G. M. Acta Cryst. A 2015, 71, 3-8.
https://doi.org/10.1107/S2053273314026370

[18]. Sheldrick, G. M. Acta Cryst. C 2015, 71, 3-8.
https://doi.org/10.1107/S2053229614024218

[19]. Gao, B.; Zhang, D.; Li, Y. Opt. Mater. (Amsterdam, Neth. ) 2018, 77, 77-86.

[20]. Barfeie, H.; Grivani, G.; Eigner, V.; Dusek, M.; Khalaji, A. D. Polyhedron 2018, 146, 19-25.
https://doi.org/10.1016/j.poly.2018.02.012

[21]. Sedighipoor, M.; Kianfar, A. H.; Sabzalian, M. R.; Abyar, F. Spectrochim. Acta A 2018, 198, 38-50.
https://doi.org/10.1016/j.saa.2018.02.050

[22]. Egekenze, R. N.; Gultneh, Y.; Butcher, R. Inorg. Chim. Acta 2018, 478, 232-242.
https://doi.org/10.1016/j.ica.2018.01.027

[23]. Yousef, T. A.; Alduaij, O. K.; Ahmed, S. F.; El-Reash, G. M. A.; El-Gammal, O. A. J. Mol. Struct. 2016, 1119, 351-364.
https://doi.org/10.1016/j.molstruc.2016.04.033

[24]. Tserkezidou, C.; Hatzidimitriou, A. G.; Psomas, G. Polyhedron 2016, 117, 184-192.
https://doi.org/10.1016/j.poly.2016.05.044

[25]. Bibi, S.; Mohamad, S.; Manan, N. S. A.; Ahmad, J.; Kamboh, M. A.; Khor, S. M.; Yamin, B. M.; Halim, S. N. A. J. Mol. Struct. 2017, 1141, 31-38.
https://doi.org/10.1016/j.molstruc.2017.03.072

[26]. Kane, C. H.; Tinguiano, D.; Tamboura, F. B.; Thiam, I. E.; Barry, A. H.; Gaye, M.; Retailleau; P. Bull. Chem. Soc. Ethiop. 2016, 30, 101-110.

[27]. Hasnan, M. M. I. M.; Abdullah, N.; Said, S. M.; Salleh, M. F. M.; Hussin, S. A. M.; Shah, N. M. Electrochim. Acta 2018, 261, 330-339.
https://doi.org/10.1016/j.electacta.2017.12.145

[28]. Ammar, R. A.; Alaghaz, A. N. M. A.; Zayed, M. E.; Al-Bedair, L. A. J. Mol. Struct. 2017, 1141, 368-381.
https://doi.org/10.1016/j.molstruc.2017.03.080

[29]. Seals, W.; Arman, H.; Batha, G.; Musie, G. T. Inorg. Chim. Acta 2018, 448, 16-25.
https://doi.org/10.1016/j.ica.2016.04.008

[30]. Jana, N. C.; Brandao, P.; Saha, A.; Panja, A. Polyhedron 2017, 138, 31-36.
https://doi.org/10.1016/j.poly.2017.09.002

[31]. Thompson, L. K.; Mandal, S. K.; Tandon, S. S.; Bridson, J. N.; Park, M. K. Inorg. Chem. 1996, 35, 3117-3125.
https://doi.org/10.1021/ic9514197

[32]. Geary, W. J. Coord. Chem. Rev. 1971, 7, 81-122.
https://doi.org/10.1016/S0010-8545(00)80009-0

[33]. Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J.; Verschoor, G. C. J. Chem. Soc., Dalton Trans. 1984, 1349-1356.
https://doi.org/10.1039/DT9840001349

[34]. Bhattacharyya, A.; Sen, S.; Harms, K.; Chattopadhyay, S. Polyhedron 2015, 88, 156-163.
https://doi.org/10.1016/j.poly.2014.12.018

[35]. Azam, M.; Al-Resayes, S. I. J. Mol. Struct. 2016, 1107, 77-81.
https://doi.org/10.1016/j.molstruc.2015.11.017

[36]. Fliedel, C.; Rosa, V.; Alves, F. M.; Martins, A. M.; Aviles, T.; Dagorne, S. Dalton Trans. 2015, 44, 12376-12387.
https://doi.org/10.1039/C5DT00458F

[37]. Parrilha, G. L.; Vieira, R. P.; Rebolledo, A. P.; Mendes, I. C.; Lima, L. M.; Barreiro, E. J.; Piro, O. E.; Castellano, E. E.; Beraldo, H. Polyhedron 2011, 30, 1891-1898.
https://doi.org/10.1016/j.poly.2011.04.024

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